Setting priorities for waste management strategies in developing countries.

This study aimed to determine whether the waste management systems, that are presently applied in affluent countries are appropriate solutions for waste management in less developed regions. For this purpose, three cities (Vienna, Damascus and Dhaka) which differ greatly in their gross domestic product and waste management were compared. The criteria for evaluation were economic parameters, and indicators as to whether the goals of waste management (protection of human health and the environment, the conservation of resources) were reached. Based on case studies, it was found that for regions spending 1-10 Euro capita(-1) year(-1) for waste management, the 'waste hierarchy' of prevention, recycling and disposal is not an appropriate strategy. In such regions, the improvement of disposal systems (complete collection, upgrading to sanitary landfilling) is the most cost-effective method to reach the objectives of solid waste management. Concepts that are widely applied in developed countries such as incineration and mechanical waste treatment are not suitable methods to reach waste management goals in countries where people cannot spend more than 10 Euro per person for the collection, treatment and disposal of their waste. It is recommended that each region first determines its economic capacity for waste management and then designs its waste management system according to this capacity and the goals of waste management.     

Chloroethene dechlorination in acidic groundwater: Implications for combining fenton's treatment with natural attenuation

A sulfuric acid leak in 1988 at a chloroethene‐contaminated groundwater site at the Naval Air Station Pensacola has resulted in a long‐term record of the behavior of chloroethene contaminants at low pH and a unique opportunity to assess the potential impact of source area treatment technologies, which involve acidification of the groundwater environment (e.g., Fenton's‐based in situ chemical oxidation), on downgradient natural attenuation processes. The greater than 75 percent decrease in trichloroethene (TCE) concentrations and the shift in contaminant composition toward predominantly reduced daughter products (dichloroethene [DCE] and vinyl chloride [VC]) that were observed along a 30‐m groundwater flow path characterized by highly acidic conditions (pH = 3.5 ± 0.4) demonstrated that chloroethene reductive dechlorination can continue to be efficient under persistent acidic conditions. The detection of Dehalococcoides‐type bacteria within the sulfuric acid/chloroethene co‐contaminant plume was consistent with biotic chloroethene reductive dechlorination. Microcosm studies conducted with ¹⁴C‐TCE and ¹⁴C‐VC confirmed biotic reductive dechlorination in sediment collected from within the sulfuric acid/chloroethene co‐contaminant plume. Microcosms prepared with sediment from two other locations within the acid plume, however, demonstrated only a limited mineralization to ¹⁴CO₂ and ¹⁴CO, which was attributed to abiotic degradation because no significant differences were observed between experimental and autoclaved control treatments. These results indicated that biotic and abiotic mechanisms contributed to chloroethene attenuation in the acid plume at NAS Pensacola and that remediation techniques involving acidification of the groundwater environment (e.g., Fenton's‐based source area treatment) do not necessarily preclude efficient chloroethene degradation. © 2007 Wiley Periodicals, Inc.     

An application of 3D gasdynamic modeling for the prediction of overpressures in vented enclosures

A three-dimensional gasdynamic model with constant burning rate is applied for the prediction of the maximum pressure rise from gaseous combustion in vented enclosures. A series of calculations for an enclosure with aspect ratio close to unity are presented. Both cases with and without obstacles in the enclosure are considered. Results of calculations are compared with a simple 0D solution for spherical vessels. It is shown that, in cases without obstacles, the 0D solution for the maximum reduced overpressures is close to the predictions of the detailed modeling. In cases with obstacles, the detailed simulation gives significantly higher overpressures than those from the 0D model. However, in all the cases the reduced pressures are correlated well with the maximum flame surface area.     

Moderation of dust explosions

Inherent safety is a proactive approach to process safety in which hazards are removed or minimized so as to reduce risk without engineered (add-on) or procedural intervention. Four basic principles are available to attain an inherently safer design—minimization, substitution, moderation, and simplification. The subject of the current paper is the principle of moderation as it applies to the prevention and mitigation of dust explosions.

Moderation can be achieved by processing a material under less severe operating conditions or by processing the material in a less hazardous form. With respect to the latter approach, it may be possible to alter the composition of a dust by admixture of solid inertants, or to increase the dust particle size so as to decrease its reactivity. Additionally, avoidance of the formation of hybrid mixtures of explosible dusts and flammable gases is an application of moderation of the material hazard.

Several examples are given for each of the above three forms of moderation. The discussion on admixture of solid inertants includes examples from the following industrial applications: (i) refractory materials manufacturing, (ii) food processing, (iii) power generation, (iv) industrial recycling, and (v) foundry shell mold fabrication. The importance of particle size consideration is explained first from the perspective of engineering tools such as the Dow Fire & Explosion Index, and professional guidance on the definition of a dust and suitable particle sizes for explosibility testing. Industrial examples are then drawn from the following areas: (i) rubber recycling and textile manufacturing, (ii) industrial recycling, (iii) wood processing, (iv) dry additive handling (polyethylene facility), (v) polyethylene production, (vi) carbon block recycling, and (vii) coal mining. The concluding discussion on hybrid mixtures includes brief cases from the process safety literature.     

Fish bioassay monitoring of waste effluents

Spills of toxic materials into bodies of water receiving industrial waste discharges can be prevented only if frequent or continuous assessments of effluent quality can be made. Currently available methods can automatically measure individual physical or chemical waste components but cannot assess toxicity caused by the interaction of components or the presence of an unsuspected material. Aquatic organisms, in contrast, respond to their total environment and in this way integrate the effects of all the various chemical and physical waste parameters.This study evaluates the possibility of using the continuously and automatically recorded responses of fish to monitor the toxicity of industrial waste effluents. A review of previously developed toxicity monitoring systems is followed by a field evaluation of a method that uses the computer-monitored ventilatory patterns of 12 bluegills (Lepomis macrochirus Rafinesque) to monitor the toxicity of an industrial waste effluent as it flows into a river. No known toxic spills occurred in the effluent during the operation of this system, but acetone added to the effluent waste caused responses from the fish at concentrations which peaked near the 96-hr LC₅₀ level. Some responses were also noted when no known toxicant was present; these were related to environmental disturbances and system design problems. Recommendations are made for the design of future biologic monitoring units.     

Simulation modeling and resource management

Simulation models are becoming increasingly important as tools for synthesizing and applying information in almost all aspects of land management. They are particulary valuable for predicting and comparing outcomes of alternative decisions and assumptions. Models also permit managers to consider and integrate the potential influences of a large number of variables.     

Snowmobile impact on old field and marsh vegetation in Nova Scotia,Canada: An experimental study

A study was carried out in Nova Scotia, Canada, to experimentally assess the effect of snowmobiles on old field and marsh vegetation. Snowmobile treatments ranging from a single pass to 25 passes (five passes on five separate days) were administered. The first pass by a snowmobile caused the greatest increase in snow compaction-roughly 75% of that observed after five sequential passes. Snowmobile treatment resulted in highly significant increases in snow retention in spring. Frequency was more important than intensity in this regard.Standing crop and species composition were measured the following summer. Standing crop in the field showed a significant reduction with increasing snowmobile use; frequency of treatment (p < 0.01) was more important than intensity (p = 0.125).Stellaria graminea, Aster cordifolius, Ranunculus repens, andEquisetum arvense all showed significant (p < 0.05) differences in percent cover resulting from the treatment. Marginally significant changes were observed inAgrostis tenuis andPhleum pratense Marsh vegetation showed no significant effects of snowmobile treatment. This may have been because of solid ice cover during the winter.The literature is critically reviewed. It is concluded that snowmobile use can have a highly significant effect upon natural vegetation. Management suggestions are made.     

Plant response to Los Angeles aqueduct construction in the Mojave desert

Construction of the 1913 Los Angeles aqueduct system had a different effect on vegetation productivity, diversity, and stability in the Mojave Desert than did construction of the 1970 aqueduct. Drastic disturbance was found to impede vegetation recovery, whereas slight disturbance sometimes enhanced vegetation. Comparisons of productivity, diversity, and stability measures for both aqueducts show apparent similarities of vegetation cover, biomass, and density. However, these similarities often vanish when one considers qualitative factors, such as proportion of long-lived species and typical cominants of undisturbed communities. Percentage composition of common long-lived perennials represents a good qualitative measure to supplement quantitative comparisons. Enhancement of vegetation along the right-of-way transects of the 1913 aqueduct shows considerable recovery, owing to the more than 65 years that have passed since construction.     

GROWTH INHIBITION OF HYDRILLA VERTICILLATA BY SELECTED LAKE SEDIMENT EXTRACTS1

ABSTRACT: Sediments were investigated from two Florida lakes that have not been infested with the submersed, perennial, noxious plant Hydrilla verticillata. Aqueous extracts of the peat-like sediments from these lakes were shown to inhibit the growth of Hydrilla verticillata in laboratory systems. The extracts have substantial concentrations of organic carbon and iron. The apparent molecular weight of the inhibitory fraction is between 2,000 and 10,000, based upon ultrafiltration studies. Hydrilla growth was about 35 percent relative to control for a partially purified fraction at a level of 0.4 ppm organic carbon. Growth was measured as change in biomass (wet and dry) over a one-week period. The inhibitory material was highly fluorescent, dark brown, and inhibitory activity was lost after passage over an anion-exchange column (Cellex-D).     

FACTORS AFFECTING SALINITY REDUCTION IN LAKE TARPON,PINELLAS COUNTY,FLORIDA1

ABSTRACT: Following an enclosure of a sink-hole connecting Lake Tarpon to the Gulf of Mexico, the chloride concentration of lake waters decreased. Water and chloride budgets for the lake in 1975 were prepared, and predictions using the model of Lerman and Brunskill (1971) were made as to the time required for the lake to achieve fresh water status. Model verification indicated good agreement with predictions in 1976; however, data on [C1^-] for 1977 and 1978 are not as supportive of the model used. The information concerning the Lake Tarpon watershed provided by this latter fact is discussed.