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671.
Mehmet Berkun Egemen Aras Tugce Anılan 《Journal of Material Cycles and Waste Management》2011,13(4):305-313
As an economically developing country, Turkey has very well operated integrated solid waste management applications structured
on modern facilities, besides over 2,000 scattered open dump areas in the country. Integrated waste management applications
seem eligible for the metropolitan cities like Istanbul and Izmit (Kocaeli). Attempts have not been encouraging for the scattered
regional settlements using central storage sites due to financial shortages and received rejections from nearby settlements.
Small-scale compact solid waste management systems with materials recycling and composting can be more suitable alternatives
in the small-scale regional settlements. The major constituents of municipal solid waste are organic in nature and approximately
a quarter of municipal solid waste is recyclable. Although paper, including cardboard, is the main constituent, the composition
of recyclable waste varies strongly by the source or the type of collection point. Solid wastes need primary treatment in
order to be suitable for incineration and composting. Turkey needs to give more emphasis on the usage of modern solid waste
removal technologies to overcome the overgrowing solid waste disposal problems. 相似文献
672.
The circular economy has been developing rapidly in recent years in China. A legislative system has been created to provide
legal protection for the development of a circular economy, including a series of price and tax measures in the waste management
area. These measures form the basic foundation for promoting better waste management under the circular economic model. Many
challenges, however, remain. For instance, the legal system needs to incorporate more sophisticated science, and China lacks
key waste treatment technology that could support the further development of a circular economy. There is also a need to educate
the public about the concept of the circular economy and its benefits. Specific suggestions are made for the development and
implementation of the circular economic model. 相似文献
673.
Hisanori Watanabe Hidekichi Yoshino 《Journal of Material Cycles and Waste Management》2011,13(2):113-117
Since hydrogen is a renewable energy source, biohydrogen has been researched in recent years. However, data on hydrogen fermentation
by a leachate from a waste landfill as inoculum are scarce. We investigated hydrogen production using a leachate from an industrial
waste landfill in Kanagawa Prefecture. The results showed no methane gas production, and the leachate was a suitable inoculum
for hydrogen fermentation. The maximum H2 yield was 2.67 mol of H2 per mol of carbohydrate added, obtained at 30°C and an initial pH of 7. The acetate and butyrate production was significant
when the H2 yield was higher. Oxidation–reduction potential analysis of the culture suggested that hydrogen-producing bacteria in the
leachate were facultative anaerobic. Scanning electron microscope observations revealed that the hydrogen-producing bacteria
comprised bacilli about 2 μm in length. 相似文献
674.
Shinsuke Iijima Morito Nakamura Akira Yokoi Mitsuhiro Kubota Liwei Huang Hitoki Matsuda 《Journal of Material Cycles and Waste Management》2011,13(3):206-212
For an effective decomposition and removal of organic halogenated compounds, a packed-bed non-thermal plasma reactor with
in situ absorption of the resulting halogenated products by alkaline sorbent incorporated was proposed. In the plasma reactor,
α-Al2O3 particles of 1 and 3 mm (mean particle diameter) were packed as solid dielectric medium to enhance the plasma power density
in the reactor. Further, alkaline sorbent of Ca(OH)2 was doped onto the surface of α-Al2O3 particles, in order to remove halogenated products by in situ absorption with Ca(OH)2. A high-voltage and high-frequency pulsed power of −15 to 15 kV and 1 kHz was applied to the wire electrode of the plasma
reactor by means of a DC power source. In the present study, as the sample of an organic halogenated compound that is most
popularly used, we selected dichloromethane (CH2Cl2), and 500 ppm of the initial concentration of CH2Cl2 was fed into the reactor accompanied by air at a fixed flow rate of 500 × 10−6 m3 min−1 at room temperature. As a result, it was recognized that the amount of CH2Cl2 decomposed by non-thermal plasma in an α-Al2O3 particle bed increased with an increase in plasma input power. The ratio of decomposition of CH2Cl2 was almost 100% at 13 kV of electric power and 1 kHz frequency, and CO2, CH3Cl, COCl2, HCl, and Cl2 were observed as the major reaction products. On the other hand, when CH2Cl2 was introduced into the plasma reactor where α-Al2O3 particles doped with Ca(OH)2 were packed, the ratio of decomposition of CH2Cl2 became higher, compared to the case that α-Al2O3 particles were not doped with Ca(OH)2. Moreover, there were no halogenated by-product gases detected in the outlet gas from the reactor. As the solid reaction
products, CaClOH and Ca(ClO)2·4H2O were detected on Ca(OH)2 by X-ray diffraction. From these findings, it was recognized that CH2Cl2 was decomposed more effectively without producing unwanted harmful halogenated by-products in the proposed non-thermal plasma
reactor where α-Al2O3 particles doped with Ca(OH)2 sorbent were packed. 相似文献
675.
Waste incineration is becoming increasingly necessary to tackle the rapidly rising amounts of municipal solid waste (MSW);
in China many large cities are already surrounded by a girdle of landfills. Still, the not-in-my-backyard (nimby) syndrome
holds strong. This attitude stems from fear of dioxins. These have been associated with incineration (‘dioxin factories’)
and at times also with polyvinylchloride. In this paper this issue is analysed. China should build additional trust in MSW
incineration, following promulgation of stricter emission standards, enforced by stringent controls. 相似文献
676.
Jung-Eun Lee 《Journal of Material Cycles and Waste Management》2011,13(3):259-263
Effective handling of municipal digested sludge requires that the product cake have low water content. To this end, we investigated
the change in sludge dewaterability after the addition of fly ash to municipal digested sludge, dewatering of which is difficult
because of its high organic content. The performance of the dewatering is compared with that of electroosmotic dewatering
(EDW) and conventional mechanical dewatering (CMD). Fly ash classified by sieving to the size of 25–75 μm and >75 μm is added
to the municipal digested sludge by 10, 20, and 50 wt% by wet base. When adding fly ash particles to municipal digested sludge,
dewatering efficiency improved with smaller fly ash particle size and with increase in the amount. When sludge was dewatered
using an electroosmotic dewatering method, the dewatering efficiency is improved about 40% by adding fly ash of 25–75 μm particle
size with 20 wt% when compared with conventional mechanical dewatering method without adding the fly ash. It is concluded
that fly ash particles rich in inorganic material are helpful in the dewatering process when added to municipal digested sludge
and EDW is more effective than CDW. 相似文献
677.
Ivan S. Ristić Ljiljana Tanasić Ljubiša B. Nikolić Suzana M. Cakić Olivera Z. Ilić Radmila Ž. Radičević Jaroslava K. Budinski-Simendić 《Journal of Polymers and the Environment》2011,19(2):419-430
Different synthesis methods were applied to determine optimal conditions for polymerization of (3S)-cis-3,6-dimethyl-1,4-dioxane-2,5-dione (l-lactide), in order to obtain poly(l-lactide) (PLLA). Bulk polymerizations (in vacuum sealed vessel, high pressure reactor and in microwave field) were performed
with tin(II) 2-ethylhexanoate as the initiator. Synthesis in the vacuum sealed vessel was carried out at the temperature of
150 °C. To reduce the reaction time second polymerization process was carried out in the high pressure reactor at 100 °C and
at the pressure of 138 kPa. The third type of rapid synthesis was done in the microwave reactor at 100 °C, using frequency
of 2.45 GHz and power of 150 W at the temperature of 100 °C. The temperature in this method was controlled via infrared system
for in-bulk measuring. The solution polymerization (with trifluoromethanesulfonic acid as initiator) was possible even at
the temperature of 40 °C, yielding PLLA with narrow molecular weight distribution in a very short period of time (less than
6 h). The obtained polymers had the number-average molecular weights ranging from 43,000 to 178,000 g mol−1 (polydispersity index ranging from 1 to 3) according to the gel permeation chromatography measurements. The polymer structure
was characterized by Fourier transform infrared and NMR spectroscopy. Thermal properties of the obtained polymers were investigated
using thermogravimetry and differential scanning calorimetry. 相似文献
678.
Candice DeLeo Caio Augusto Pinotti Maria do Carmo Gonçalves Sachin Velankar 《Journal of Polymers and the Environment》2011,19(3):689-697
Plasticized starch (PLS) is a renewable, degradable, and inexpensive polymer, but it suffers from poor mechanical properties.
The mechanical properties can be improved by blending PLS with polyolefins, nonetheless, at high PLS content, the mechanical
properties remain poor. Here we show that addition of clay can greatly improve the mechanical properties of PLS/polypropylene
blends at high starch content. Unmodified and organically modified montmorillonite clays, MMT and Cloisite 30B respectively,
were added to blends of glycerol-plasticized starch and polypropylene, compatibilized using maleated polypropylene. TEM indicates
that MMT is well dispersed in the PLS phase of the blends, while Cloisite 30B is located both within the PLS phase as well
as at the interface between PLS and PP. At high PLS content, the addition of clay increased the tensile strength and tensile
modulus by an order of magnitude, while reducing the ultimate elongation only slightly. Such improvements are attributable
to both the addition of clay as a reinforcing component, as well as to the change in the two phase morphology due to addition
of clay. 相似文献
679.
Poly-β-hydroxybuyrate (PHB) is a carbon—energy storage material which is accumulated as intracellular granule in variety of
microorganism under nutrient starved conditions. Solid PHB is a biodegradable thermoplastic polymer and is utilizable in various
ways similar to many conventional plastics. Ralstonia eutropha (Alcaligenes sp.), a gram negative bacteria accumulates PHB as insoluble granules inside the cells when nutrients other than carbon are
limited. In this report effort has been made to analyze PHB granule synthesis inside Alcaligenes sp. NCIM 5085 by transmission electron microscopy and qualitative estimation of PHB was carried out by fourier transform
infrared spectroscopy which provide better precision compared to other conventional techniques previously applied for PHB
determination. Maximum PHB concentration of 2.20 ± 0.40 g/L and cell biomass of 3.42 ± 0.20 g/L was obtained after 48.0 h
of fermentation. Leudking-Piret equation deduced mixed growth associated product formation which varies from earlier reports. 相似文献
680.
K. Abdel Tawab M. M. Magida Sayeda M. Ibrahim 《Journal of Polymers and the Environment》2011,19(2):440-446
Blends of water—soluble polymers based on Poly vinyl alcohol (PVA) and Polyethylene glycol (PEG) have been prepared by the
solution casting technique. The effect of various doses of γ-radiation on the structural properties of PVA/PEG polymer blends
with all its compositions has been investigated. From the visual observation of all the blend compositions, it was found that,
the best compatibility of the blend is up to 40% PVA/60%PEG. The structure–Property behavior of all the prepared blends before
and after γ-irradiation was investigated by IR Spectroscopy, thermogravimetric analysis (TGA), mechanical properties and Scanning
electron microscope (SEM). The gel content and the swelling behavior of the PVA/PEG blends were investigated. It was found
that the gel content increases with increasing irradiation dose and PVA concentration in the blend. Swelling percent increased
as the composition of PEG increased in the blend. The results obtained by FTIR analysis and SEM confirm the existence of possible
interaction between PVA and PEG homopolymers. TGA of PVA/PEG blend, before and after γ-irradiation, showed that the unirradiated
and irradiated PVA/PEG blends are more stable against thermal decomposition than pure PVA. Improvement in tensile mechanical
properties of PVA/PEG blends was occurred. 相似文献