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511.
Iain McLellan Andrew Hursthouse Calum Morrison Adélia Varela Cristina Silva Pereira 《Environmental monitoring and assessment》2014,186(2):1281-1293
A major concern for the cork and wine industry is ‘cork taint’ which is associated with chloroanisoles, the microbial degradation metabolites of chlorophenols. The use of chlorophenolic compounds as pesticides within cork forests was prohibited in 1993 in the European Union (EU) following the introduction of industry guidance. However, cork produced outside the EU is still thought to be affected and simple, robust methods for chlorophenol analysis are required for wider environmental assessment by industry and local environmental regulators. Soil samples were collected from three common-use forests in Tunisia and from one privately owned forest in Sardinia, providing examples of varied management practice and degree of human intervention. These provided challenge samples for the optimisation of a HPLC-UV detection method. It produced recoveries consistently >75 % against a soil CRM (ERM-CC008) for pentachlorophenol. The optimised method, with ultraviolet (diode array) detection is able to separate and quantify 16 different chlorophenols at field concentrations greater than the limits of detection ranging from 6.5 to 191.3 μg/kg (dry weight). Application to a range of field samples demonstrated the absence of widespread contamination in forest soils at sites sampled in Sardinia and Tunisia. 相似文献
512.
Marina Pereira Dore Cássia Farias Cláudia Hamacher 《Environmental monitoring and assessment》2017,189(1):44
The exploration and production of oil and gas reserves often result to drill cutting accumulations on the seafloor adjacent to drill locations. In this study, the detection of drilling influence on marine sediments was performed by meta-analytical comparison between data from pre- and post-drilling surveys undertaken in offshore Campos Basin, southeast of Brazil. Besides this overall appraisal on the geochemical variables, a multivariate assessment, considering only the post-drilling data, was performed. Among the variables, fines content, carbonates, total organic carbon, barium, chromium, copper, iron, manganese, nickel, lead, vanadium, zinc, and total petroleum hydrocarbons, only barium, copper, and hydrocarbons were related to drilling impacts. In relation to the point of discharge, relative elevated levels in the post-drilling campaigns were observed preferentially up to 500 m in the northeast and southwest directions, associated to the Brazil Current-predominant direction. Other distributed concentrations in the surroundings seem to indicate the dilution and dispersion of drilling waste promoted by meteoceanographic factors. 相似文献
513.
Samara Teixeira Pereira Elisngela Maria Rodrigues Rocha Elson Santos da Silva Giulia Beatriz Mota da Silva Maria Luisa Palitot Remigio Alves 《环境质量管理》2020,29(3):43-49
The present work investigated color and biochemical oxygen demand (COD) removal from treated landfill leachate via advanced oxidative processes (AOPs) artificially emitted. The AOP H2O2/UV, TiO2/UV, and photolysis were tested in two bench‐scale photoreactors: The first one with UV‐C lamp and the other with UV‐A lamp associated or not with coagulation / flocculation pretreatment. Crude leachate samples with pH ranging from 8 to 3 were used, and time varied in 30, 45, and 60 minutes. Experiments were performed in two stages: step 1 with a 20 mL volume from each sample and step 2 with repetition of the best results from the previous step, adopting the 150 mL volume. In step 1, the AOP applied in the crude leachate sample showed the best results, standing out H2O2/UV‐C with 30 minutes and TiO2/UV‐A with 60 minutes. In step 2, H2O2/UV‐C had a 60% color removal and 25% COD reduction, while TiO2/UV‐A had a 10% color removal and 20% COD reduction. Therefore, the H2O2/UV‐C process was the most efficient, because the complex characteristics of the effluent interfered in the TiO2/UV‐A efficiency, but it is necessary to eliminate the process interferences. The use of artificial radiation is a viable alternative; however, it can be costly, being relevant in the associations between processes with artificial UV and solar UV, as the natural radiation becomes more attractive and allows the process operating costs reduction. 相似文献
514.
Rodrigues SM Henriques B Ferreira da Silva E Pereira ME Duarte AC Groenenberg JE Römkens PF 《Chemosphere》2010,81(11):1560-1570
To assess environmental risks related to contaminants in soil it is essential to predict the available pool of inorganic contaminants at regional scales, accounting for differences between soils from variable geologic and climatic origins. An approach composed of a well-accepted soil extraction procedure (0.01 M CaCl(2)) and empirical Freundlich-type models in combination with mechanistically based models which to date have been used only in temperate regions was applied to 136 soils from a South European area and evaluated for its possible general use in risk assessment. Empirical models based on reactive element pools and soil properties (pH, organic carbon, clay, total Al, Fe and Mn) provided good estimations of available concentrations for a broad range of contaminants including As, Ba, Cd, Co, Cu, Hg, Mo, Ni, Pb, Sb, Se and Zn (r(2): 0.46-0.89). The variation of the pools of total Al in soils expressed the sorptive capacity of aluminosilicates and Al oxides at the surfaces and edges of clay minerals better than the actual variability of clay contents. The approach has led to recommendations for further research with particular emphasis on the impact of clay on the solubility of As and Sb, on the mechanisms controlling Cr and U availability and on differences in binding properties of soil organic matter from different climatic regions. This study showed that such approach may be included with a good degree of certainty for first step risk assessment procedures to identify potential risk areas for leaching and uptake of inorganic contaminants in different environmental settings. 相似文献
515.
Degradation of phenols in olive oil mill wastewater by biological,enzymatic, and photo-Fenton oxidation 总被引:1,自引:0,他引:1
Celine Justino Ana Gabriela Marques Kátia Reis Duarte Armando Costa Duarte Ruth Pereira Teresa Rocha-Santos Ana Cristina Freitas 《Environmental science and pollution research international》2010,17(3):650-656
Background, aim, and scope
Olive oil mill wastewater (OOMW) environmental impacts minimization have been attempted by developing more effective processes, but no chemical or biological treatments were found to be totally effective to mitigate their impact on receiving systems. This work is the first that reports simultaneously the efficiency of three different approaches: biological treatment by two fungal species (Trametes versicolor or Pleurotus sajor caju), enzymatic treatment by laccase, and chemical treatment by photo-Fenton oxidation on phenols removal. 相似文献516.
Lake Vela, located in the Portuguese littoral-centre, is a temperate shallow lake exhibiting a high trophic status. This aquatic
ecosystem has been potentially exposed to contamination generated by agricultural and livestock activities held in their drainage
basin, which seriously compromise their health. This work summarizes some background information and presents the problem
formulation step of the ERA. Therefore, it evaluates the characteristics of the stressor(s), describes the ecological system
and receptors and suggests a conceptual model, which predicts the potential exposure pathways, relating suspected sources
to the defined endpoints. This introductory step also described an analysis plan on the entire study, which includes a delineation
of the assessment design, data needs, measures, and methods for conducting the analysis phase of the risk assessment process. 相似文献
517.
de Oliveira Maria Rayane Correia de Lima Silva Maria Gabriely Alcântara Isabel Sousa Filho Jaime Ribeiro Tintino Cícera Datiane de Morais Oliveira Magalhães Francisco Ernani Alves Martins Anita Oliveira Brito Pereira Bezerra Pessoa Renata Torres Duarte Antonia Eliene da Costa José Galberto Martins de Lima Sidney Gonçalo Coutinho Henrique Douglas Melo Capasso Raffaele de Menezes Irwin Rose Alencar 《Environment, Development and Sustainability》2021,23(10):14958-14981
Environment, Development and Sustainability - This work aimed to analyze the chemical composition and evaluate the anti-inflammatory and antinociceptive properties of the essential oil obtained... 相似文献
518.
Monitoring of ambient air PCDD/F levels in Portugal 总被引:3,自引:0,他引:3
As part of a monitoring program conducted by IDAD--Institute for Environment and Development and supported by regional municipal solid waste (MSW) management authorities, dioxin concentrations in ambient air were measured in three regions of Portugal: Porto, Lisbon and Madeira. These independent studies were performed with the intention of providing data as a basis for the evaluation of potential impacts of the operation of recently built MSW incinerators. Thus, 170 samples were collected in nine different sites from January 1999 till present. The measured levels revealed an extremely variable content of PCDDs/PCDFs depending both on the area and the season of the year. Samples taken in Porto and Lisbon reveal a similar homologue structure even if concentrations measured in the Porto region are significantly greater. Data from Madeira is characteristic of a remote site with some of the congeners concentrations below the detection limit. 相似文献
519.
The influence of the colonization of salt marsh sediments with Halimione portulacoides was evaluated by analysing the fluorescent dissolved organic matter (FDOM) in sediment pore waters from a salt marsh at different depths. Cores of sediments at colonized and non-colonized sites were collected from a coastal lagoon (Ria de Aveiro, Portugal). The DOC content of extracted pore waters was determined and characterized by synchronous molecular fluorescence (Deltalambda=60nm) and UV-visible spectroscopies. The common practice of freezing sediment cores for further and later chemical investigation was shown not to be an appropriate methodology of sample preservation. On the contrary, freezing of extracted and filtered pore water seemed not to affect either the DOC content or the fluorescence properties of pore waters. Two types of fluorescent substances were found in the pore waters spectra; one corresponding to humic-like substances and another one resembling proteins. However, major differences were found in the spectra of pore waters depending on both depth and the presence/absence of vegetation colonization. 相似文献
520.
Poliana Cardoso-Gustavson Francine Faia Fernandes Edenise Segala Alves Mariana Pereira Victorio Barbara Baesso Moura Marisa Domingos Caroline Albuquerque Rodrigues Andreza Portella Ribeiro Catarina Carvalho Nievola Ana Maria G Figueiredo 《Environmental science and pollution research international》2016,23(2):1779-1788