Carbon source in the future chemical industries

Rising crude oil prices favour the exploitation of hitherto unutilised energy carriers and the realisation of new technologies in all sectors where carbon is used. These changed economic constraints necessitate both savings in conventional petrochemistry and a change to oil-independent carbon sources in the chemical industry. While, in coal chemistry, the synthesis and process principles of petrochemistry — fragmentation of the raw material and subsequent buildup of molecular structures — can be maintained, the raw material structure largely remains unchanged in the chemistry of renewable raw materials. This lecture is to demonstrate the structural as well as the technological and energy criteria of the chemistry of alternative carbon sources, to forecast the chances of commercial realization and to discuss some promising fields of research and development.     

Reduction of surfactant concentrations in static fish tests compared with biodegradation rates in the OECD screening test

The loss of chemicals in static fish tests due to biodegradation has been studied with eight model surfactants whose biodegradabilities in the OECD Screening Test range from 0 to 99 % BiAS removal. There was a good correlation between biodegradation in the fish test and in the OECD Screening Test. Only surfactants with a very high BiAS removal of above 93 % were also degraded quickly in the fish test. Surfactants with less than 80 % BiAS removal incurred losses of less than 20 % in the fish test. These results indicate that those substances which are not lost by volatility or adsorption will be maintained to at least 80 % of their nominal concentration during a 96 hour static fish test.     

Trace Metals in New England Marine Sediments: Casco Bay, Maine, in relation to Other Sites

The concentrations in surface sediments of the trace metals Cd, Cr, Cu, Ni, Pb and Zn have been determined at 32 stations in the Casco Bay region of the Gulf of Maine. The metals are not distributed homogeneously but exhibit elevated levels around the Portland waterfront and generally low levels at offshore and tidally scoured stations. Comparison of these results to those from both industrialized and non-industrialized sites throughout New England indicates that the sediments in parts of the Casco Bay region are affected by trace metals.     

Resource Potentials and Limitations of A Nicaraguan Agricultural Region

Food production has to be increased in a sustainable way to meet the future global demand. A key position is attributed to developing countries. A deepened understanding of their agricultural regions with specific resource endowments and constraints is therefore crucial. In this study we propose a methodology based on material flux analysis (MFA) to assess the resource potentials and limitations of a Nicaraguan agricultural region. We focus on current regional and farm resource management and explore them under two scenarios. Indicators are nitrogen and the degrees of self-sufficiency (DSS) for energy, and the staples maize and beans. As data is scarce, most information is based on interviews with farmers of four categories and key persons, and on literature. The results show that nitrogen management does not differ considerably among categories. Nitrogen is mined mostly from staple plots. Self-sufficiency for beans is given in an average year. Yet, landless and small farmers neither produce enough maize for autoconsumption, nor are they self-sufficient for firewood. Energy supply is also the core problem of the region, since the DSS is 70%. Soil nitrogen stocks last at most for three more generations. Analyses with the scenario technique show that: (a) Unlimited population growth has serious consequences in the near future e.g. severe shortage of energy and food. (b) Alternative farming systems are possible, but they require reducing the population by a factor 2, and thus the creation of jobs in a Hinterland. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

The mental health of expatriate and Kosovar Albanian humanitarian aid workers

The mental health consequences of exposure to traumatic events and the risk factors for psychological morbidity among expatriate and Kosovar Albanian humanitarian aid workers have not been well studied. In June 2000, we used standardised screening tools to survey 285 (69.5%) of 410 expatriate aid workers and 325 (75.8%) of 429 Kosovar Albanian aid workers from 22 humanitarian organizations that were implementing health programmes in Kosovo. The mean number of trauma events experienced by expatriates was 2.8 (standard deviation: 2.7) and by Kosovar staff 3.2 (standard deviation: 2.8). Although only 1.1% of expatriate and 6.2% of Kosovar aid workers reported symptoms consistent with the diagnosis for post-traumatic stress disorder, 17.2% and 16.9%, respectively, reported symptoms satisfying the definition of depression. Regression analysis demonstrated that the number of trauma events experienced was significantly associated with depression for the two sets of workers. Organisational support services may be an important mediating factor and should be targeted at both groups.     

Planning environmental sanitation programmes in emergencies

Environmental sanitation programmes are vital for tackling environmental-related disease and ensuring human dignity in emergency situations. If they are to have maximum impact they must be planned in a rapid but systematic manner. An appropriate planning process comprises five key stages: rapid assessment and priority setting; outline programme design; immediate action; detailed programme design; and implementation. The assessment should be based on carefully selected data, which are analysed via comparison with suitable minimum objectives. How the intervention should be prioritised is determined through objective ranking of different environmental sanitation sector needs. Next, a programme design outline is produced to identify immediate and longer-term intervention activities and to guarantee that apposite resources are made available. Immediate action is taken to meet acute emergency needs while the detailed programme design takes shape. This entails in-depth consultation with the affected community and comprehensive planning of activities and resource requirements. Implementation can then begin, which should involve pertinent management and monitoring strategies.     

Cracking the code: the genesis, use and future of the Code of Conduct

This paper reflects on the genesis of the Code of Conduct for the International Red Cross and Red Crescent Movement and Non-Governmental Organizations (NGOs) in Disaster Relief, on the tenth anniversary of its adoption. The origins, usage and future of the code are examined with respect to three debates, current at the time of its inception, namely: the debate about the core content of humanitarianism; the debate about coherence and the consensual nature of the humanitarian community; and the debate about the need for, and the ability to demonstrate, accountability. The paper concludes that although the Code of Conduct was very much a product of its time, its content remains relevant today. However, its future application hinges on the capacity of those who purport to follow it to realise true accountability, and on proving that the code, written essentially for natural disasters, is relevant to contemporary complex emergencies.     

Performance of semipermeable membrane devices for sampling of organic contaminants in groundwater

Lipid-filled semipermeable membrane devices (SPMDs) are receiving increasing attention as passive, in situ samplers for the assessment of environmental pollutant exposure. Although SPMDs have been successfully used in a variety of field studies in surface waters, only a few studies have addressed their characteristics as groundwater samplers. In this study, the performance of the SPMDs for monitoring organic contaminants in groundwater was evaluated in a pilot field application in an area severely contaminated by chemical waste, especially by chlorinated hydrocarbons. The spatial distribution of hydrophobic groundwater contaminants was assessed using a combination of passive sampling with SPMDs and non-target semiquantitative GC-MS analysis. More than 100 contaminants were identified and semiquantitatively determined in SPMD samples. Along the 6 field sites under investigation, a large concentration gradient was observed, which confirms a very limited mobility of hydrophobic substances in dissolved form in the aquifer. The in situ extraction potential of the SPMD is limited by groundwater flow, when the exchange volume of well water during an exposure is lower than the SPMD clearance volume for the analytes. This study demonstrates that SPMDs present a useful tool for sampling and analyzing of groundwater polluted with complex mixtures of hydrophobic chemicals and provides guidance for further development of passive sampling technology for groundwater.