Effect of point source removal on mercury bioaccumulation in an industrial pond

A one hectare pond on the headwaters of a mercury-contaminated creek in Oak Ridge, Tennessee acted as a biochemical reactor for the production of methylmercury, increasing waterborne methylmercury concentrations in the stream below the pond discharge. The flow of the creek was diverted around the pond in order to eliminate this input. Waterborne total mercury, methylmercury, and mercury in fish, were monitored in the pond and stream before and after bypass. Waterborne methylmercury concentration in the creek downstream from the pond decreased over 800% following diversion of streamflow around the pond, but mercury in redbreast sunfish in the pond tailwater did not decline similarly. Within the pond, now isolated from fresh waterborne mercury inputs from the stream, methylmercury concentrations in the water column remained similar to levels present before bypass. However, mercury concentrations in sunfish in the pond decreased approximately 75% following bypass, despite the continued presence of highly contaminated sediments (approximately 50 mg Hg/kg dry weight). We concluded that a decrease in the fraction of 'dissolved methylmercury' in the isolated pond relative to pre-bypass conditions explained the decrease in mercury in fish within the pond. That observation also indicates that mercury associated with pond sediments was relatively unavailable for eventual bioaccumulation when compared to 'fresh' mercury contributed by upstream sources. The lack of a post-bypass decrease in mercury concentrations in tailwater fish was also likely to be associated with the particle-associated nature of waterborne methylmercury exported from the pond.     

MAPPING REGIONAL PRECIPITATION INTENSITY DURATION FREQUENCY ESTIMATES1

ABSTRACT: For regional precipitation frequency analyses, methods are needed to spatially interpolate or smooth point intensity duration frequency (IDF) estimates at gage sites for the purposes of visualization and estimation at ungaged sites. In this study to update IDF estimates for Michigan, the assumption is made that for practical purposes, the entire state may be treated as a homogeneous region in which annual maximum precipitation is identically distributed at each site apart from a site‐specific scaling factor, commonly known as the index flood. Several interpolation and smoothing techniques are evaluated for IDF estimation at ungaged sites, including trend surface analysis, thin plate splines, inverse distance weighting, and several kriging algorithms. Ordinary block kriging is recommended as a practical and objective method for smoothing the variability in the index flood values and developing isopluvial maps.     

ENVIRONMENTAL THRESHOLD FUNCTIONS FOR USER ORIENTED RESOURCE PLANNING AND MANAGEMENT1

ABSTRACT: Managers of water related outdoor recreation resources want to provide facilities and recreational opportunities of high quality that are attractive to recreationists. The reported research develops a relevant site quality assessment and measurement procedure called environmental threshold modeling. This modeling procedure is based upon the idea that individuals (i.e., recreationists) have specific, identifiable evaluative criteria which can be expressed as a mathematical function of various site characteristics. The function of interest is called a threshold function because it separates acceptable recreational settings from unacceptable settings. Individual specific threshold functions can be easily aggregated to form a population specific threshold function that estimates the proportion of a population that would find the recreational setting acceptable for some specific activity. Presented in this paper are illustrative calibration results based upon survey data collected from recreational canoeists using the Pine River in Michigan's Manistee National Forest.     

LAKE RESTORATION BY SEDIMENT REMOVAL1

ABSTRACT: Fresh water lake sediment removal is usually undertaken to deepen a lake and increase its volume to enhance fish production, to remove nutrient rich sediment, to remove toxic or hazardous material, or to reduce the abundance of rooted aquatic plants. Review of more than 60 projects and five case histories reveals that the first three objectives are usually met through sediment removal. Dredging to control aquatic plants has not been well documented. Disadvantages of dredging include cost, temporary phosphorus release from sediment, increased phytoplankton productivity, noise, lake drawdown, temporary reduction in benthic fish food organisms, the potential for toxic material release to the overlying water and potential for environmental degradation at the dredged material disposal site. The technique is recommended for deepening and for long range reduction of phosphorus release from sediment. Sediment removal to control toxic materials is possible with minimal environmental impact when proper equipment is used, but it may more than double the cost. Lack of definitive information about rooted plant regrowth rates in dredged areas prohibits explicit recommendations on sediment removal to control plant growth.     

Nitrogen biogeochemistry in the Adirondack Mountains of New York: hardwood ecosystems and associated surface waters

Studies on the nitrogen (N) biogeochemistry in Adirondack northern hardwood ecosystems were summarized. Specific focus was placed on results at the Huntington Forest (HFS), Pancake-Hall Creek (PHC), Woods Lake (WL), Ampersand (AMO), Catlin Lake (CLO) and Hennessy Mountain (HM). Nitrogen deposition generally decreased from west to east in the Adirondacks, and there have been no marked temporal changes in N deposition from 1978 through 1998. Second-growth western sites (WL, PHC) had higher soil solution NO(3-) concentrations and fluxes than the HFS site in the central Adirondacks. Of the two old-growth sites (AMO and CLO), AMO had substantially higher NO(3-) concentrations due to the relative dominance of sugar maple that produced litter with high N mineralization and nitrification rates. The importance of vegetation in affecting N losses was also shown for N-fixing alders in wetlands. The Adirondack Manipulation and Modeling Project (AMMP) included separate experimental N additions of (NH4)2SO4 at WL, PHC and HFS and HNO3 at WL and HFS. Patterns of N loss varied with site and form of N addition and most of the N input was retained. For 16 lake/watersheds no consistent changes in NO(3-) concentrations were found from 1982 to 1997. Simulations suggested that marked NO(3-) loss will only be manifested over extended periods. Studies at the Arbutus Watershed provided information on the role of biogeochemical and hydrological factors in affecting the spatial and temporal patterns of NO(3-) concentrations. The heterogeneous topography in the Adirondacks has generated diverse landscape features and patterns of connectivity that are especially important in regulating the temporal and spatial patterns of NO(3-) concentrations in surface waters.     

Constructing vulnerability: the historical, natural and social generation of flooding in metropolitan Manila

Flooding is not a recent hazard in the Philippines but one that has occurred throughout the recorded history of the archipelago. On the one hand, it is related to a wider global ecological crisis to do with climatic change and rising sea levels but on the other hand, it is also the effect of more localised human activities. A whole range of socio-economic factors such as land use practices, living standards and policy responses are increasingly influencing the frequency of natural hazards such as floods and the corresponding occurrence of disasters. In particular, the reason why flooding has come to pose such a pervasive risk to the residents of metropolitan Manila has its basis in a complex mix of inter-relating factors that emphasise how the nature of vulnerability is constructed through the lack of mutuality between environment and human activity over time. This paper examines three aspects of this flooding: first, the importance of an historical approach in understanding how hazards are generated; second, the degree of interplay between environment and society in creating risk; and third, the manner in which vulnerability is a complex construction.     

Biodegradation by Composting of Surface Modified Starch and PVA Blended Films

Several starch/PVA/glycerol polymer blends were prepared by a solution casting technique and examined for biodegradation by composting over 45 days. Within this time frame, the starch and glycerol components were fully degraded, leaving the PVA component essentially intact. The lowest PVA content film (20%) was selected as a polymer with enough PVA to impart important physical characteristics, but also enough starch to be considered biodegradable. The film characteristics were further improved by surface modification with chitosan. This modification did not interfere with the biodegradation of the starch component. Furthermore, there was slight evidence that PVA biodegradation had been initiated in composted, surface modified starch/PVA blends.     

COLUMBIA RIVER FLOW AND DROUGHT SINCE 17501

ABSTRACT: A network of 32 drought sensitive tree‐ring chronologies is used to reconstruct mean water year flow on the Columbia River at The Dalles, Oregon, since 1750. The reconstruction explains 30 percent of the variability in mean water year (October to September) flow, with a large portion of unexplained variance caused by underestimates of the most severe low flow events. Residual statistics from the tree‐ring reconstruction, as well as an identically specified instrumental reconstruction, exhibit positive trends over time. This finding suggests that the relationship between drought and streamflow has changed over time, supporting results from hydrologic models, which suggest that changes in land cover over the 20th Century have had measurable impacts on runoff production. Low pass filtering the flow record suggests that persistent low flows during the 1840s were probably the most severe of the past 250 years, but that flows during the 1930s were nearly as extreme. The period from 1950 to 1987 is anomalous in the context of this record for having no notable multiyear drought events. A comparison of the flow reconstruction to paleorecords of the Pacific Decadal Oscillation (PDO) and El Nino/Southern Oscillation (ENSO) support a strong 20th Century link between large scale circulation and streamflow, but suggests that this link is very weak prior to 1900.