Radiogenic Lead Isotopes and Time Stratigraphy in the Hudson River, New York

Radionuclide, radiogenic lead isotope and trace metal analyses on fine-grained sediment cores collected along 160 km of the upper and tidal Hudson River were used to examine temporal trends of contaminant loadings and to develop radiogenic lead isotopes both as a stratigraphic tool and as tracers for resolving decadal particle transport fluxes. Very large inputs of Cd, Sb, Pb, and Cr are evident in the sediment record, potentially from a single manufacturing facility. The total range in radiogenic lead isotope ratios observed in well-dated cores collected about 24 km downstream of the plant is large (e.g., maximum difference in ²⁰⁶Pb/²⁰⁷Pb is 10%), characterized by four major shifts occurring in the 1950s, 1960s, 1970s and 1980s. The upper Hudson signals in Cd and radiogenic lead isotopes were still evident in sediments collected 160 km downstream in the tidal Hudson. The large magnitude and abrupt shifts in radiogenic lead isotope ratios as a function of depth provide sensitive temporal constraints that complement information derived from radionuclide analyses to significantly improve the precision of dating assignments. Application of a simple dilution model to data from paired cores suggests much larger sediment inputs in one section of the river than previously reported, suggesting particle influxes to the Hudson have been underestimated.     

Measurements of PCB Fluxes into the Atmosphere from a Site Receiving Stabilized Dredged Material

A 50 ha known contaminated site in Bayonne, New Jersey, U.S.A. is permitted to receive up to 3 × 10⁶ m³ of sediment dredged from navigation channels in the New York/New Jersey Harbor. Much of the sediment is expected to contain low to moderate concentrations of industrial and agricultural chemicals, including Polychlorinated Biphenyls (PCBs). The dredged material brought to the site is stabilized with cement and then placed as a capping and grading layer. The flux of PCBs from drying stabilized dredged material has been estimated from measurements of PCB air concentrations at two heights above the ground along with micrometeorological observations. A statistically significant gradient in PCB concentrations has been consistently measured in the first 3 m above the ground. Observed PCB fluxes were highest over freshly placed stabilized dredged sediment and decreased as it cured. The highest flux observed in this study was 7214 ng/m²/h, but during subsequent sampling intervals at the same site, the flux estimates decreased by an order of magnitude over a 5-day interval.     

Transition to self‐directed work teams: implications of transition time and self‐monitoring for managers' use of influence tactics

In the face of heightened competitive pressures, elevated quality expectations, and calls for worker empowerment, more and more organizations have turned to self‐directed work teams (SDWTs). A review of the literature devoted to SDWTs suggests that managers often struggle with the transition to SDWTs because of the required shift in control to SDWT members. To promote the development of work teams, managers must modify their use of influence tactics in direct response to the control shift. In this study, we explore changes in managers' usage of influence tactics during the transition to SDWTs within a large aluminum manufacturing plant. Analyses of longitudinal data show that despite the new team environment, managers' use of influence tactics was focused at the individual level. We also found that transition time accounts for variance in managers' choices of influence tactics. Finally, an exploratory analysis suggests that high as opposed to low self‐monitoring managers may be more prone to increase their usage of soft influence tactics and decrease their usage of hard influence tactics over the course of the transition; the influence behavior of low self‐monitoring managers remained unchanged. Implications for future research are discussed. Copyright © 2004 John Wiley & Sons, Ltd.     

EFFECTIVENESS OF POLYACRYLAMIDE (PAM) IN IMPROVING RUNOFF WATER QUALITY FROM CONSTRUCTION SITES1

ABSTRACT: Erosion from construction sites significantly affects water quality in receiving streams. A rainfall simulator was used to evaluate the effectiveness of different methods for controlling erosion from construction sites. Erosion control methods investigated included dry and liquid applications of polyacrylamide (PAM), hydroseed, and straw mulch. Fertilizer was also applied to each plot to examine the effectiveness of the methods in reducing nutrient losses in runoff. Runoff samples were analyzed for total suspended solids (TSS), nitrate, total Kjeldahl nitrogen (TKN), ammonium, total phosphorus (TP), and orthophosphate. Among all treatments investigated, straw mulch was the most effective treatment for controlling TSS and nutrient losses during short term and long term simulations. The low liquid PAM (half the recommended PAM) treatment resulted in the highest reduction in runoff, TSS bound nitrogen, and total nitrogen (TN) concentrations and loadings. The study results indicate that a high application rate (twice the recommended rate) of PAM could actually increase runoff and TSS losses. At a low application rate, both liquid and dry PAM were effective in reducing TSS and nutrient losses in runoff. However, application of the liquid form of PAM to construction sites is more practical and perhaps more economical than applying the PAM in the dry form.     

EFFECTS OF WATERSHED REPRESENTATION ON RUNOFF AND SEDIMENT YIELD MODELING1

ABSTRACT: This paper evaluates the effects of watershed geometric representation (i.e., plane and channel representation) on runoff and sediment yield simulations in a semiarid rangeland watershed. A process based, spatially distributed runoff erosion model (KINEROS2) was used to explore four spatial representations of a 4.4 ha experimental watershed. The most complex representation included all 96 channel elements identifiable in the field. The least complex representation contained only five channel elements. It was concluded that oversimplified watershed representations greatly influence runoff and sediment yield simulations by inducing excessive infiltration on hillslopes and distorting runoff patterns and sediment fluxes. Runoff and sediment yield decrease systematically with decreasing complexity in watershed representation. However, less complex representations had less impact on runoff and sediment‐yield simulations for small rainfall events. This study concludes that the selection of the appropriate level of watershed representation can have important theoretical and practical implications on runoff and sediment yield modeling in semiarid environments.     

ENHANCING FECAL COLIFORM TOTAL MAXIMUM DAILY LOAD MODELS THROUGH BACTERIAL SOURCE TRACKING1

ABSTRACT: Surface water impairment by fecal coliform bacteria is a water quality issue of national scope and importance. In Virginia, more than 400 stream and river segments are on the Commonwealth's 2002 303(d) list because of fecal coliform impairment. Total maximum daily loads (TMDLs) will be developed for most of these listed streams and rivers. Information regarding the major fecal coliform sources that impair surface water quality would enhance the development of effective watershed models and improve TMDLs. Bacterial source tracking (BST) is a recently developed technology for identifying the sources of fecal coliform bacteria and it may be helpful in generating improved TMDLs. Bacterial source tracking was performed, watershed models were developed, and TMDLs were prepared for three streams (Accotink Creek, Christians Creek, and Blacks Run) on Virginia's 303(d) list of impaired waters. Quality assurance of the BST work suggests that these data adequately describe the bacteria sources that are impairing these streams. Initial comparison of simulated bacterial sources with the observed BST data indicated that the fecal coliform sources were represented inaccurately in the initial model simulation. Revised model simulations (based on BST data) appeared to provide a better representation of the sources of fecal coliform bacteria in these three streams. The coupled approach of incorporating BST data into the fecal coliform transport model appears to reduce model uncertainty and should result in an improved TMDL.     

REGION,LANDSCAPE, AND SCALE EFFECTS ON LAKE SUPERIOR TRIBUTARY WATER QUALITY1

ABSTRACT: In 1998 and 1999, third‐order watersheds in high mature forest (HMF) and low mature forest (LMF) classes were selected along gradients of watershed storage within each of two hydrogeomorphic regions in the Lake Superior Basin to evaluate threshold effects of storage on hydrologic regimes and watershed exports. Differences were detected between regions (North and South Shore) for particulates, nutrients, and pH, with all but silica values higher for South Shore streams (p < 0.05). Mature forest effects were detected for turbidity, nutrients, color, and alkalinity, with higher values in the LMF watersheds, that is, watersheds with less that 50 percent mature forest cover. Dissolved N, ammonium, N:P, organic carbon, and color increased, while suspended solids, turbidity, and dissolved P decreased as a function of storage. Few two‐way interactions were detected between region and mature forest or watershed storage, thus threshold based classification schemes could be used to extrapolate effects across regions. Both regional differences in water quality and those associated with watershed attributes were more common for third‐order streams in the western Lake Superior drainage basin as compared with second‐order streams examined in an earlier study. Use of ecoregions alone as a basis for setting regional water quality criteria would have led to misinterpretation of reference condition and assessment of impacts in the Northern Lakes and Forest Ecoregion.     

细水雾阻隔火焰热辐射的模拟研究

从热辐射传递方程出发，根据Mie散射理论,考虑雾滴对热辐射的散射和吸收特性，建立细水雾阻隔火焰热辐射的两通量模型，并给出简化算法；同时建立小尺度模拟实验系统，对理论模型进行验证。结果表明，两通量模型较为合理地预测了细水雾对火焰热辐射的衰减作用。在此基础上，应用上述理论模型进一步探讨火焰温度、细水雾特性参数、雾场厚度对阻隔热辐射效率的影响，为细水雾系统的实际工程应用提供了理论和依据。     

平朔矿区生态经济重建的意义及其内容

以处于生产鼎盛期的全国最大露天煤矿之一的平朔矿区为例,针对它与区域生态经济紧密相关的特点,分析它在生态经济方面存在的问题,研究生态经济重建对资源型区域可持续发展的作用,提出生态经济重建的主要内容.