Simple Modeling Tool for Reconstructing Source History Using High Resolution Contaminant Profiles From Low‐k Zones

An innovative but simple analytical modeling tool for reconstructing contaminant concentration versus time trends (i.e., “source history”) for a site using high‐resolution contaminant profiles from low permeability (low‐k) zones was developed and tested. Migration of contaminants into low‐k zones via diffusion (and possibly slow advection) produce concentration versus depth profiles that can be used to understand temporal concentration trends at the interface with overlying transmissive zones, including evidence of attenuation over time due to source decay. A simple transport‐based spreadsheet tool for generating source history estimates fit to the profiles was developed and applied to published soil concentration versus depth data from five distinct areas of four different sites contaminated with chlorinated ethenes. Using the root mean square error as an optimization metric, strong fits between measured and model‐predicted soil data were obtained in the majority of cases using site‐specific values for input parameters. In general, significant improvements could not be obtained by varying these parameters. As a result, the source history estimates generated by the tool were similar to those that had already been generated using more intensive analytical or numerical inverse modeling approaches. This included confirmation of constant source histories at locations where dense nonaqueous‐phase liquid was present (or suspected to be present), and declining source histories for locations where source isolation and/or attenuation had occurred. The advantage of the modeling tool described here is that it provides a simpler yet more dynamic method for understanding source behavior over time than existing approaches. ©2015 Wiley Periodicals, Inc.     

Use of macroinvertebrate assemblages for assessing performance of stabilization ponds treating effluents from sugarcane and molasses processing

Wastewater discharge from sugarcane processing is a significant pollutant of tropical aquatic ecosystems. For most developing countries, monitoring of the level of pollutants is done mostly through chemical analysis, but this does not reflect potential impacts on aquatic assemblages. In addition, laboratory facilities for accurate concentration measurements are often not available for regular monitoring programs. In this study, we investigated the use of benthic macroinvertebrates for biological monitoring in western Kenya. Benthic macroinvertebrates were sampled in stabilization ponds treating wastewater from sugarcane- and molasses-based processing plants to assess their composition and abundance in relation to different concentrations of chemical variables. Optimum concentrations and tolerance values were identified for various taxa, and a biotic index was developed that combined tolerance values (ranked between 0 and 10) for the various macroinvertebrate taxa. A succession in composition and distribution of macroinvertebrate taxa was observed from the inlet to the outlet of the pond systems. Diptera dominated in the first ponds that had high concentrations of chemical oxygen demand (COD), biological oxygen demand (BOD₅), and nutrients, while intolerant Ephemeroptera, Plecoptera, and Trichoptera (EPT) appeared as the concentrations dropped in subsequent ponds. The effluent quality was classified as “good,” “fair,” and “poor,” corresponding with biotic index value ranges 0–3.50, 3.51–6.50, and 6.51–10, respectively. During validation, the index grouped sites with respect to levels of measured environmental variables. The study revealed that the developed biotic index would help in monitoring the quality of sugarcane processing and molasses effluents before release into recipient aquatic ecosystems, replacing the need for costly chemical analyses.     

A sustainable sulfate process to produce TiO2 pigments

Titanium dioxide (TiO₂) is a widely used white pigment. TiO₂ production in 2006 was about 1,400,000 metric tons in the USA. The two major processes to manufacture TiO₂ are the chloride process and the sulfate process. Currently, the TiO₂ industry finds the waste generated in the chloride process less than the waste generated in the sulfate process in its present design, despite generating large quantities of process-related carbon dioxide and carbon monoxide. As a consequence, the sulfate process appears less economical, notably due to the production of green vitriol, FeSO₄·7H₂O, as a major waste. Here, we describe a more sustainable sulfate process based on an earlier study on thermal decomposition of iron(II) sulfates. In the sustainable sulfate process, FeSO₄·7H₂O waste is used for greener production of sulfuric acid, H₂SO₄, used in turn for the digestion of ilmenite. Theoretical and actual yields of waste byproducts per metric ton of TiO₂ produced are used to show the environmental and economic advantages of the sustainable sulfate process.     

URBAN INFLUENCE ON PHOSPHORUS AND SEDIMENT LOADING OF WEST POINT LAKE,GEORGIA1

ABSTRACT: West Point Lake is a 10,360 ha mainstream impoundment of the Chattahoochee River located 95 kilometers downstream of Atlanta, Georgia. Origins and magnitude of external total phosphorus (TP) and total suspended solids (TSS) loads from the West Point Lake basin were estimated over a one-year period. Partitioning the drainage basin allowed the sources of these loads to be determined. The upper subbasin area, from Franklin, Georgia, to the headwaters of the Chattahoochee River, contributed 96 percent of the discharge and 97 percent of the TP and TSS loads into West Point Lake. The lower subbasin area, from Franklin to West Point Lake dam, only contributed 3 percent of the TP and TSS loads. Ninety-one percent and 87 percent of the TP and TSS loads, respectively, from the upper subbasin originated from the Atlanta area. Point sources discharged 70 percent and 3 percent of the upper subbasin TP and TSS loads, respectively. A large portion (66 percent) of the TP from the upper subbasin was in the bioavailable form.     

FACTORS INVOLVED IN EVALUATING GROUND WATER IMPACTS OF DEEP COAL MINE DRAINAGE1

ABSTRACT: The determination of probable ground water impacts of proposed deep coal mining is required as part of permit applications. Impact prediction generally involves well production test analysis and modeling of ground water systems associated with coal seams. Well production tests are often complicated due to the relatively low permeabilities of sandstones and shales of ground water systems. The effects of the release of water stored within finite diameter production wells must be considered. Well storage capacity appreciably affects early well production test time drawdown or time recovery data. Low pumping rates, limited cones of depression, and length of required pumping periods ate important well production test design factors. Coal seam ground water system models are usually multilayered and leaky artesian. Mine drafts partially penetrate the ground water system. Simulation of coal mine drainage often involves the horizontal permeability and storage coefficient of the coal seam zone, vertical permeabilities of sandstones and shales (aquitard) above and below the coal seam zone, and the hydrologic properties of the source bed above the aqultard overlying the coal seam zone. Ground water level declines in both the coal seam zone and source bed near land surface are necessary factors in impact analysis. An example of evaluation studies in southwest Indiana will illustrate factors involved in deep coal mine drainage modeling efforts.     

Monitoring and management of streambank erosion and natural revegetation on the lower Gordon River,Tasmanian Wilderness World Heritage Area,Australia

The wash from high-speed tourist cruise launches causes erosion of the formerly stable banks of the lower Gordon River within the Tasmanian Wilderness World Heritage Area. Speed and access restrictions on the operation of commercial cruise vessels have considerably slowed, but not halted erosion, which continues on the now destabilized banks. To assess the effectiveness of restrictions, bank erosion and natural revegetation are monitored at 48 sites using erosion pins, survey transects, and vegetation quadrats. The subjectively chosen sites are grouped on the basis of geomorphology and bank materials. The mean measured rate of erosion of estuarine banks slowed from 210 to 19 mm/year with the introduction of a 9 knot speed limit. In areas where cruise vessels continue to operate, alluvial banks were eroded at a mean rate of 11 mm/yr during the three-year period of the current management regime. Very similar alluvial banks no longer subject to commercial cruise boat traffic eroded at the slower mean rate of 3 mm/yr. Sandy levee banks have retreated an estimated maximum 10 m during the last 10–15 years. The mean rate of bank retreat slowed from 112 to 13 mm/yr with the exclusion of cruise vessels from the leveed section of the river. Revegetation of the eroded banks is proceeding slowly; however, since the major bank colonizers are very slow growing tree species, it is likely to be decades until revegetation can contribute substantially to bank stability.     

The development of alum rates to enhance the remediation of phosphorus in fluvial systems following manure spills

Following the remediation of animal manure spills that reach surface waters, contaminated streambed sediments are often left in place and become a source for internal phosphorus (P) loading within the stream in subsequent flow. The objective of this study was to develop treatment rates and combinations of alum and CaCO(3) to mitigate P from contaminated sediments of different particle size distributions following a manure spill. Sediment specific alum and CaCO(3) treatment rates were developed based upon the resultant alum treatment ranges established for each sediment type. Clay loam sediments required 54% more alum to mitigate P desorption relative to sediments that contain at least 60% sand. Amending sediments with the highest rates of alum/alum + CaCO(3), resulted in a 98-100% reduction in P desorption and a similar water column pH for all sediments types. Observations from this study demonstrated the effectiveness of alum/alum + CaCO(3) to increase P retention in sediments following a manure spill.     

Consumer attitudes regarding environmentally sustainable wine: an exploratory study of the New Zealand marketplace

Previous research has suggested that consumers are becoming increasingly concerned by the effects of conventional agricultural food production practices on human health and environmental wellbeing. This study sought to understand whether environmentally sustainable practices in the vineyard would equate to advantages in the wine marketplace. Structured questionnaires were used to ascertain the views of wine consumers in Christchurch, New Zealand. The findings of this study indicate that consumers have a strong demand for wine which is produced using “green” production practices. Consumers believe that the quality of sustainable wine will be equal to or better than conventionally produced wine, and they are prepared to pay a higher price for this wine.     

Antimony biomethylation by Scopulariopsis brevicaulis: characterization of intermediates and the methyl donor

The filamentous fungus Scopulariopsis brevicaulis biomethylates inorganic antimony(III) compounds to trimethylstibine, that can be detected in culture headspace gases. Dimethylantimony and trimethylantimony species have been detected in the medium of these cultures, but the origin of these species was controversial. We now show that the dimethylantimony species is a true intermediate on the pathway to trimethylstibine (rather than arising from trimethylstibine oxidation or as an analytical artifact) because no dimethylantimony species are formed on trimethylstibine oxidation, as determined by using HG-GC-AAS. Furthermore, the dimethylantimony and trimethylantimony species can be separated, by using anion exchange chromatography, and so the dimethylantimony species is not an analytical artifact, formed during the hydride generation process. The antimony biomethylation mechanism was further probed by measuring incorporation of the methyl group, from 13CD3-L-methionine and CD3-D-methionine, into methylantimony species and, for comparison, into methylarsenic species. The percentage incorporation of the labeled methyl group into methylarsenic and methylantimony species was not significantly different. The incorporation from 13CD3-L-methionine was 54% and 47% for antimony and arsenic, respectively. The incorporation from CD3-D-methionine was 20% and 16% for antimony and arsenic, respectively. It appears that the biomethylation of arsenic and antimony occur by very similar, perhaps identical, mechanisms.