Principal component analysis of indicator PCB profiles in breast milk from Poland

Principal component analysis (PCA) was applied to a data set containing the levels of indicator polychlorinated biphenyls (PCBs) in human milk of mothers living in the Wielkopolska region, Poland, in order to investigate the information captured in the PCB patterns and to elucidate the relationship between PCB concentrations in milk and donor characteristics. According to the obtained PCA results milk fat content was the most influential factor affecting the PCB levels in milk of the Wielkopolska cohort. The lifestyle data collected from the questionnaire completed by the donors appeared to have no influence on PCB concentrations in breast milk. The score plots revealed the PCB contents of milk were quite low and uniform with a few outliers, without discrimination observed either between the primipareous and secundipareous females or between donors from the urban and rural areas. Comparison of the PCB levels and profiles of human milk from the Wielkopolska region and from various European and Asian locations made by PCA reflected a generally low background exposure and indicated the possible reasons for the outlying of some samples. In order to enhance the chances of observing the relationship between donor habits and PCB levels in breast milk it was suggested that the questionnaire be redesigned to gather information about vegetable product consumption and indoor air exposure.     

Relevant parameters for assessing the environmental impact of some pyridinium, ammonium and pyrrolidinium based ionic liquids

Several physico-chemical properties relevant to determine the environmental impact of ionic liquids - aqueous solubility, octanol/water partition coefficient, chromatographically derived lipophilicity and infinite dilution diffusion coefficients in water - were measured in ionic liquids based on pyridinium, ammonium and pyrrolidinium cations with bis(trifluoromethylsulfonyl)imide anions. The influence of the presence of hydroxyl or ester groups in the physico-chemical properties of these liquids was checked. It appeared that the presence of functional oxygenated moieties reduces the lipophilicity of ionic liquids and so decreases the risk of bioaccumulation in environment.     

Different perceptions of adaptation to climate change: a mental model approach applied to the evidence from expert interviews

We argue that differences in the perception and governance of adaptation to climate change and extreme weather events are related to sets of beliefs and concepts through which people understand the environment and which are used to solve the problems they face (mental models). Using data gathered in 31 in-depth interviews with adaptation experts in Europe, we identify five basic stakeholder groups whose divergent aims and logic can be related to different mental models they use: advocacy groups, administration, politicians, researchers, and media and the public. Each of these groups uses specific interpretations of climate change and specifies how to deal with climate change impacts. We suggest that a deeper understanding and follow-up of the identified mental models might be useful for the design of any stakeholder involvement in future climate impact research processes. It might also foster consensus building about adequate adaptation measures against climate threats in a society.     

Legal requirements and wastewater discharges to Polish water bodies, 1945-2003

The postwar development of water protection legislation and wastewater discharges is poorly known for the Baltic Sea region as a whole. This article presents national efforts to govern wastewater discharges in Poland using legal tools over the twentieth century with an emphasis on the postwar period, 1945-2003. The study also attempts to evaluate how the state authority responded to changing legal demands in terms of urban and industrial wastewater discharges in the postwar period. It outlines the main changes during the socialist regime in Poland and after it regained independence. Also the implications of Poland's integration into the European Union are briefly discussed. Mathematical calculations are used to illustrate some changes in legal requirements over time.     

Preliminary Studies on Converting Agricultural Waste into Biodegradable Plastics,Part I: Corn Distillers’ Dry Grain

Distillers dry grain (DDG) was derivatized either by carboxymethylation, glutaration, maleiation, phthallation, or succination in order to produce anionic materials suitable for complexation with soy protein isolate. Infrared spectroscopy confirmed that derivatization of DDG by all reagents was successful. Blending of derivatized anionic products with soy protein resulted in instant precipitation of gels. The gels were centrifuged, molded, and dried into solid pellets with tensile strengths as high as 1.67MPa, suggesting that these materials could be promising as biodegradable structural materials. Infrared spectroscopy suggested the possibility of complexes forming between soy protein isolate and each of the derivatized DDG samples.     

Predictors of motor vehicle collision injuries among a nationally representative sample of Canadians

OBJECTIVE: The purpose of this study was to examine predictors of subsequent motor vehicle collision injuries, with a particular focus on health-related variables, using the longitudinal dataset from the Canadian National Population Health Survey (NPHS) for the years 1994-2002. METHODS: Multiple logistic regression analysis was used to determine the relations between motor vehicle collision injury and four risk factors: binge drinking, health status, distress, and medication use. Age and sex were included as control variables. The total sample size was 14,529. RESULTS: A higher percentage of females and younger persons reported a motor vehicle collision injury. Binge drinkers, respondents with poor health, respondents with distress, and respondents reported using two or more medications reported a higher percentage of subsequent injuries. Logistic regression analysis found that persons with poorer health status and persons who used more medications had higher odds of motor vehicle injuries. Only one statistically significant interaction effect was found: alcohol bingeing and medication use. CONCLUSIONS: Among a nationally representative sample of Canadians, various demographic and risk factors predict subsequent injuries. Given that this number represents a considerable economic burden, this study underscores the need for continued research and countermeasures on alcohol, drugs, and driving.