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Repeated application may increase rates of pesticide dissipation in soil and reduce persistence. The potential for this to occur was investigated for the fungicide, tebuconazole (alpha-[2-(4-chlorophenyl)ethyl]-alpha-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol), when used for peanut (Arachis hypogaea L.) production. Soil samples were collected from peanut plots after each of four tebuconazole applications at 2-wk intervals. Soil moisture was adjusted to field capacity as necessary and samples were incubated in the laboratory for 63 d at 30 degrees C. Untreated plot samples spiked with the compound served as controls. Results indicated accelerated dissipation in field-treated samples with the time to fifty percent dissipation (DT50) decreasing from 43 to 5 d after three tebuconazole applications. Corresponding increases in rates of accumulation and decay of degradates were also indicated. Best-fit equations (r2 = 0.84-0.98) to dissipation kinetic data combined with estimates of canopy interception rates were used to predict tebuconazole and degradates concentration in soil after each successive application. Predicted concentrations compared with values measured in surface soil samples were from twofold less to twofold greater. Use of kinetic data will likely enhance assessments of treatment efficacy and human and ecological risks from normal agronomic use of tebuconazole on peanut. However, the study indicated that varying soil conditions (in particular, soil temperature and water content) may have an equal or greater impact on field dissipation rate than development of accelerated dissipation. Results emphasize that extension of laboratory-derived kinetic data to field settings should be done with caution. 相似文献
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Evaluating Infiltration Requirements for New Development Using Extreme Storm Transposition: A Case Study from Dane County,WI 下载免费PDF全文
Nicholas G. Hayden Kenneth W. Potter David S. Liebl 《Journal of the American Water Resources Association》2016,52(5):1170-1178
Changes in land use and extreme rainfall trends can lead to increased flood vulnerability in many parts of the world, especially for urbanized watersheds. This study investigates the performance of existing stormwater management strategies for the Upper Yahara watershed in Dane County, WI to determine whether they are adequate to protect urban and suburban development from an extreme rainfall. Using extreme storm transposition, we model the performance of the stormwater infiltration practices required for new development under current county ordinances. We find during extreme rainfall the volume of post‐development runoff from impervious surfaces from a typical site would increase by over 55% over pre‐development conditions. We recommend the ordinance be strengthened to reduce vulnerability to flooding from future urban expansion and the likely increase in the magnitude and frequency of extreme storms. 相似文献
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Konstantinov A Bejan D Bunce NJ Chittim B McCrindle R Potter D Tashiro C 《Chemosphere》2008,72(8):1159-1162
Electrochemical debromination of the commercial decabromodiphenyl ether flame retardant DE-83 in partly aqueous tetrahydrofuran (THF) solution gave lower brominated congeners by sequential loss of bromine atoms. Hydrodebromination was most facile for the most heavily brominated congeners. It involves initial electron transfer and proton transfer from water, rather than hydrogen atom abstraction from THF, as shown by experiments with deuterated water. The product distribution from electrolysis involves preferential loss of bromine meta- and para- to the ether linkage, comparable with the products of metabolism of BDE-209 in various organisms. Significantly, the environmentally relevant congeners BDE-47, BDE-99, and BDE-154 were not major products of debromination of BDE-209 by the electron transfer mechanism. 相似文献
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Structure characterization and thermal stabilities of the isomers of the brominated flame retardant 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane 总被引:1,自引:1,他引:0
Arsenault G Lough A Marvin C McAlees A McCrindle R MacInnis G Pleskach K Potter D Riddell N Sverko E Tittlemier S Tomy G 《Chemosphere》2008,72(8):1163-1170
1,2-Dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH) is used primarily as an additive flame retardant. 1H NMR spectroscopy and an X-ray structure determination have revealed that a technical mixture consists largely of two (of the four possible) diastereomers, rac-(1R,2R)-1,2-dibromo-(4S)-4-((1S)-1,2-dibromoethyl)cyclohexane (alpha-TBECH) and rac-(1R,2R)-1,2-dibromo-(4S)-4-((1R)-1,2-dibromoethyl)cyclohexane (beta-TBECH), in a mole ratio of approximately 1:1. The two other possible isomers, gamma- and delta-TBECH, were not detected in a technical mixture. The TBECH isomers are thermally sensitive and can easily interconvert at temperatures of 125 degrees C. A thermal equilibrium mixture of alpha-, beta-, gamma- and delta-TBECH consists of approximately 33%, 33%, 17% and 17% of these isomers, respectively. Separation of all four TBECH diastereomers, with minimal thermal interconversion of the isomers, was achieved by careful selection of GC-capillary column length and injector temperature. Although technical TBECH does not contain the gamma- and delta-isomers, they may still be relevant environmental contaminants since manufacturing processes utilize thermal processes which may induce their formation. 相似文献
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A stow net (90 m2 opening) was used, at regular intervals between July 1989 and June 1993, to collect fish over ca. 4 h on both the flood and
ebb tides at five sites distributed at regularly spaced distances throughout the Elbe Estuary. Overall, 53.4% of the species
were marine, and some of these were abundant, e.g.Clupea harengus, Pleuronectes flesus, Pomatoschistus minutus, Merlangius merlangus and Sprattus sprattus. However, in terms of number of individuals, such species contributed only 9.1%, compared with 90.0% by anadromous species,
which was predominantly due to exceptionally high catches of Osmerus eperlanus. The ichthyofaunal compositions on the flood and ebb tides were similar, even downstream where salinities change markedly
during each tidal cycle. Although this is probably due in part to groups of fish being swept first upstream on the flood tide
and then back downstream on the ebb tide, several species clearly tended to occupy particular regions of the estuary. Each
year the species composition changed sequentially from the most downstream site (max. salinity=ca. 31.4‰) to the most upstream
site (max. salinity=ca. 1.5‰), mainly as a result of a sequential decline in the number and abundance of marine species and
a progressive increase in the contributions of both anadromous and freshwater species. However, the marine species diagnostic
of differences in the compositions among regions varied between years. Thus, for example, the diagnostic species for the downstream
sites were C. harengus and M. merlangus in 1990/1991 and S. sprattus in 1992/1993, reflecting differences in the recruitment strengths of these marine species in the two years. The ichthyofaunal
composition exhibited pronounced annual cyclical changes in each region and thus occurred irrespective of whether or not the
salinity in a region underwent pronounced changes during the year. This cyclicity was attributable to intra-annual variations
in the times of recruitment of certain marine species, particularly in the downstream region, and to seasonal migrations of
diadromous species into each region, as well as to the movements of freshwater species into the upstream region in winter
and early spring.
Received: 18 November 1999 / Accepted: 25 October 2000 相似文献
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Martin H. David Erhard F. Joeres Eric D. Loucks Kenneth W. Potter Stuart S. Rosenthal 《Journal of the American Water Resources Association》1988,24(1):141-148
ABSTRACT: Water level fluctuations of the Great Lakes often have created regional controversies among the states and Canadian provinces that share this vast resource. Even though the 100-year range of their water levels is only four to five feet, episodes of high and low Great Lakes water levels have been a recurring problem throughout the twentieth century. The possibility of increased diversion and consumptive use has exacerbated the existing conflicts over how to manage this water resource. A research project evaluated the effects of interbasin diversion on the Great Lakes system and on the industries that depend on the maintenance of historical water levels, namely hydropower and commercial navigation. The simulation approach employed in this research and some of the important findings are presented. The approach is similar to that used in recent government studies of Great Lakes water level regulation. Several significant modifications were made specifically addressing the diversion issue. Aggregate annual impacts to hydropower and shipping resulting from a diversion of 10,000 cubic feet per second were found to vary from 60 to 100 million dollars. Increases in impacts as a function of diversion rate are nonlinear for the navigation industry. 相似文献