Assessment of organochlorine pesticide residues in Indian flue-cured tobacco with gas chromatography-single quadrupole mass spectrometer

Presence of pesticide residues in tobacco increases health risk of both active and passive smokers, apart from the imminent potential health problems associated with it. Thus, monitoring of pesticide residue is an important issue in terms of formulating stringent policies, enabling global trade and safeguarding the consumer’s safety. In this study, a gas chromatography-single quadrupole mass spectrometry (GC-MS) method based upon quantifier-qualifier ions (m/z) ratio was employed for detecting and assessing ten organochlorine pesticide residues (α-HCH, β-HCH, γ-HCH, δ-HCH, 2,4-DDT, 4,4-DDT, endrin, α-endosulfan, β-endosulfan and endosulfan sulphate) in 152 flue-cured (FC) tobacco leave samples from two major tobacco growing states, Karnataka and Andhra Pradesh, of India. In the majority of samples, pesticide residue levels were below the limit of quantification (LOQ). In few samples, pesticide residues were detected and they found to comply with the guidance residue levels (GRL) specifications of the Cooperation Center for Scientific Research Relative to Tobacco (CORESTA). Detection of the phase out pesticides like DDT/HCH might be due to transfer of persistent residues from the environmental components to the plant. This is the first report on these ten organochlorine pesticide residues in Indian FC tobacco.     

Selenium in surface and irrigation water in the Kendrick irrigation district, Wyoming

High selenium (Se) concentrations have been found in surface waters in the Kendrick Reclamation Project, Wyoming. Precipitation and irrigation water moving over seleniferous soils are contributing causes, and drought may exacerbate this. This study surveyed Se concentrations and discharges in local surface streams, irrigation drains, and the delivery canal. Sites were sampled monthly and analyzed for Se and total suspended solids (TSS). A completely randomized design with two factors (soil parent material and location, inside or outside irrigation district) was used. Mean Se concentrations were 64 μg L^???1 inside the irrigation district on shale soils, 17 μg L^???1 inside the district off shale soils, 5 μg L^???1 outside the district on shale soils, and 3 μg L^???1 outside the district off shale soils. Correlations between discharge and Se concentrations were generally negative, while correlations between discharge and Se load were generally positive. There was little correlation between load and concentration, and little correlation between TSS and Se. A comparison of Se concentrations in streams and drains showed Se concentrations were significantly higher (p?<?0.001) in streams during the irrigation season, but not in the off-season (p?=?0.515). We conclude that higher discharges decrease Se concentration, but increase load. Conversion from flood to sprinkle irrigation may increase Se concentrations by reducing discharge, but decrease Se loads going into the N. Platte River, and will likely alter the timing and magnitude of flows. Both load and concentration should be considered when implementing Se regulations and standards.     

Habitat monitoring and conservation prioritisation of protected areas in Western Ghats,Kerala, India

Spatially explicit approach is essential to prioritise the ecosystems for biodiversity conservation. In the present study, the conservation status of 20 protected areas of the Western Ghats of Kerala, India, was analysed based on long-term changes in forests (1975–1985–1995–2005–2013), landscape level changes in fragmentation and forest fires (2005–2015). This study has shown that a significant forest loss occurred in protected areas before declaration. Idukki is one of the major protected areas which showed a drastic reduction (18.83%) in its forest cover. During 1985–1995, Periyar tiger reserve had lost 24.19 km² core 3 forest area followed by Peppara (18.54 km²), Parambikulam (17.93 km²), Chimmony (17.71 km²), Peechi-Vazhani (12.31 km²) and Neyyar (11.67 km²). An area of 71.33 km² of the protected area was affected by fires in 2014. Overall protected area-wise decadal analysis indicates Periyar has the highest number of fire incidences followed by Wayanad, Kurinjimala, Silent Valley and Eravikulam. Disturbances in the form of fires and fragmentation still exist and may have significant conservation threat to flora and fauna. Among protected areas, many are having a probability to go under threat or dynamic stage. Chinnar, Thattekkad and Kurinjimala sanctuaries are representing high levels of vulnerability, or they are near to decline stage. Habitat level monitoring of the anthropogenic disturbances can be efficiently useful for the strategic conservation planning. The present study has provided geospatial database on spatial patterns of deforestation, fragmentation and forest fires in protected areas of Kerala. Conservation prioritization approach based on these parameters will be useful for the strategic planning in the state of Kerala.     

Geospatial assessment and monitoring of historical forest cover changes (1920–2012) in Nilgiri Biosphere Reserve,Western Ghats,India

Deforestation in the biosphere reserves, which are key Protected Areas has negative impacts on biodiversity, climate, carbon fluxes and livelihoods. Comprehensive study of deforestation in biosphere reserves is required to assess the impact of the management effectiveness. This article assesses the changes in forest cover in various zones and protected areas of Nilgiri Biosphere Reserve, the first declared biosphere reserve in India which forms part of Western Ghats-a global biodiversity hotspot. In this study, we have mapped the forests from earliest available topographical maps and multi-temporal satellite data spanning from 1920’s to 2012 period. Mapping of spatial extent of forest cover, vegetation types and land cover was carried out using visual interpretation technique. A grid cell of 1 km?×?1 km was generated for time series change analysis to understand the patterns in spatial distribution of forest cover (1920–1973–1989–1999–2006–2012). The total forest area of biosphere reserve was found to be 5,806.5 km² (93.8 % of total geographical area) in 1920. Overall loss of forest cover was estimated as 1,423.6 km² (24.5 % of the total forest) with reference to 1920. Among the six Protected Areas, annual deforestation rate of >0.5 was found in Wayanad wildlife sanctuary during 1920–1973. The deforestation in Nilgiri Biosphere Reserve is mainly attributed to conversion of forests to plantations and agriculture along with submergence due to construction of dams during 1920 to 1989. Grid wise analysis indicates that 851 grids have undergone large-scale negative changes of >75 ha of forest loss during 1920–1973 while, only 15 grids have shown >75 ha loss during 1973–1989. Annual net rate of deforestation for the period of 1920 to 1973 was calculated as 0.5 followed by 0.1 for 1973 to 1989. Our analysis shows that there was large-scale deforestation before the declaration of area as biosphere reserve in 1986; however, the deforestation has drastically reduced after the declaration due to high degree of protection, thus indicating the secure future of reserve in the long term under the current forest management practices. The present work will stand as the most up-to-date assessment on the forest cover of the Nilgiri Biosphere Reserve with immediate applications in monitoring and management of forest biodiversity.     

Biodegradable Composites Containing Chicken Feathers as Matrix and Jute Fibers as Reinforcement

This research demonstrates that chicken feathers can be used as matrix to develop completely biodegradable composites with properties similar to that of composites having polypropylene (PP) as matrix. Feathers are ubiquitous and inexpensive but have limited industrial applications. Feathers have been preferably used for composite applications due to their low density and presence of hollow structures that facilitate sound absorption. However, previous approaches on using feathers for composites have used the whole feather or the feather fractions as reinforcement with synthetic polymers as matrix resulting in partially degradable composites. In addition, the hydrophilicity of the feathers and hydrophobicity of the synthetic matrix results in poor compatibility and therefore less than optimum properties. Although it has been shown that feathers can be made thermoplastic and suitable to develop films and other thermoplastics, there are no reports on using feathers as matrix for composites. In this research, chicken feathers were used as matrix and jute fibers as reinforcement to develop completely biodegradable composites. Tensile, flexural and acoustic properties of the feather-jute composites were compared to PP-jute composites. Utilizing feathers as matrix could enable us to develop low cost 100 % biodegradable composites containing feathers or other biopolymers as the reinforcement.     

Processability and Biodegradability Evaluation of Composites from Poly(butylene succinate) (PBS) Bioplastic and Biofuel Co-products from Ontario

This study investigates the processability and biodegradability of composite bioplastic materials. Biocomposites were processed using twin-screw compounding of the bioplastic poly(butylene succinate) (PBS) with bio-based fillers derived from co-products of biofuel production. An extensive biodegradability evaluation was conducted on each biocomposite material, as well as the base materials, using respirometric testing to analyze the conversion of organic carbon into carbon dioxide. This evaluation revealed that the presence of meal-based fillers in the biocomposites increased the rate of biodegradation of the matrix polymer, degrading at a faster pace than both the pure PBS polymer and the switchgrass (SG) composite. This degradation was further confirmed using FT-IR and thermal analysis of the material structure before and after biodegradation. The increased biodegradation rate is attributed to the high concentration of proteins in the meal-based composites, which enhanced the hydrolytic biodegradation of the material and facilitated micro-organism growth. The SG-based composite degraded slower than the pure polymer due to its lignin content, which degrades via a different mechanism than the polymer, and slowed the biodegradation process.     

Lubrication Oil Reservoir Mist Elimination

Visible emissions from lubrication oil reservoir vents on stationary internal combustion engines, compressors and turbines can be virtually eliminated through the use of properly engineered fiber beds. The fiber bed is more successful than other approaches at eliminating visible emissions because of the inherent low pressure drop, minimal or non-existent maintenance requirements, and proven collection efficiency. In fact, with fiber bed technology, visible emissions can be reduced to virtually zero percent opacity. This paper reviews the applicable emission standards, explores the nature of the lubrication oil vent (LOV) oil mist, describes some of the equipment that has previously been used to control LOV emissions, and details the application of fiber beds for this purpose.     

Immobilization and volume reduction of heavy metals in municipal solid waste fly ash using nano-size calcium and iron-dispersed reagent

This study was conducted to examine the synthesis and application of novel nano-size calcium/iron-based composite material as an immobilizing and separation treatment of the heavy metals in fly ash from municipal solid waste incineration. After grinding with nano-Fe/Ca/CaO and with nano-Fe/Ca/CaO/[PO₄], approximately 30 wt% and 25 wt% of magnetic fraction fly ash were separated. The highest amount of entrapped heavy metals was found in the lowest weight of the magnetically separated fly ash fraction (i.e., 91% in 25% of treated fly ash). Heavy metals in the magnetic or nonmagnetic fly ash fractions were about 98% and 100% immobilized, respectively. Additionally, scanning electron microscopy combined with energy-dispersive X-ray spectrometry (SEM-EDS) observations indicate that the main fraction of enclosed/bound materials on treated fly ash includes Ca/PO₄-associated crystalline complexes. After nano-Fe/Ca/CaO/[PO₄] treatment, the heavy metal concentrations in the fly ash leachate were much lower than the Japan standard regulatory limit for hazardous waste landfills. These results appear to be extremely promising. The addition of a nano-Fe/Ca/CaO/PO₄ mixture with simple grinding technique is potentially applicable for the remediation and volume reduction of fly ash contaminated by heavy metals.

Implications: After grinding with nano-Fe/Ca/CaO and nano-Fe/Ca/CaO/[PO₄], approximately 30 wt% and 25 wt% of magnetic fraction fly ash were separated. The highest amount of entrapped heavy metals was found in the lowest weight of the magnetically separated fly ash fraction (i.e., 91% in 25% of treated fly ash), whereas heavy metals either in the magnetic or nonmagnetic fly ash fractions were about 98% and 100% immobilized. These results appear to be very promising, and the addition of nano-Fe/Ca/CaO/PO₄ mixture with simple grinding technique may be considered potentially applicable for the remediation and volume reduction of contaminated fly ash by heavy metals.     

Trends of surface water quality of the Krishna River,India during the urbanization process

In the present study, Amaravati, the proposed city of India is considered to assess the impacts of urbanization on water quality of the Krishna River in the vicinity. Long-term surface water quality data of various parameters of Krishna River are obtained from Central Water Commission (CWC). Trends of various parameters are analyzed using a modified version of Mann-Kendall (M-K) test; bootstrapped M-K trend test with optional bias corrected pre-whitening and R programming are used affecting water quality prior to and at the commencement of urbanization. During the onset of urbanization, minimum BOD is decreased from 0.49 to 0.2 mg/L, while the maximum BOD is increased by 67.7%. Dissolved oxygen's (DO) minimum value is decreased by 29.33% while maximum DO value is decreased by 4.47% at the beginning of urbanization. During the process of urbanization, total coliform's minimum count is increased to 330 from 2 MPN/100 ml while the maximum count of total coliforms is increased to 16,000 from 2400 MPN/100 ml. Faecal coilform's minimum count is increased from 2 to 80 MPN/100 ml while maximum count is increased to 16,000 from 800 MPN/100 ml during urbanization. It is found that due to urbanization, pH, DO values exceed the allowable limit.     

Real-time wet scavenging of major chemical constituents of aerosols and role of rain intensity in Indian region

Real-time simultaneous studies on chemical characteristics of rainwater and PM₁₀ aerosols were carried out to understand the scavenging of major chemical components in Indian region. The concentrations of Ca²⁺, NH₄⁺, SO₄²⁻ and NO₃⁻ were observed to be lower in the aerosol samples collected during rain as compared to before and after rain events. The most significant reduction was noticed for Ca²⁺ (74%) during rain which showed highest scavenging ratio (SR) and indicated that below-cloud scavenging is an effective removal process for Ca²⁺ in Indian region. Among non-sea salt components, Ca²⁺ had highest SR at Hyderabad indicating typical characteristics of crustal influence as abundance of calcium carbonate in soil dust has been reported in India. However, the levels of these major chemical components gradually got build-up in due course of time. After rain events, the levels of SO₄²⁻ aerosols were noticed to be substantially higher (more than double) within 24 h. In general, scavenging ratios for all components (except Ca²⁺, NH₄⁺ and K⁺) were higher over BOB as compared to Hyderabad. The maximum fall in aerosol levels (BR minus AR) was observed during continuous and low intensity rain events that did not allow building up of aerosol concentrations.