全文获取类型
收费全文 | 2476篇 |
免费 | 72篇 |
国内免费 | 473篇 |
专业分类
安全科学 | 90篇 |
废物处理 | 145篇 |
环保管理 | 228篇 |
综合类 | 733篇 |
基础理论 | 465篇 |
环境理论 | 3篇 |
污染及防治 | 973篇 |
评价与监测 | 196篇 |
社会与环境 | 144篇 |
灾害及防治 | 44篇 |
出版年
2024年 | 4篇 |
2023年 | 24篇 |
2022年 | 82篇 |
2021年 | 75篇 |
2020年 | 46篇 |
2019年 | 70篇 |
2018年 | 54篇 |
2017年 | 78篇 |
2016年 | 122篇 |
2015年 | 156篇 |
2014年 | 181篇 |
2013年 | 264篇 |
2012年 | 201篇 |
2011年 | 189篇 |
2010年 | 143篇 |
2009年 | 135篇 |
2008年 | 189篇 |
2007年 | 150篇 |
2006年 | 138篇 |
2005年 | 99篇 |
2004年 | 92篇 |
2003年 | 81篇 |
2002年 | 87篇 |
2001年 | 55篇 |
2000年 | 35篇 |
1999年 | 43篇 |
1998年 | 35篇 |
1997年 | 28篇 |
1996年 | 32篇 |
1995年 | 23篇 |
1994年 | 21篇 |
1993年 | 19篇 |
1992年 | 15篇 |
1991年 | 13篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1966年 | 1篇 |
1965年 | 1篇 |
1964年 | 1篇 |
1958年 | 1篇 |
1956年 | 1篇 |
排序方式: 共有3021条查询结果,搜索用时 0 毫秒
81.
Romero-Ruiz A Alhama J Blasco J Gómez-Ariza JL López-Barea J 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):1340-1347
Metallothionein (MT) and other biomarker levels were measured in Scrobicularia plana clams to assess pollution of the Guadalquivir Estuary possibly affected by metals released from Aznalcóllar pyrite mine in 1998. After optimizing reagent concentrations for monobromobimane derivatization, MT levels were quantified by reversed-phase high-performance liquid chromatography coupled to fluorescence detection (RP-HPLC-FD) in heated or unheated digestive gland extracts and compared to those obtained by differential pulse polarography (DPP). MT content assayed by RP-HPLC-FD in unheated samples was higher than that obtained by DPP and correlated better with metals and anti-oxidant activities. MT assay by RP-HPLC-FD in unheated extracts would be preferable for assessing metal pollution, due to its greater sensitivity and specificity. In addition to MT induction, glyoxalase II inhibition was well correlated with metal contents. Our results suggest that metals at the estuary do not originate from Aznalcóllar spill, but from those carried along by the river and deposited at its concave bank. 相似文献
82.
Hernández-Allica J Becerril JM Garbisu C 《Environmental pollution (Barking, Essex : 1987)》2008,152(1):32-40
A hydroponic screening method was used to identify high biomass crop plants with the ability to accumulate metals. Highest values of shoot accumulation were found in maize cv. Ranchero, rapeseed cv. Karat, and cardoon cv. Peralta for Pb (18 753 mg kg(-1)), Zn (10 916 mg kg(-1)), and Cd (242 mg kg(-1)), respectively. Subsequently, we tested the potential of these three cultivars for the phytoextraction of a metal spiked compost, finding out that, in cardoon and maize plants, increasing Zn and Cd concentrations led to lower values of root and shoot DW. By contrast, rapeseed shoot growth was not significantly affected by Cd concentration. Finally, a metal polluted soil was used to check these cultivars' phytoextraction capacity. Although the soil was phytotoxic enough to prevent the growth of cardoon and rapeseed plants, maize plants phytoextracted 3.7 mg Zn pot(-1). We concluded that the phytoextraction performance of cultivars varies depending on the screening method used. 相似文献
83.
Manzanilla-Cano JA Barceló-Quintal MH Rendón-Osorio RB Flores-Rodríguez J 《Journal of environmental science and health. Part. B》2007,42(5):515-522
A study was undertaken to determine the transformation kinetic of methylparathion (O, O, -dimethyl O-4 nitrophenylphosphorotioate) in the presence of Fe(III) between pH 2 and 7. The Fe(III) was not electroactive under the conditions used in this study, and polarographic signals were exhibited by methylparathion and main degradation product only. Data suggest that hydrolysis of methylparathion in an acid medium is catalyzed by Fe(III) and the pesticide did not degrade in this medium without this cation. Methylparathion degradation was observed at all the pHs studied and was independent of the predominant chemical form of Fe(III) in the aqueous medium. The reaction was first-order with pH-dependent rate constant (k) values ranging from 3.3 x 10(- 3) h(- 1) to 7.0 x 10(- 3) h(- 1). The k values increased as pH decreased, suggesting that Fe(III) acted as an electrophile in the reaction mechanism. 相似文献
84.
The acid-base properties of humic acids (HAs) and fulvic acids (FAs) isolated from composted sewage sludge (CS), thermally-dried sewage sludge (TS), soils amended with either CS or TS at a rate of 80 t ha(-1)y(-1) for 3y and the corresponding unamended soil were investigated by use of potentiometric titrations. The non-ideal competitive adsorption (NICA)-Donnan model for a bimodal distribution of proton binding sites was fitted to titration data by use of a least-squares minimization method. The main fitting parameters of the NICA-Donnan model obtained for each HA and FA sample included site densities, median affinity constants and widths of affinity distributions for proton binding to low and high affinity sites, which were assumed to be, respectively, carboxylic- and phenolic-type groups. With respect to unamended soil HA and FA, the HAs and FAs from CS, and especially TS, were characterized by smaller acidic functional group contents, larger proton binding affinities of both carboxylic- and phenolic-type groups, and smaller heterogeneity of carboxylic and phenolic-type groups. Amendment with CS or TS led to a decrease of acidic functional group contents and a slight increase of proton binding affinities of carboxylic- and phenolic-type groups of soil HAs and FAs. These effects were more evident in the HA and FA fractions from CS-amended soil than in those from TS-amended soil. 相似文献
85.
Twenty four hours diel cycles of arsenic speciation in Acid Mine Drainage (AMD) due to photooxidation have been reported for the first time. AMD samples were taken during 48 h (31st March and 1st April, 2005) at 6 h intervals from the effluent of a massive abandoned polymetallic sulphide mine of the Iberian Pyrite Belt (Sw Spain). Samples were preserved in situ using cationic exchange prior to analysis by coupled high performance liquid chromatography, hydride generation and atomic fluorescence spectrometry (HPLC-HG-AFS) for arsenic speciation. The results indicated the presence of inorganic arsenic species with daily means of 262mugl(-1) for As(V) and 107 microg l(-1) for As(III). No marked diel trend was observed for As(V). However, a marked diel trend was observed for As(III) in the two studied days, with maximum concentrations during nighttime (141-143 microg l(-1)) and minimum concentrations at daytime (72-77 microg l(-1)). This difference in concentration during daytime and nighttime is ca. 100%. A similar diel cycle was observed for iron. An explanation for the arsenic diel cycles observed is the light induced photooxidation of As(III) and the elimination of As(V) due to its adsorption onto Fe precipitates during the daytime. Furthermore, the diel changes in arsenic speciation emphasize the importance of designing suitable sampling strategies in AMD systems. 相似文献
86.
Scott Newey Paul Davidson Sajid Nazir Gorry Fairhurst Fabio Verdicchio R. Justin Irvine René van der Wal 《Ambio》2015,44(4):624-635
The availability of affordable ‘recreational’ camera traps has dramatically increased over the last decade. We present survey results which show that many conservation practitioners use cheaper ‘recreational’ units for research rather than more expensive ‘professional’ equipment. We present our perspective of using two popular models of ‘recreational’ camera trap for ecological field-based studies. The models used (for >2 years) presented us with a range of practical problems at all stages of their use including deployment, operation, and data management, which collectively crippled data collection and limited opportunities for quantification of key issues arising. Our experiences demonstrate that prospective users need to have a sufficient understanding of the limitations camera trap technology poses, dimensions we communicate here. While the merits of different camera traps will be study specific, the performance of more expensive ‘professional’ models may prove more cost-effective in the long-term when using camera traps for research. 相似文献
87.
Thomas M. Lewinsohn José Luiz Attayde Carlos Roberto Fonseca Gislene Ganade Leonardo Ré Jorge Johannes Kollmann Gerhard E. Overbeck Paulo Inácio Prado Valério D. Pillar Daniela Popp Pedro L. B. da Rocha Wesley Rodrigues Silva Annette Spiekermann Wolfgang W. Weisser 《Ambio》2015,44(2):154-162
Ecological science contributes to solving a broad range of environmental problems. However, lack of ecological literacy in practice often limits application of this knowledge. In this paper, we highlight a critical but often overlooked demand on ecological literacy: to enable professionals of various careers to apply scientific knowledge when faced with environmental problems. Current university courses on ecology often fail to persuade students that ecological science provides important tools for environmental problem solving. We propose problem-based learning to improve the understanding of ecological science and its usefulness for real-world environmental issues that professionals in careers as diverse as engineering, public health, architecture, social sciences, or management will address. Courses should set clear learning objectives for cognitive skills they expect students to acquire. Thus, professionals in different fields will be enabled to improve environmental decision-making processes and to participate effectively in multidisciplinary work groups charged with tackling environmental issues. 相似文献
88.
89.
90.