The Development of a Condenser for Odor Control from Dry Rendering Plants

A new surface condenser and carbon adsorber has been developed which provides arc economic solution to the problem of odours from dry rendering plants.     

Ozone Injury to Pinus Strobus

In a study of the ozone-induced needle blight of eastern white pine in central New York, acute injuries naturally induced on field trees during a year of relatively low ozone concentrations (1 966) were compared with injuries induced during a year of higher concentrations (1967). Injuries were more frequent and severe and were associated with higher mean ozone concentrations in 1967 than in 1966. Characteristic symptoms were induced on foliage of pine branches exposed to controlled doses of ozone as low as 7 ± 1 pphm for four hours or 3 ± 1 pphm for 48 hours. Such doses were equalled or exceeded two and four times, respectively, in the field during the 1 967 season. Ozone sensitivity of pine needle tissue was increased by fumigation in atmospheres containing water mist. High concentrations of ozone (40-60 pphm) caused general injury of foliage of both ozone-susceptible and resistant trees; the symptoms were unlike those found in the field or caused by fumigation with low concentrations of ozone.     

New PbO2, Support for the Measurement of Sulfation

Since 1966, the Division of Laboratories of the Department of Health of the City of Montreal is carrying on measurements of gaseous pollutants. In order to efficiently use the technical staff that our administrators wanted to devote to the fight against air pollution, a new lead dioxide support for the determination of sulfur dioxide has been devised. The preparation of candies according to the standard method requires much time and skill from the operator, whereas the technique that is proposed is rapid, easy, and provides plates of a high degree of uniformity. A technician with little experience can coat a great number of plates per day with no difficulty. N. A. Huey working at the National Center for Air Pollution Control in Cincinnati published in the September 1968 issue of this Journal a new technique which consists of coating the inside of a plastic Petri dish with a PbO² paste. His method also has the above mentioned advantages. The plates that are suggested allow a simplification of the preliminary work for several types of analyses such as gra-vimetry,¹ colorimetry,³ turbidimetry,^4,5 titrimetry,⁶ and nephelemetry.⁸     

Ozone Dosage Response of Ponderosa Pine Seedlings

Photochemical oxidant injury to ponderosa pine (Pinus ponderosa Laws) is a severe problem in the southern California mountains. Three-year-old ponderosa pines fumigated in controlled environment chambers with ozone at 0.15, 0.30, or 0.45 ppm had apparent photosynthesis rates reduced by 10, 70, and 85%, respectively, after 30 days exposure. A fumigation with 0.30 ppm ozone for 33 days depressed the cold perchloric acid extracted polysaccharides of both current and one-year-old needles by 40%. The 80% ethanol soluble sugar concentration of current year, ozone-injured needles increased 16% and that of the one-year-old needles decreased slightly. Both carbohydrate fractions of control trees in carbon-filtered air increased moderately. Higher, endogenous concentrations of ascorbic acid in needles did not protect the tissue from ozone injury. Apparent photosynthesis rate was a sensitive index for ozone dosage response. Needle carbohydrate depletion probably induces premature abscission.     

Determination of the Detailed Hydrocarbon Composition and Potential Atmospheric Reactivity of Full-Range Motor Gasolines

The quantitative data obtained with a capillary GLC method, which is used to determine the individual C₃-C₁₂ hydrocarbons in full-range motor gasolines, have been employed in a computer program to calculate the hydrocarbon composition of the vapor in equilibrium with a gasoline at 100°F, as well as the equilibrium vapor-pressure of the gasoline at that temperature. The method used for computation is similar to that previously described by McEwen, assuming the gasoline to behave as an ideal liquid. Also calculated is the potential atmospheric reactivity of this equilibrium vapor relative to that from other gasolines when specific reactivity weighting factors for the individual hydrocarbons are employed. Calculated total vapor-pressure data agree well with experimental Reid vapor-pressure data obtained for typical premium-grade gasolines. Definite differences were observed in the relative potential atmospheric reactivities calculated at 100°F for the equilibrium vapors from the test gasolines.     

Forecasting COH Levels at Six Outlying Sampling Stations in Allegheny County Using Statistical Correlations Derived from the Downtown Station

Verification of forecasts of COH levels at the Downtown Sampling Station using our objective forecast method developed in conjunction with the Allegheny County Bureau of Air Pollution Control gave excellent results. The next step was to expand the area of forecast coverage.

COH data taken from July 1968 through June 1969 from six sampling stations located roughly in a large concentric arc around the Downtown Station were studied. Three of the stations are located in river valleys near large industrial plants and the other three are located on higher terrain in suburban areas.

COH levels of Low, Moderate, High, and Very High (where Low = 0–0.9, Moderate = 1.0–1.9, High = 2.0–3.0, and Very High = >3.0) were used.

The total number of occurrences of High and Very High COHS at the Downtown Station was 10.7% of the total data sample. This was more than twice the frequency of any of the outlying stations.

An evaluation of the statistical frequencies indicate the Downtown Station can safely be used as a “control station” in forecasting Low or Moderate COH levels for the six surrounding stations. However, the occurrence of High or Very High COH levels at the six outlying stations do not occur with a high enough statistical consistency to be predicted by using the forecast value of the Downtown Station.

The valley stations exhibit the characteristics of separate sub air basins particularly during a period in which morning inversions occur for two or more consecutive days and the average daily wind speed does not exceed 4 m/sec.

The results show it is possible to forecast only Low or Moderate COH levels for each of the six outlying stations by using statistical correlations derived from the Downtown Station. Separate objective forecasts which relate the pollution buildup in each valley sub air basin must be used when High or Very High COHS are forecast at the Downtown Station.     

The Removal of Particulate Matter from Fluid Bed Catalytic Cracking Unit Stack Gases

The application of a high-efficiency centrifugal type of separator to fluid bed catalytic cracking units is described in which most of the catalyst particles often lost to the atmosphere are concentrated into a small part of the stack gas (2%). A further separation can then be made on this small stream by an auxiliary separator which further concentrates the catalyst particle into 0.1% of the initia stream. Performance of the main and auxiliary separators are such as to reduce the loss of catalyst particles in the stack gas from 800 ppm to less than 60 ppm in a typical unit. Large amounts of power can be recovered by application of expander turbines to catalytic cracking plants employing this system of separation.