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141.
Wheeler AJ Xu X Kulka R You H Wallace L Mallach G Van Ryswyk K MacNeill M Kearney J Rasmussen PE Dabek-Zlotorzynska E Wang D Poon R Williams R Stocco C Anastassopoulos A Miller JD Dales R Brook JR 《Journal of the Air & Waste Management Association (1995)》2011,61(3):324-338
The Windsor, Ontario Exposure Assessment Study evaluated the contribution of ambient air pollutants to personal and indoor exposures of adults and asthmatic children living in Windsor, Ontario, Canada. In addition, the role of personal, indoor, and outdoor air pollution exposures upon asthmatic children's respiratory health was assessed. Several active and passive sampling methods were applied, or adapted, for personal, indoor, and outdoor residential monitoring of nitrogen dioxide, volatile organic compounds, particulate matter (PM; PM-2.5 pm [PM2.5] and < or =10 microm [PM10] in aerodynamic diameter), elemental carbon, ultrafine particles, ozone, air exchange rates, allergens in settled dust, and particulate-associated metals. Participants completed five consecutive days of monitoring during the winter and summer of 2005 and 2006. During 2006, in addition to undertaking the air pollution measurements, asthmatic children completed respiratory health measurements (including peak flow meter tests and exhaled breath condensate) and tracked respiratory symptoms in a diary. Extensive quality assurance and quality control steps were implemented, including the collocation of instruments at the National Air Pollution Surveillance site operated by Environment Canada and at the Michigan Department of Environmental Quality site in Allen Park, Detroit, MI. During field sampling, duplicate and blank samples were also completed and these data are reported. In total, 50 adults and 51 asthmatic children were recruited to participate, resulting in 922 participant days of data. When comparing the methods used in the study with standard reference methods, field blanks were low and bias was acceptable, with most methods being within 20% of reference methods. Duplicates were typically within less than 10% of each other, indicating that study results can be used with confidence. This paper covers study design, recruitment, methodology, time activity diary, surveys, and quality assurance and control results for the different methods used. 相似文献
142.
William P. Linak Jeffrey V. Ryan Erica Perry Ron W. Williams David M. DeMarini 《Journal of the Air & Waste Management Association (1995)》2013,63(6):836-846
Chemical and biological analyses were performed to characterize products of Incomplete combustion emitted during the simulated open field burning of agricultural plastic. A small utility shed equipped with an air delivery system was used to simulate pile burning and forced-air-curtain incineration of a nonhalogenated agricultural plastic that reportedly consisted of polyethylene and carbon black. Emissions were analyzed for combustion gases; volatile, semi-volatile, and particulate organics; and toxic and mutagenlc properties. Emission samples, as well as samples of the used (possibly pesticide-contaminated) plastic, were analyzed for the presence of several pesticides to which the plastic may have been exposed. Although a variety of alkanes, alkenes, and aromatic and polycyclic aromatic hydrocarbon (PAH) compounds were identified in the volatile, seml-volatlle, and particulate fractions of these emissions, a substantial fraction of higher molecular weight organic material was not identified. No pesticides were Identified in either combustion emission samples or dlchloromethane washes of the used plastic. When mutagenlcity was evaluated by exposing Salmonella bacteria (Ames assay) to whole vapor and vapor/partlculate emissions, no toxic or mutagenlc effects were observed. However, organic extracts of the particulate samples were moderately mutagenlc. This mutagenlcity compares approximately to that measured from residential wood heating on a revertant per unit heat release basis. Compared to pile burning, forced air slightly decreased the time necessary to burn a charge of plastic. There was not a substantial difference, however, in the variety or concentrations of organic compounds Identified In samples from these two burn conditions. This study highlights the benefits of a combined chemical/biological approach to the characterization of complex, multi-component combustion emissions. These results may not reflect those of other types of plastic that may be used for agricultural purposes, especially those containing halogens. 相似文献
143.
Noortje M. Reeuwijk Antonia Talidda Rainer Malisch Alexander Kotz Angelika Tritscher Heidelore Fiedler Marco J. Zeilmaker Martin Kooijman Koen J.H. Wienk Wim A. Traag Ron L.A.P. Hoogenboom 《Chemosphere》2013,90(5):1678-1685
Geophagy, the practice of consuming clay or soil, is encountered among pregnant women in Africa, Eastern Asia and Latin America, but also in Western societies. However, certain types of clay are known to contain high concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). The aim of this study was to determine the PCDD/F contents of orally consumed clays purchased from Dutch and African markets. Congener patterns were compared with those of pooled human milk samples collected in eight African countries, to investigate a possible relationship with clay consumption. From the Dutch market thirteen clay products were examined, seven of African and six of Suriname origin. From seven African countries, twenty clay products were collected. All 33 clay products were screened with a cell-based bioassay and those showing a high response were analyzed by GC/HRMS. High PCDD/F concentrations were measured in three clay products from the Dutch market, ranging from 66 to 103 pg TEQ g-1, whereas clay products from African countries were from 24 to 75 pg TEQ g-1. Patterns and relatively high concentrations of PCDD/Fs in human milk samples from the Democratic Republic of the Congo and Côte d’Ivoire suggest a relationship with the consumption of contaminated clay. Frequent use of PCDD/F contaminated clay products during pregnancy may result in increased exposure of the mother and subsequently the developing fetus and new-born child. The use of these contaminated clays during pregnancy should be carefully considered or even discouraged. 相似文献
144.
Phung DT Connell D Miller G Hodge M Patel R Cheng R Abeyewardene M Chu C 《Chemosphere》2012,87(4):294-300
Chlorpyrifos is the most common organophosphate insecticide registered for use in Vietnam and is widely used in agriculture, particularly rice farming. However, chlorpyrifos exposure to and adverse effects on farmers has not been evaluated. In this study, biological monitoring of chlorpyrifos exposure in a group of rice farmers was conducted after a typical application event using back-pack spraying.Urine samples (24 h) were collected from the rice farmers before and post insecticide application. Samples were analysed for 3,5,6-trichloropyridinol (TCP), the major urinary metabolite of chlorpyrifos, using an enzymatic pre-treatment before extraction followed by HPLC-MS/MS. Absorbed Daily Dose (ADD) of chlorpyrifos for farmers were then estimated from urinary TCP levels, expressed as μg g−1 creatinine. The analytical method for urinary TCP had a low detection limit (0.6 μg L−1), acceptable recovery values (80-114%), and low relative percentage differences in duplicate and repeated samples.Post-application chlorpyrifos ADD of farmers varied from 0.4 to 94.2 μg kg−1 (body weight) d−1 with a mean of 19.4 μg kg−1 d−1 which was approximately 80-fold higher than the mean baseline exposure level (0.24 μg kg−1 d−1). Hazard Quotients (ratio of the mean ADD for rice farmers to acute oral reference dose) calculated using acute oral reference doses recommended by United States and Australian agencies varied from 2.1 (Australian NRA), 4.2 (US EPA) to 6.9 (ATSDR).Biological monitoring using HPLC-MS/MS analysis of urinary TCP (24 h) was found to be an effective method for measuring chlorpyrifos exposure among farmers. This case study found that Vietnamese rice farmers had relatively high exposures to chlorpyrifos after application, which were likely to have adverse health effects. 相似文献
145.
Bruce E. Young †††† Karen R. Lips † Jamie K. Reaser ‡ Roberto Ibáñez § Antonio W. Salas J. Rogelio Cedeño †† Luis A. Coloma ‡‡ Santiago Ron ‡‡ Enrique La Marca §§ John R. Meyer Antonio Muñoz ††† Federico Bolaños ‡‡‡ Gerardo Chaves ‡‡‡ David Romo§§§ 《Conservation biology》2001,15(5):1213-1223
Abstract: Although dramatic amphibian population declines have been reported worldwide, our understanding of the extent of the declines in Latin America, where amphibian diversity is high, is limited to a few well-documented studies. To better understand the geographic extent of declines, their possible causes, and the measures needed to improve Latin American scientists' ability to research the phenomenon and make effective management recommendations, we convened three regional workshops with 88 Latin American herpetologists and conservationists. Population declines are widespread in Latin America. At least 13 countries have experienced declines, and in 40 cases species are now thought to be extinct or extirpated in a country where they once occurred. Declines or extinctions have affected 30 genera and nine families of amphibians. Most declines have occurred in remote highlands, above 500 m in elevation in Central America and above 1000 m in the Andes. Most documented declines occurred in the 1980s. Of the possible causes studied to date, climate change appears to be important at one site and chytrid fungal disease has been identified at sites in three countries. Although many monitoring studies are currently underway in a variety of habitats, most studies are recent and of short duration. In a signed resolution, workshop participants called for greater collaboration and communication among scientists working in Latin America to understand the geographic extent of population declines and the distribution of possible causal factors. In situ conservation is important to protect habitats, but captive-rearing programs for species subject to imminent extinction are also needed. Better understanding of the taxonomy and natural history of amphibians and more funding for research and monitoring are critical to developing a scientific basis for management action to arrest and reverse population declines. 相似文献
146.
147.
148.
Johanna J. Vollenweider Ron A. Heintz Lawrence Schaufler Robert Bradshaw 《Marine Biology》2011,158(2):413-427
Quantifying the nutritional quality of forage fish is integral for understanding upper trophic levels as forage fish are the
dominant prey for top predator fish, marine mammals, and sea birds. Many existing reports documenting body composition of
forage species are not comparable due to confounding effects. This study systematically assessed the variability in proximate
composition and energy content of 16 forage species in southeastern Alaska (57.2626 N/133.7394 W) between 2001 and 2004. Variation
in energy and lipid contents was related to habitat, epipelagic planktivores varying most, mesopelagics intermediate, and
demersal species relatively invariable. Season was the greatest source of variation as a result of short growing seasons at
high latitude and energy allocation strategies for reproduction and growth. Among species that varied seasonally, energy and
lipid increased over summer and declined during winter. Annual differences in body composition occurred during periods of
peak energy content. Sampling recommendations and guidance for bioenergetics models are provided. 相似文献
149.
Ron Janssen Gustavo Arciniegas Karen A. Alexander 《Journal of Environmental Planning and Management》2015,58(4):719-737
The expansion of offshore renewable energy production, such as wind, wave and tidal energy, is likely to lead to conflict between different users of the sea. Two types of spatial decision support tools were developed to support stakeholder workshops. A value mapping tool combines regional attributes with local knowledge. A negotiation support tool uses these value maps to support stakeholders in finding acceptable locations for tidal energy devices. Interactive value mapping proved useful to address deficiencies in data and to create credibility for these maps. The negotiation tool helped stakeholders in balancing objectives of the various stakeholders. 相似文献
150.
This study analyses disparities in the provision of environmental services in Jerusalem, specifically through the distribution of recycling bins. The allocation of recycling bins in Jerusalem is uneven. Some neighbourhoods have more than their share of infrastructure, while others do not have any recycling bins at all. The spatial distribution of recycling bins throughout the city is analysed across the ethno-religious and socioeconomic divides, enabling us to determine whether the opportunity to recycle is a right or a privilege. The findings demonstrate that the Arab areas are literally not serviced. Ultra-Orthodox (Haredi) Jewish neighbourhoods are discriminated against unless socioeconomic levels and population size are controlled. Therefore, waste-management policies reproduce social inequalities resulting in environmental injustice. Due to the fact that recycling in Jerusalem is voluntary and not obligatory, and that in general the public wants to recycle, the opportunity to recycle is indeed a privilege. 相似文献