Laboratory evaluation of dust-control effectiveness of pen surface treatments for cattle feedlots

Emission of particulate matter (PM) is one of the major air quality concerns for large beef cattle feedlots. Effective treatments on the uncompacted soil and manure mixture of the pen surface may help in reducing PM emission from feedlots. A laboratory apparatus was developed for measuring dust-emission potential of cattle feedlot surfaces as affected by pen surface treatments. The apparatus was equipped with a simulated pen surface, four mock cattle hooves, and samplers for PM with equivalent aerodynamic diam. ≤ 10 μm (PM(10)). The simulated pen surface had a layer of dry, loose feedlot manure with a compacted soil layer underneath. Mock hooves were moved horizontally on the manure layer to simulate horizontal action of cattle hooves on the pen surface. High-volume PM samplers were used to collect emitted dust. Effects of hoof speed, depth of penetration, and surface treatments with independent candidate materials (i.e., sawdust, wheat straw, hay, rubber mulch, and surface water application) on PM(10) emission potential of the manure layer were investigated. Our laboratory study showed PM(10) emission potential increased with increasing depth of penetration and hoof speed. Of the surface treatments evaluated, application of water (6.4 mm) and hay (723 g m(-2)) exhibited the greatest percentage reduction in PM(10) emission potential (69 and 77%, respectively) compared with the untreated manure layer. This study indicated application of hay or other mulch materials on the pen surface might be good alternative methods to control dust emission from cattle feedlots.     

Assessment of carcinogenic heavy metal levels in Brazilian cigarettes

Total mercury (Hg(T)) and bioavailability Hg (Hg(HCl)) concentrations in soil were determined in five districts in Wuhu urban area. Spatial pattern of soil Hg concentration was generated through kriging technology. Results showed that Hg concentration in soil ranged from 0.024 to 2.844 mg kg(?-1) with an average of 0.207 mg kg(?-1). Hg concentration in soil appeared to have a block distribution and decreased from downtown to surrounding district. And Hg concentrations appeared to have a medium scale spatial auto correlation, strongly affected by human activity. The maximal Hg average concentration (0.332 mg kg(?-1)) in soil appeared in Jinghu district, where the high intensity of human activities is. Second highest Hg average concentration (0.263 mg kg(?-1)) in soil appeared in development district, where the intensive industrial activities are. Bioavailability Hg concentration in soil ranged from 2.6 to 4.9 μg kg(?-1) with an average of 3.8 μg kg(?-1), which had a ratio of 0.28~6.44% to total Hg. The ratios of bioavailability Hg to total Hg in vegetable soil were bigger than those of park soil. Correlation analysis showed that total Hg, organic matter, total phosphorus, and bioavailability Hg concentrations in soil were significantly positively correlated. Hg concentration in vegetable ranged from 2.7 to 15.2 μg kg(?-1) with an average of 6.5 μg kg(?-1). Hg concentration in vegetable was positively correlated with Hg(HCl) concentration in soil. According to the calculation on hazard quotient (HQ) for children, inhalation of Hg vapor from soil is the main exposure pathway, in which HQ is 2.517 × 10(?-2), accounting for 80.3% of the four exposure pathways. Hazard index (HI) of the four exposure pathways is lower than the "safe" level of HI = 1; therefore, exposure of soil Hg exhibited little potential health risk to children in Wuhu urban area.     

Combined use of Nassarius reticulatus imposex and statolith age determination for tracking temporal evolution of TBT pollution in the NW Portuguese continental shelf

Spatial and temporal trends of tributyltin (TBT) pollution on the northern continental shelf of Portugal (5-34 m depth) were assessed using Nassarius reticulatus as a bioindicator. Imposex levels were determined in 2006 and 2010, and integrated with age readings from statoliths for a better chronological analysis of the data. Females affected with imposex were detected in 84% of the sites surveyed in 2006, with levels higher than the Ecological Quality Objective (EcoQO) set by the OSPAR Commission for N. reticulatus (VDSI < 0.3) in approximately half of those sites. In 2010, imposex was only detected in 20% of the surveyed sites and, when detected, the VDSI were lower than the EcoQO, except for one location. The comparison between the current results and the levels previously reported for 2004 and 2005 in the same offshore area evidences a clear decline of imposex in 2010 that confirms the efficacy of Regulation (EC) No. 782/2003 and the IMO AFS-Convention (entered into force in 2003 and 2008, respectively). Moreover, the age of the whelks used in the monitoring is estimated in 3-5 years, indicating that actual TBT water contamination in 2010 may in fact be lower than that extrapolated from the imposex levels. We conclude that the legislation was indeed very effective in reducing TBT pollution in the NW Portuguese continental shelf, not only in terms of the magnitude but also in terms of fast field repercussion.     

Comparing the Number of Ozone Exceedances in Different Seasons of the Year in Mexico City

Ozone air pollution is a serious problem in several cities of the world. Hence, to analyse the behaviour of this pollutant is a very important issue. One problem of interest is to study the behaviour of the inter-occurrences times between two ozone exceedances, i.e. between two days in which the pollutant’s measurement surpasses a given threshold. Another interest resides in comparing the behaviour of ozone measurements in different seasons of the year. In this paper we use some Poisson models to analyse this problem. The time interval at which the ozone measurements were taken is split into subintervals corresponding roughly to the seasons of the year. We consider three parametric forms for the mean of the Poisson model, and consequently for the mean of the inter-occurrences times. In each model, the parameters describing its mean are estimated using Bayesian inference via Markov chain Monte Carlo methods. The models are applied to the ozone measurements provided by the Mexico City monitoring network. Theoretical results suggest that an increase has occurred in the mean inter-exceedances times and this is corroborated by the observed data. Differences between the behaviour of the pollutant during different seasons of the year are also detected as well as similarities in the same season in different years. Besides estimating the mean of the Poisson models, inference for the possible presence and location of change-points indicating change of parameters of the model is also performed.     

Chemical and toxicological evaluation along with unprecedented transformation products during photolysis and heterogeneous photocatalysis of chloramphenicol in different aqueous matrices

Environmental Science and Pollution Research - As the presence of antibiotics in environmental waters enhances antimicrobial resistance, photolysis and heterogeneous photocatalysis of...     

Improved 4-nitrophenol removal at Ti/RuO2–Sb2O4–TiO2 laser-made anodes

Environmental Science and Pollution Research - In this study, binary and ternary mixed metal oxide anodes of Ti/RuO2–Sb2O4 and Ti/RuO2–Sb2O4–TiO2 were prepared using two different...     

Natural heavy metal and metalloid concentrations in sediments of the Minho River estuary (Portugal): baseline values for environmental studies

Forty-nine surface sediment samples from the Minho estuary sector between Tui and Caminha were analyzed for grain-size contents, Al, As, Cr, Cu, Hg, Li, Pb, Sn, and Zn concentrations. Selected heavy metal (Cu, Cr, Hg, and Zn) and metalloid (As and Sn) distributions were normalized against Al and Li with the main goal of compensating for natural grain-size variability and to separate natural from anthropogenic contributions, by using a combination of normalization techniques (definition of regional geochemical baselines (RGB) and determination of enrichment factors (EF)). Lead did not reveal a significant relationship with Al and Li. Aluminum explained more variance than Li for As, Cu, Hg, and Zn. Assuming the general non-impacted metal character of the Minho River estuary sediments, RGBs are defined for differentiating between natural and anthropogenic contributions. Based on RGB defined for each heavy metal/metalloid, the degree of enrichment is estimated through the determination of EF. Despite the relatively low total heavy metal and metalloid concentrations, the defined RGB identifies a set of samples characterized by presenting As, Cu, Cr, Hg, and Zn enrichments relatively to expected natural levels. Mercury is the element showing the highest level of enrichment relative to the baseline values being spread through all the study area. Tin present enrichments relatively to Al and or Li always lower than 1.5 suggesting natural contributions.     

The implementation of environmental education to promote sustainability: an overview of the processes and challenges

ABSTRACT

This paper interprets aspects of the implementation of environmental education in a Higher Education Institution, situated in a developing country, to promote Education for Sustainable Development (ESD). The paper will allow educators to categorise the multiplicity of ESD programmes and projects in higher education institutions, determine their limitations and acceptability, and benefit from the theoretical framework of affective learning in designing new ESD interventions. The paper will also provide an overview of the processes required to establish ESD in developing and developed countries. This paper will further help universities to develop a better understanding of how integration of the three components of sustainable development – economic development, social development and environmental protection – can be incorporated in higher education. The paper explores the challenges for planning the implementation of ESD in an education faculty, outlining the potential lessons learned that could assist in improving ESD efforts in Faculties of Education.     

Control of molecular weight distribution of the biopolymer pullulan produced byAureobasidium pullulans

The influence of carbon, nitrogen, and phosphate source, along with concentration, was determined for effect on the weight average molecular weight, molecular weight distribution, and yield of pullulan produced byAureobasidium pullulans NRRL-Y 6220. Batch systems, scale-up batch, and continuous fermentations of 1 L and 10 L were also evaluated as were processing variables, including solvents, and extraction conditions. Products with weight average molecular weight from 1.0 × 10⁵ to 4.0 × 10⁶ were produced in 100-g quantities by varying fermentation conditions such as constituents of the culture medium, pH, and length of incubation. Three sets of culture conditions were defined for the formation of low (<5.0×10⁵), medium (1.0–2.0×10⁶), and high (>2.0×10⁶) weight average molecular weight polymer. These defined molecular weight fractions of pullulan were used in further studies in producing films and fibers.     

Yeasts as a model for assessing the toxicity of the fungicides Penconazol, Cymoxanil and Dichlofluanid

In the present work the sensitivity of yeast strains of Kluyveromyces marxianus, Pichia anomala, Candida utilis, Schizosaccharomyces pombe and Saccharomyces cerevisiae, to the fungicides cymoxanil, penconazol, and dichlofluanid, was evaluated. Dichlofluanid induced the most negative effects, whereas penconazol in general was not very toxic. Overall, our results show that the parameters IC50 for specific respiration rates of C. utilis and S. cerevisiae and C(D) for cell viability of S. cerevisiae can be applied to quantify the toxicity level of the above compounds in yeast. Hence, could be explored as an alternative or at least as a complementary test in toxicity studies and, therefore, its potential for inclusion in a tier testing toxicity test battery merits further research.