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951.
Charles R. Davis 《Journal of the Air & Waste Management Association (1995)》2013,63(12):964-966
In order to determine the influence of SO2 fumigation of soybean plants on yield, a three-year experiment was conducted on 485 plois of soybeans. Single fumigations of S02 were applied at 10 different stages of growth in 1968-69 and 7 stages of growth in 1970. A linear relationship was found to exist beiween the percent of leaf area destroyed and ihe percent crop loss with a significant regression coefficient of b = —0.659, or iwo-thirds of one percent crop loss for each percent of area destroyed. No definite significant stage-of-growth effect was found and no treatment effects were significant for the early stages of growth from the 3-leaf to the 15-leaf stage, nor was there any loss in yield without visible leaf injury. 相似文献
952.
Alice Gitchell R. Simonaitis Julian Heicklen 《Journal of the Air & Waste Management Association (1995)》2013,63(4):357-361
In urban atmospheres hydrocarbons promote the conversion of NO to NO2 under the influence of sunlight, ultimately giving rise to photochemical smog. The conversion results from a long chain process with HO radicals as the chain carrier. If this chain could be interrupted by suitable radical traps, the formation of photochemical smog would be inhibited. In this paper we report the results of studies using phenol, benzaldehyde, and aniline as inhibitors. Mixtures containing 16 mTorr C3H6, 8 mTorr NO, ~85 Torr 02, and the addi tives were irradiated at 25°C. The NO2 pressure was monitored photometrically. In the absence of additive, the NO2 pressure first increases with irradiation time reaching a maximum conversion corresponding to 70% of the NO at 1 2 minutes. As the radiation time is lengthened, the NO2 pressure drops. With the additive present, the formation of NO2 is delayed. The time to reach the maximum percent conversion of NO to N02 becomes 20, 22, 31, and 40 minutes respectively, for 13 mTorr C6H5OH, 2 mTorr C6H5CHO, 8 mTorr C6H5CHO, and 4.1 mTorr C6H5NH2 added. The problems and possibilities of adding inhibitors to the atmosphere to control air pollution are discussed. 相似文献
953.
Timothy M. Gilmore Thomas R. Hanna 《Journal of the Air & Waste Management Association (1995)》2013,63(5):535-539
The so-called “Six Month Study” of the air toxics problem in the United States was initiated in November 1983 by the U.S. Environmental Protection Agency. The study focused on the magnitude, nature, and distribution of the problem—three major issues that were felt to be most useful to policy makers as they attempted to define the scope and direction of a national program for controlling toxic air pollutants. The following paper is based on a draft staff report on the study released for review in September 1984. The report has not been formally released by the U.S. EPA; a final report is due by late spring of 1985. 相似文献
954.
R. A. Stoehr J. P. Pezze 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1119-1122
The evolution of H2S and SO2 from hot blast furnace slags by reaction with H2O has been found to be dependent upon the presence of O2 or H2 in the reaction zone as well as on the temperature. H2 has been found to produce a small increase in H2S and a small decrease in SO2 emission, while O2 has been found to produce a very great inhibiting effect on H2S emission and only a small increase in SO2 emission. The total emission of sulfur bearing gases is much less when H2O + air is blown at the slag than when H2O + Ar is blown at the slag, particularly at 1200°C and above. These effects may be useful in attempts to design systems for slag quenching which will produce less pollution. 相似文献
955.
J. M. Genco H. S. Rosenberg M. Y. Anastas E. C. Rosar J. M. Dulin 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1244-1253
This paper describes some technical and economic aspects of the nahcolite ore injection process for the simultaneous removal of fly ash and sulfur oxides from stack gases. The process is capable of removing greater than 99% of the particulate matter and greater than 70% of the sulfur oxides present in such gases. In the process, nahcolite ore, a naturally occurring material containing 70 to 90% sodium bicarbonate, is ground to 90% passing through —200 mesh screens. Approximately 20% of the ground ore is used to precoat the filter bags in a baghouse filter while the remainder of the material is fed into the flue gas Just ahead of the baghouse. The flue gas is drawn through the baghouse by induced draft fans and sent up the stack. Most of the SO2 and practically all of the fly ash in the flue gas can be removed as the gas passes through the filter bags. The spent nahcolite ore and fly ash are collected and conveyed to waste disposal as landfill, or alternatively processed for insolubilization by coprecipitation prior to landfilling. The technical feasibility of the process has been demonstrated in both bench scale and pilot scale engineering studies. Economic analyses performed for the cases of plants located in the midwest and southwest indicate lower capital costs for the nahcolite injection process when compared to wet scrubbing. On an annual cost basis, the nahcolite ore Injection process is comparable in cost to wet scrubbing for the case of the southwestern power plant, and somewhat more expensive for the case of the midwestern plant. 相似文献
956.
R. D. Steele G. C. Page G. F. Meenaghan 《Journal of the Air & Waste Management Association (1995)》2013,63(6):634-635
Reference methods for the determination of mercury emissions from stationary sources typically include collection of mercury by solutions which are acidic and oxidizing. In the presence of high levels of SO2 the oxidizing capacity of these absorbing solutions will be degraded and the collection efficiency for mercury compromised. This seriously limits the usefulness of the reference methods as they apply to the mining and smelting industries. In the present work peroxide is used to remove SO2 and acidic permanganate is used to collect mercury. At a mean sampling rate of 10 L/min concentrations of at least 12 mg/m3 mercury can be satisfactorily collected in the presence of up to 20,000 ppm SO2. 相似文献
957.
J.I. Accortt A. L Plumley J.R. Martin 《Journal of the Air & Waste Management Association (1995)》2013,63(10):966-969
This paper includes results from pilot plant studies and early field demonstration units and a discussion of the application of the limestone wet scrubbing process to a low sulfur syb-butuminous coal. This latter application required the development of a hybrid two stage scrubber to enable collection of the fine particulate matter as well as removal of a significant amount of the sulfur dioxide. 相似文献
958.
Keshava S. Murthy Harvey S. Rosenberg Richard B. Engdahl 《Journal of the Air & Waste Management Association (1995)》2013,63(9):851-855
Fourteen sulfur and/or sulfuric acid producing regenerate FGD processes were discussed at the 1974 FGD Symposium in Atlanta. During the period elapsed since then, considerable status change has occurred on many of these regenerable processes. Other regenerable processes which were not as well known during 1974 have surfaced in 1975. The problems of obtaining reducing gases (hydrogen sulfide, carbon monoxide, and hydrogen) for the reduction of sulfur dioxide product streams to elemental sulfur have become severe due to shortages of natural gas or other petroleum based feedstock. A new sulfur producing process which employs CO and H2 directly (rather than the H2S required for liquid and vapor base Claus reactions) is gaining attention. This paper discusses briefly: (1) the announced status of the many regenerable FGD processes, (2) the problem of reductant gas supply, and (3) the effect on FGD processes of using coal based reducing gas instead of reformed natural gas. 相似文献
959.
Timothy M. Gilmore Thomas R. Hanna 《Journal of the Air & Waste Management Association (1995)》2013,63(10):965-967
Recent investigations have indicated that ambient air CO measurements may not reflect population exposure to CO. The lack of correlation may be due to improper siting of CO instruments, improper interpretation of air quality data, or both. Studies of population carboxy-hemoglobin levels are evaluated and compared with ambient air data., No significant correlation was found between median population COHb levels and reductions in CO concentrations required to meet ambient air standards when calculations used to estimate reductions were based on the second highest 8 hour average. However, calculated reductions based on annual average concentrations and a trend analysis technique correlated significantly with COHb levels in five cities from which both CAMP and COHb data were available. Studies to determine the nature of the relationship between ambient air CO concentrations and population COHb levels are needed. The differences between the Occupational Safety and Health Act Regulations and the National Ambient Air Standards for carbon monoxide should be scrutinized to determine if a redefinition of the standards or their applicability is warranted. A reevaluation of the controls necessary to make reductions in population COHb burden may be necessary. 相似文献
960.
J. G. Munson Jr. R.E. Lewis G.T. Weber W.E. Brayton 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1059-1062
At the Clairton Coke Works of the United States Steel Corporation (the world’s largest coke plant), with coal charges of about 30,000 net tons per day, a system designated as “stage charging” has been developed for charging coal into the coke oven chamber without emissions to the atmosphere. The principles of the system are based on controlled sequential flow of the coal from the charging hoppers, during which the oven chamber is maintained under a very slight negative pressure condition by use of steam aspiration in the offtakes for on-the-main charging. The techniques are basic but require knowledge of the coal characteristics, adequate and properly maintained aspirating systems, including clean offtake piping, control of coal volume in the individual hoppers, and last, and probably most important, adherence by the operating crew to specific charging and leveling practices. 相似文献