Apparatus for Simultaneous Size-Differentiated Sampling of Optical and Suboptical Aerosols: Application to Analysis of Nitrates and Sulfates

In recent years, the EPA has moved toward a risk assessment/risk reduction framework for making regulatory decisions. The Agency has taken a number of steps to assure the quality and consistency of the risk assessment component of those decisions. The first, and perhaps most important of these steps, is the development of Agency-wide risk assessment guidelines. Five guidelines have been published. They are: carcinogenicity, mutagenicity, developmental toxicity, chemical mixtures, and exposure. The provisions of the five guidelines are discussed in the context of the four components of risk assessment. Other activities designed to assure quality and consistency in risk assessments, reduce uncertainty in risk assessment, ensure a more efficient information exchange about risk and risk assessment, and develop the appropriate oversight mechanisms are also discussed. These include additional guidelines, the Risk Assessment Forum, risk assessment research, the Integrated Risk Information System, the Hazard Assessment Notification System, and the Risk Assessment Council.     

Airborne Emissions of Mercury from Municipal Solid Waste. I: New Measurements from Six Operating Landfills in Florida

Abstract

Mercury-bearing material enters municipal landfills from a wide array of sources, including fluorescent lights, batteries, electrical switches, thermometers, and general waste; however, the fate of mercury (Hg) in landfills has not been widely studied. Using automated flux chambers and downwind atmospheric sampling, we quantified the primary pathways of Hg vapor releases to the atmosphere at six municipal landfill operations in Florida. These pathways included landfill gas (LFG) releases from active vent systems, passive emissions from landfill surface covers, and emissions from daily activities at each working face (WF). We spiked the WF at two sites with known Hg sources; these were readily detected downwind, and were used to test our emission modeling approaches. Gaseous elemental mercury (Hg⁰) was released to the atmosphere at readily detectable rates from all sources measured; rates ranged from ～1–10 ng m^?2 hr^?1 over aged landfill cover, from ～8–20 mg/hr from LFG flares (LFG included Hg⁰ at μg/m³ concentrations), and from ～200–400 mg/hr at the WF. These fluxes exceed our earlier published estimates. Attempts to identify specific Hg sources in excavated and sorted waste indicated few readily identifiable sources; because of effective mixing and diffusion of Hg⁰, the entire waste mass acts as a source. We estimate that atmospheric Hg releases from municipal landfill operations in the state of Florida are on the order of 10–50 kg/yr, substantially larger than our original estimates, but still a small fraction of current overall anthropogenic losses.     

The addition of organic carbon and nitrate affects reactive transport of heavy metals in sandy aquifers

Organic carbon introduction in the soil to initiate remedial measures, nitrate infiltration due to agricultural practices or sulphate intrusion owing to industrial usage can influence the redox conditions and pH, thus affecting the mobility of heavy metals in soil and groundwater. This study reports the fate of Zn and Cd in sandy aquifers under a variety of plausible in-situ redox conditions that were induced by introduction of carbon and various electron acceptors in column experiments. Up to 100% Zn and Cd removal (from the liquid phase) was observed in all the four columns, however the mechanisms were different. Metal removal in column K1 (containing sulphate), was attributed to biological sulphate reduction and subsequent metal precipitation (as sulphides). In the presence of both nitrate and sulphate (K2), the former dominated the process, precipitating the heavy metals as hydroxides and/or carbonates. In the presence of sulphate, nitrate and supplemental iron (Fe(OH)(3)) (K3), metal removal was also due to precipitation as hydroxides and/or carbonates. In abiotic column, K4, (with supplemental iron (Fe(OH)(3)), but no nitrate), cation exchange with soil led to metal removal. The results obtained were modeled using the reactive transport model PHREEQC-2 to elucidate governing processes and to evaluate scenarios of organic carbon, sulphate and nitrate inputs.     

International comparative study of 3R and waste management policy developments

Reduce, reuse, and recycle (3R) policies form the basis of waste management and global warming countermeasures globally, so we conducted a comparative study of 3R and waste management policies in the European Union (EU), USA, Korea, Japan, China, and Vietnam. An international workshop for 3R and waste management policymakers was held in Kyoto, Japan, and a bibliographic survey was also conducted to collect data. 3R policies are clearly given priority in the hierarchy of waste management in every country studied. Thermal recovery, which includes power generation from waste heat and methane gas collected from organic waste, is also a priority; this is consistent with the increased use of countermeasures to reduce greenhouse gas (GHG) emissions. In the EU, waste management is characterized by practical and effective 3R policies through the development of realistic regulations and by the policymakers??desire to simplify management systems. The policy ideal in China, however, is the development of a circular economy that targets reductions in the amount and hazardousness of waste. Limits on the number of final disposal sites, strategies for procuring resources, and GHG emission countermeasures are closely linked with 3R policies, and further development of 3R policies in parallel with such issues is expected.     

Identification of brake wear particles and derivation of a quantitative tracer for brake dust at a major road

Traffic-generated air pollutant emissions can be classified into exhaust and non-exhaust emissions. Increased attention is focussing on non-exhaust emissions as exhaust emissions are progressively limited by regulations. To characterise metal-rich emission from abrasion processes, size-segregated analysis of atmospheric aerosol particles sampled with micro-orifice uniform deposit impactors (MOUDI) in March 2007 in London was performed. The samples were collected at a roadside and a background site and were analysed for Al, Ba, Cu, Fe, Sb, Ti, V, Zn, Ca²⁺, K⁺, Mg²⁺, Na⁺, and NH₄⁺. Most components showed a clear roadside increment, which was evident as a higher mass concentration and a change in the size distribution. In particular, Fe, Cu, Ba, and Sb correlated highly, indicative of a common traffic-related source. Using complementary information on the fleet composition, vehicle number and average speed, the brake wear emission was calculated using the EMEP/CORINAIR emission database. The total PM₁₀ and barium emission of the traffic was determined by ratio to NO_x whose source strength was estimated from published emission factors. Barium was found to comprise 1.1% of brake wear (PM₁₀) particles from the traffic fleet as a whole, allowing its use as a quantitative tracer of brake wear emissions at other traffic-influenced sites.     

Investigating habitat value to inform contaminant remediation options: case study

Habitat valuation methods were implemented to support remedial decisions for aquatic and terrestrial contaminated sites at the East Tennessee Technology Park (ETTP) on the US Department of Energy (DOE) Oak Ridge Reservation in Oak Ridge, TN, USA. The habitat valuation was undertaken for six contaminated sites: Contractor's Spoil Area, K-901-N Disposal Area, K-770 Scrapyard, K-1007-P1 pond, K-901 pond, and the Mitchell Branch stream. Four of these sites are within the industrial use area of ETTP and two are in the Black Oak Ridge Conservation Easement. These sites represent terrestrial and aquatic habitat for vertebrates, terrestrial habitat for plants, and aquatic habitat for benthic invertebrates. Current and potential future, no-action (no remediation) scenarios were evaluated primarily using existing information. Valuation metrics and scoring criteria were developed in a companion paper, this volume. The habitat valuation consists of extensive narratives, as well as scores for aspects of site use value, site rarity, and use value added from spatial context. Metrics for habitat value were expressed with respect to different spatial scales, depending on data availability. There was significant variation in habitat value among the six sites, among measures for different taxa at a single site, between measures of use and rarity at a single site, and among measures for particular taxa at a single site with respect to different spatial scales. Most sites had aspects of low, medium, and high habitat value. Few high scores for current use value were given. These include: wetland plant communities at all aquatic sites, Lepomid sunfish and waterbirds at 1007-P1 pond, and Lepomid sunfish and amphibians at K-901 pond. Aquatic sites create a high-value ecological corridor for waterbirds, and the Contractor's Spoil Area and possibly the K-901-N Disposal Site have areas that are part of a strong terrestrial ecological corridor. The only example of recent observations of rare species at these sites is the gray bat observed at the K-1007-P1 pond. Some aspects of habitat value are expected to improve under no-action scenarios at a few of the sites. Methods are applicable to other contaminated sites where sufficient ecological data are available for the site and region.     

Antioxidant responses of the earthworm Lampito mauritii exposed to Pb and Zn contaminated soil

The aim of this study was to provide fundamental data on the biochemical analysis of antioxidant defences in the earthworm exposed to low levels (75, 150, 300 mg kg(-1) soil) of Pb and Zn. In order to attain this objective, adult Lampito mauritii were exposed to different doses of Pb and Zn separately for 28 days and the concentrations of oxidized and reduced glutathione, activities of glutathione-S-transferase, glutathione peroxidase and glutathione reductase were assessed. Dose-dependent perturbations were observed in the glutathione-glutathione-S-transferase system and other antioxidant enzymes during the early phase of the exposure to Pb. In the Zn exposed earthworm, the glutathione-glutathione-S-transferase system remained stable and the stimulation of glutathione peroxidase and glutathione reductase activities occurred significantly only on day 14 at 300 mg Zn kg(-1). It is concluded that the antioxidants are directly involved in the adaptive response of Lampito mauritii for survival in metal contaminated soil.