TMDL Balance: A Model for Coastal Water Pollutant Loadings

Bacterial contamination accounts for more than 60% of the impairments included on the 2008 Texas 303(d) List. Many of these bacterial impairments are along the Texas Gulf Coast because coastal waters often are regulated for oyster harvesting, which have strict water quality standards. Under the Clean Water Act, each one of these impaired waterbodies requires a total maximum daily load (TMDL) study to be performed. A recent, statewide study recommended the development and application of simple modeling approaches to address the majority of Texas's bacteria TMDLs, including “… simple load duration curve, GIS [geographic information systems], and/or mass balance models.” We developed the TMDL Balance model in response to this recommendation. TMDL Balance is a steady state, mass balance, GIS‐based model for simulating pollutant loads and concentrations in coastal systems. The model uses plug‐flow reactor and continuously‐stirred tank reactor equations to route spatially distributed point and nonpoint source loads through a watershed via overland flow, non‐tidal flow, and tidal flow, decaying the loads via first‐order kinetics. In this paper, we explain the development of the watershed loading portion of the TMDL Balance model, demonstrating the methodology through a case study: computing bacterial loads in the Copano Bay watershed of southeast Texas. The application highlights an example of distributing bacterial sources spatially based on land use data.     

Dissolved organic carbon fluxes under bare soil

The flux of dissolved organic carbon (DOC) in soil facilitates transport of nutrients and contaminants in soil. There is little information on DOC fluxes and the relationship between DOC concentration and water flux in agricultural soils. The DOC fluxes and concentrations were measured during 2.5 yr using 30 automatic equilibrium tension plate lysimeters (AETPLs) at 0.4 m and 30 AETPLs at 1.20-m depth in a bare luvisol, previously used as an arable soil. Average annual DOC fluxes of the 30 AETPLS were 4.9 g C m(-2) y(-1) at 0.4 m and 2.4 g C m(-2) y(-1) at 1.2 m depth. The average leachate DOC concentrations were 17 mg C L(-1) (0.4 m) and 9 mg C L(-1) (1.2 m). The DOC concentrations were unrelated to soil moisture content or average temperature and rarely dropped below 9 mg C L(-1) (0.4 m) and 5 mg C L(-1) (1.2 m). The variability in cumulative DOC fluxes among the plates was positively related to leachate volume and not to average DOC concentrations at both depths. This suggests that water fluxes are the main determinants of spatial variability in DOC fluxes. However, the largest DOC concentrations were inversely proportional to the mean water velocity between succeeding sampling periods, suggesting that the maximal net DOC mobilization rate in the topsoil is limited. Elevated DOC concentrations, up to 90 mg C L(-1), were only observed at low water velocities, reducing the risks of DOC-facilitated transport of contaminants to groundwater. The study emphasizes that water flux and velocity are important parameters for DOC fluxes and concentrations.     

Denitrification in the shallow ground water of a tile-drained, agricultural watershed

Nonpoint-source pollution of surface water by N is considered a major cause of hypoxia. Because Corn Belt watersheds have been identified as major sources of N in the Mississippi River basin, the fate and transport of N from midwestern agricultural watersheds have received considerable interest. The fate and transport of N in the shallow ground water of these watersheds still needs additional research. Our purpose was to estimate denitrification in the shallow ground water of a tile-drained, Corn Belt watershed with fine-grained soils. Over a 3-yr period, N was monitored in the surface and ground water of an agricultural watershed in central Illinois. A significant amount of N was transported past the tile drains and into shallow ground water. The ground water nitrate was isotopically heavier than tile drain nitrate, which can be explained by denitrification in the subsurface. Denitrifying bacteria were found at depths to 10 m throughout the watershed. Laboratory and push-pull tests showed that a significant fraction of nitrate could be denitrified rapidly. We estimated that the N denitrified in shallow ground water was equivalent to 0.3 to 6.4% of the applied N or 9 to 27% of N exported via surface water. These estimates varied by water year and peaked in a year of normal precipitation after 2 yr of below average precipitation. Three years of monitoring data indicate that shallow ground water in watersheds with fine-grained soils may be a significant N sink compared with N exported via surface water.     

A focus group study of factors that promote and constrain the use of satellite-derived fire products by resource managers in southern Africa

Semi-structured focus group interviews were employed to examine factors that affect the likelihood that resource managers in southern Africa will use information on vegetation fires provided by two satellite-derived products: an active fire product and a burned area product. The two products are updated regularly and aim to deliver the state-of-the-art in the global monitoring of fires from satellite remote-sensing. Both products are derived from data transmitted by the Moderate Resolution Imaging Spectroradiometer (MODIS) sensors carried onboard NASA's Aqua and Terra satellites. The active fire product can be accessed for free via the internet and on media by users working anywhere in the world; the burned area product will be accessible in a similar manner in 2006. The MODIS fire products provide systematic, near-global coverage and are freely available; as such, they give resource managers new opportunities to obtain or supplement information they need to manage vegetation fires effectively. However, the availability of these products does not mean that resource managers will use them, and many other factors are involved. To understand factors that affect whether southern African resource managers will use the two products, two focus groups were held with members of the Southern African Fire Network (SAFNet) in Malawi, Africa, August 2004. Analysis of the group discussions reveals a number of factors that influence whether they will use the products. The qualitative, in depth nature of the group discussions revealed 12 main factors that influence product use; not least the low international internet bandwidths for African countries outside of South Africa. Analysis of the group discussions also suggests how the uptake of MODIS fire products by resource managers in southern Africa might be enhanced by affecting specific changes to how MODIS products are packaged and delivered.     

Predicted impact and evaluation of North Carolina's phosphorus indexing tool

Increased concern about potential losses of phosphorus (P) from agricultural fields receiving animal waste has resulted in the implementation of new state and federal regulations related to nutrient management. In response to strengthened nutrient management standards that require consideration of P, North Carolina has developed a site-specific P indexing system called the Phosphorus Loss Assessment Tool (PLAT) to predict relative amounts of potential P loss from agricultural fields. The purpose of this study was to apply the PLAT index on farms throughout North Carolina in an attempt to predict the percentage and types of farms that will be forced to change management practices due to implementation of new regulations. Sites from all 100 counties were sampled, with the number of samples taken from each county depending on the proportion of the state's agricultural land that occurs in that county. Results showed that approximately 8% of producers in the state will be required to apply animal waste or inorganic fertilizer on a P rather than nitrogen basis, with the percentage increasing for farmers who apply animal waste (approximately 27%). The PLAT index predicted the greatest amounts of P loss from sites in the Coastal Plain region of North Carolina and from sites receiving poultry waste. Loss of dissolved P through surface runoff tended to be greater than other loss pathways and presents an area of concern as no best management practices (BMPs) currently exist for the reduction of in-field dissolved P. The PLAT index predicted the areas in the state that are known to be disproportionately vulnerable to P loss due to histories of high P applications, high densities of animal units, or soil type and landscapes that are most susceptible to P loss.     

Empirical relationship between use, area, and ambient air concentration of methyl bromide

Methyl bromide (MeBr) is one of the most widely used soil fumigants. Human exposure to MeBr above threshold values can cause serious health problems. The exposure assessment of MeBr depends on estimation or measurement of its air concentrations. This study proposed a methodology for systematically exploring the empirical relationship between MeBr use intensity and ambient air concentrations. Monitored air concentrations were regressed to MeBr use over various spatiotemporal scales that step-wise increased around the monitoring site and monitoring period. The results showed that the goodness-of-fit varied with the spatiotemporal scale of MeBr use. The best fit was Y = 0.46 + 0.00120X (R2 = 0.95, n = 11), where Y was the 8-wk average ambient air concentration (microg/m3), and X was the weekly average use (kg/wk) over an area of 11.3 x 11.3 km (7 x 7 mi). The model was calibrated with air-monitoring data and use data of 2000, and verified with the same type data of 2001. The model estimated subchronic air concentration with reasonable accuracy.     

Spatial relationships and matrilineal kinship in African savanna elephant (Loxodonta africana) clans

African savanna elephants, Loxodonta africana, live in stable family groups consisting of adult females and their dependent offspring. During the dry season, clans consisting of several family groups typically share a common home range. We compared spatial relationships and mitochondrial DNA (mtDNA) haplotypes among 14 adult female elephants within 3 clans during the dry season in northern Zimbabwe. Spatial relationships were studied by radio-tracking. Home-range similarity was quantified by correlating the estimated utilization distributions of all pairs of elephants. Clans were identified by cluster analysis of the home-range similarity values. All three clans contained at least two of the five mtDNA haplotypes that were found, indicating that clan members are not necessarily matrilineally related. Within clans, home ranges of elephants with the same haplotype were not significantly more similar to each other than those of elephants with different haplotypes. Most elephants within each clan used their shared home ranges independently of each other: the distribution of distances between their positions at any given time did not differ from the distribution expected by chance. However, 8 out of the 26 within-clan pairs exhibited long-term coordination of space use by remaining within known hearing distance of each others low-frequency calls significantly more often than expected by chance. At least four of these coordinated pairs consisted of animals in different family groups. Elephants in three of the four different-family pairs whose movements were coordinated had different haplotypes. Further research is needed to determine the relationship between these coordinated movements and conventionally defined bond-group behavior.Electronic Supplementary Material Supplementary material is available in the online version of this article at .Communicated by C. Nunn     

Ground‐Water Response to Forest Harvest: Implications for Hillslope Stability1

Abstract: Timber harvest may contribute to increased landsliding frequency through increased soil saturation or loss of soil strength as roots decay. This study assessed the effects of forest harvest on hillslope hydrology and linked hydrologic change before and after harvest with a simple model of hillslope stability. Observations of peak water table heights in 56 ground‐water monitoring wells showed that soil saturation levels on hillslopes differed significantly with harvest intensity at one of the two study locations following 25%, 75%, and 100% harvest. Before the forest was cut 100%, the average rainfall needed for 50% saturation of the soil was 54 mm, but after clearcutting soils reached an equivalent saturation with 61% less rainfall (21 mm). Hillslope stability model results indicate that shallow soils at both study locations, with slopes generally < 30° (58%), were not steep enough to be affected significantly by observed increases in saturation. The stability model indicates that with 100% harvest, there is a 7% reduction in the factor of safety for slope gradients of 35° (70%) with soil depths of 1.25 m. Forest managers may be aided by an understanding that variable hydrologic effects may result from similar forest harvests having different landscape position, land contributing area, and soil depths.     

Evaluating the “Catch‐Can” Test for Measuring Lawn Sprinkler Application Rates1

Abstract: The effectiveness of measuring lawn sprinkler application rates using the catch‐can test was evaluated. A survey of sources recommending the catch‐can test for measuring application rates show that catch‐can test procedures differ in the collector type, collector placement, number of collectors, and test duration. Analyses of catch‐can tests were performed to address these procedural differences, with emphasis on the type and number of collectors required to provide a reasonable level of confidence in test results. The accuracy of the catch‐can test generally improves as the number of randomly placed collectors increases. In order to achieve an accuracy of ±25% for 90 out of 100 catch‐can tests, the number of randomly placed collectors required ranged from 6 to over 50 for hand‐move systems, while for in‐ground systems, the number of randomly placed collectors required ranged from 2 to 8, depending on the pressure and percent overlap of the water distribution pattern. As long as a reasonable number of collectors were used when performing a catch‐can test, no consistent differences were observed in catch‐can test results due to type of collectors when using tuna fish cans, soup cans, or coffee mugs.     

Beyond the resource curse? Diamond mining,development and post-conflict reconstruction in Sierra Leone

In recent years, the so-called ‘resource curse’ syndrome has gained increasing currency. Growing evidence suggests that many African countries with significant natural wealth have actually reaped limited rewards, instead experiencing underdevelopment, corruption, political instability, and in some cases, violent conflict. In the small West African state of Sierra Leone, it has been suggested that diamonds played a key role in fuelling a brutal civil war during the 1990s, an issue that has given rise to a burgeoning literature on ‘blood diamonds’. However, as Sierra Leone emerges from a decade of destruction, other research suggests that diamonds could actually provide the impetus for post-war reconstruction. This paper explores the role of alluvial diamond mining in post-conflict Sierra Leone, focusing on two communities in the Eastern Province that were badly affected by the war. Drawing on field-based research conducted between 2002 and 2007, the paper considers the diamond mining situation in the context of broader development strategies in post-conflict reconstruction. It is argued that sustainable development can only be achieved if future policies are based on a detailed understanding of relationships between diamond mining and rural development at local, regional and national levels.