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211.
We examine issues to consider when reframing conservation science and practice in the context of global change. New framings of the links between ecosystems and society are emerging that are changing peoples’ values and expectations of nature, resulting in plural perspectives on conservation. Reframing conservation for global change can thus be regarded as a stage in the evolving relationship between people and nature rather than some recent trend. New models of how conservation links with transformative adaptation include how decision contexts for conservation can be reframed and integrated with an adaptation pathways approach to create new options for global‐change‐ready conservation. New relationships for conservation science and governance include coproduction of knowledge that supports social learning. New processes for implementing adaptation for conservation outcomes include deliberate practices used to develop new strategies, shift world views, work with conflict, address power and intergenerational equity in decisions, and build consciousness and creativity that empower agents to act. We argue that reframing conservation for global change requires scientists and practitioners to implement approaches unconstrained by discipline and sectoral boundaries, geopolitical polarities, or technical problematization. We consider a stronger focus on inclusive creation of knowledge and the interaction of this knowledge with societal values and rules is likely to result in conservation science and practice that meets the challenges of a postnormal world.  相似文献   
212.
213.
Many economic processes are intertwined with landscape change. A large number of individual economic decisions shape the landscape, and in turn the changes in the landscape shape economic decisions. This article describes key research questions about the economics of landscape change and reviews the state of research knowledge. The rich and varied economic–landscape interactions are an active area of research by economists, geographers, and others. Because the interactions are numerous and complex, disentangling the causal relationships in any given landscape system is a formidable research challenge. Limited data with mismatched temporal and spatial scales present further obstacles. Nevertheless, the growing body of economic research on these topics is advancing and shares fundamental challenges, as well as data and methods, with work in other disciplines.  相似文献   
214.
During wintertime measurements in coastal southern California, organonitrate groups accounted for up to 10% of organic mass (OM) in submicron particles. In this study, we report the calibrated absorptivity, the uncertainties in the calibrations, the detection limits for 12 and 24 h ambient sampling, and the multipeak retrieval algorithm for the method developed. Organonitrate groups were observed when both submicron particle-phase nitrate and OM concentrations exceeded 1 μg m?3. These high concentrations were associated with a mixed urban fossil fuel combustion source type that had potential source regions near Riverside and the South Coast Air Basin. The high frequency of these organonitrate observations contrasts with a number of studies of aerosol particles in other regions with more humid conditions, in which organonitrate groups were not detected and submicron sulfate concentrations exceeded those of nitrate. Our results suggest both that organonitrates form and/or exist in significant concentrations during polluted urban conditions and that their lifetime may be limited by hydrolysis in the particle phase.  相似文献   
215.
Crown fire endangers fire fighters and can have severe ecological consequences. Prediction of fire behavior in tree crowns is essential to informed decisions in fire management. Current methods used in fire management do not address variability in crown fuels. New mechanistic physics-based fire models address convective heat transfer with computational fluid dynamics (CFD) and can be used to model fire in heterogeneous crown fuels. However, the potential impacts of variability in crown fuels on fire behavior have not yet been explored. In this study we describe a new model, FUEL3D, which incorporates the pipe model theory (PMT) and a simple 3D recursive branching approach to model the distribution of fuel within individual tree crowns. FUEL3D uses forest inventory data as inputs, and stochastically retains geometric variability observed in field data. We investigate the effects of crown fuel heterogeneity on fire behavior with a CFD fire model by simulating fire under a homogeneous tree crown and a heterogeneous tree crown modeled with FUEL3D, using two different levels of surface fire intensity. Model output is used to estimate the probability of tree mortality, linking fire behavior and fire effects at the scale of an individual tree. We discovered that variability within a tree crown altered the timing, magnitude and dynamics of how fire burned through the crown; effects varied with surface fire intensity. In the lower surface fire intensity case, the heterogeneous tree crown barely ignited and would likely survive, while the homogeneous tree had nearly 80% fuel consumption and an order of magnitude difference in total net radiative heat transfer. In the higher surface fire intensity case, both cases burned readily. Differences for the homogeneous tree between the two surface fire intensity cases were minimal but were dramatic for the heterogeneous tree. These results suggest that heterogeneity within the crown causes more conditional, threshold-like interactions with fire. We conclude with discussion of implications for fire behavior modeling and fire ecology.  相似文献   
216.
ABSTRACT

Ozone (O3) concentrations in the Baltimore-Washington (B-W) metropolitan area frequently exceed the National Ambient Air Quality Standard (NAAQS) in the summer months. The most extreme O3 events occur in multi-day high O3 episodes.1 These events can be regional in scale, with O3 concentrations exceeding the NAAQS at numerous locations along the eastern U.S. seaboard, and are typically associated with slow-moving or stagnant high pressure systems.2-5 In the B-W region, the most extreme events typically occur with surface high pressure overhead or just west of the region and an upper air high-pressure area (ridge) to the west or northwest.1 Besides providing conditions conducive to local O3 production (subsidence and strong low-level inversions, weak horizontal winds, little cloud cover), this weather pattern may also result in transport of O3 and its precursors from heavily industrialized areas west and north of the B-W region. In this paper, observations and back trajectories made during the severe regional O3 event of July 12-15, 1995, are used to confirm the hypothesis that significant regional-scale transport of O3 and its precursors occur during extreme O3 events of the standard type in the B-W area.  相似文献   
217.
A Two-stage Size Selective Inlet for use with hi-vol samplers was designed and tested. The inlet, which operates at a flow rate of 1.13 m3/min, is shown to have a cutpoint of 9.8 μm and a fractionation curve slope of 1.45. The cutpoint is well within the EPA suggested limits of 10 ± 1 μm. Fractionation is not affected by wind speed over the test range of 2-24 km/h.

Re-entrainment or bounce of solid particles is not of consequence. The difference in penetration of 20 μm aerodynamic diameter glass beads and liquid aerosols is less than 1% at all wind speeds.  相似文献   
218.
Since the Bhopal incident, the public has placed pressure on regulatory agencies to set community exposure limits for the dozens of chemicals that may be released by manufacturing facilities. More or less objective limits can be established for the vast majority of these chemicals through the use of risk assessment. However, each step of the risk assessment process (i.e., hazard identification, dose-response assessment, exposure assessment, and risk characterization) contains a number of pitfalls that scientists need to avoid to ensure that valid limits are established. For example, in the hazard identification step there has been little discrimination among animal carcinogens with respect to mechanism of action or the epidemiology experience. In the dose-response portion, rarely is the range of “plausible” estimated risks presented. Physiologically based pharmacokinetic (PB-PK) models should be used to understand the difference between the tissue doses and the administered dose, as well as the difference in target tissue concentrations of the toxicant between rodents and humans. Biologically-based models like the Moolgavkar-Knudson-Venzon (MKV) should be developed and used, when appropriate. The exposure assessment step can be significantly improved by using more sensitive and specific sampling and analytical methods, more accurate exposure parameters, and computer models that can account for complex environmental factors. Whenever possible, model predictions of exposure and uptake should be validated by biological monitoring of exposed persons (urine, blood, adipose) or by field measurements of plants, soil, fish, air, or water. In each portion of an assessment, the weight of evidence approach should be used to identify the most defensible value. In the risk characterization, the best estimate of the potential risk as well as the highest plausible risk should be presented. Future assessments would be much improved if quantitative uncertainty analyses were conducted. Procedures are currently available for making future assessments. By correcting some of these shortcomings in how health risk assessments have been conducted, scientists and risk managers should be better able to identify scientifically appropriate ambient air standards and emission limits.  相似文献   
219.
Abstract: Unlike most North American blackbirds, Rusty Blackbirds (  Euphagus carolensis ) have shown steep population declines. Declines of approximately 90% are indicated for three recent decades from the Breeding Bird Survey, Christmas Bird Counts, and Quebec Checklist Program. Analyses of abundance classifications in bird distribution books and annotated checklists reveal an overlooked but long-term decline dating back to at least the early part of this century. Rusty Blackbirds were described as very common to abundant in 56% of the pre-1920 published accounts, 19% of the 1921–1950 accounts, and only 7% of the post-1950 accounts. Rusty Blackbirds were described as uncommon in none of the pre-1950 accounts, 18% of the 1951–1980 accounts, and 43% of the post-1980 accounts. A similar pattern was found for analyses based on local checklists. Destruction of wooded wetlands on wintering grounds, acid precipitation, and the conversion of boreal forest wetlands could have contributed to these declines. Systematic analysis of regional guides and checklists provides a valuable tool for examining large-scale and long-term population changes in birds.  相似文献   
220.
Abstract

A high pressure liquid chromatographic (HPLC) method is described to determine zearalenone in chicken blood. Samples are extracted with acetonitrile, followed by a hexane cleanup procedure and extracted further with ethyl acetate. The analysis of zearalenone is by HPLC using a reverse phase radial compression separation system, an ultraviolet absorbance detector and a mobile phase of acetonitrile‐water 60:40 (v/v). Recoveries of zearalenone in blood at levels of 50–200 ng/ml are in the range of 66.8–72.6%.  相似文献   
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