Polybrominated diphenyl ethers and their methoxylated metabolites in anchovy (<Emphasis Type="Italic">Coilia</Emphasis> sp.) from the Yangtze River Delta,China

Background, aim, and scope  

Polybrominated diphenyl ethers (PBDEs) and their metabolites are toxic to animals, and concentrations of the PBDEs metabolites can exceed those of the parent materials. But no information was available on concentrations of PBDEs metabolites in the lower Yangtze River in the region around Jiangsu Province of China, which is heavily urbanized and industrialized area. The aims of this study were to determine whether PBDEs and their methoxylated PBDEs (MeO-PBDEs) were accumulated in Coilia sp. in this area and to investigate the potential sources for these two kinds of brominated organic pollutants.     

CeO_2/Al_(0.2)Ti_(0.6)Zr_(0.2)O_(1.9)/ATS复合脱硝催化剂的制备及其抗硫抗水性能研究

将预先经酸处理的铝钛硅(ATS)多相陶瓷片先后负载Al0.2Ti0.6Zr0.2O1.9复合氧化物与CeO2活性组分,制得新型CeO2/Al0.2Ti0.6Zr0.2O1.9/ATS复合脱硝催化剂。运用X射线衍射(XRD)、扫描电镜(SEM)手段对该催化剂进行表征,研究催化剂的晶相、微观形貌。评价了催化剂的脱硝活性,研究了H2O和SO2对其脱硝活性的影响。实验结果表明,CeO2/Al0.2Ti0.6Zr0.2O1.9/ATS具有良好的脱硝活性,高活性温度窗口在100～350℃,当反应温度为250℃时,NO的转化率达98.49%。SO2和H2O在一定程度抑制该催化剂的低温脱硝活性,但随着温度的升高,其脱硝活性逐渐恢复。催化剂中活性组分CeO2具有储硫作用,当有SO2存在时,活性温度窗口向高温区偏移了100℃,在250～400℃时,H2O的存在反而提高了催化剂的脱硝活性。     

废弃中药渣催化热解制取生物油的研究

利用热重分析仪(TGA)对植物类中药渣的热解特性进行了研究,用Coats-Redfern积分法计算了其热解动力学参数,得出中药渣热解反应符合一级反应动力学方程,其活化能较低,为36.0kJ/mol。考察了热解温度对气体、液体、固体产物的影响,在723K时,液体产物生物油产率最高,为39%。以介孔分子筛SBA-15以及分别负载Al、Sn、Ni、Cu和Mg的SBA-15作为催化剂,研究催化热解对气体、液体、固体产率及生物油组分的影响。研究表明,Al-SBA-15的催化效果较好,液体产率最高,为36%;采用元素分析仪和热值测定仪,得到用Al-SBA-15作为催化剂时生物油的氧质量分数最低,低位热值最高。用GC/MS对生物油组分的分析结果表明,添加Al-SBA-15后,热解产物中脂肪族和芳香族化合物增加,而含氧化合物减少。     

Integrated emergy,energy and economic evaluation of rice and vegetable production systems in alluvial paddy fields: Implications for agricultural policy in China

China is the largest rice producing and consuming country in the world, but rice production has given way to the production of vegetables during the past twenty years. The government has been trying to stop this land-use conversion and increase the area in rice-vegetable rotation. Important questions that must be answered to determine what strategy is best for society are, “What is the reason behind this conversion?”; “Which system is more productive and which is more sustainable?”; and “How can economic policy be used to adjust the pattern of farmland use to attain sustainable development?” To answer these questions, a combined evaluation of these agricultural production systems was done using emergy, energy and economic methods. An economic analysis clearly showed that the reason for this conversion was simply that the economic output/input ratio and the benefit density of the vegetable production system were greater than that of rice. However, both energy and emergy evaluations showed that long-term rice was the best choice for sustainable development, followed by rotation systems. The current price of rice is lower than the em-value of rice produced from the long-term rice system, but higher than that of rice produced from the rotation system. Scenario analysis showed that if the government increases the price of rice to the em-value of rice produced from the long-term rice system, US$0.4/kg, and takes the value of soil organic matter into account, the economic output/input ratios of both the rice and rotation systems will be higher than that of the vegetable system. The three methods, energy, emergy and economics, are different but complementary, each revealing a different aspect of the same system. Their combined use shows not only the reasons behind a system’s current state or condition, but also the way to adjust these systems to move toward more sustainable states.     

低碳理念在工业园区规划环评中的应用低碳理念在工业园区规划环评中的应用

工业园区是温室气体排放的重要源头之一,工业园区规划环评应在规划的基础上,探讨如何在评价过程中通过制定合理的对策措施,促进园区低碳发展。本文分析了低碳发展理念纳入工业园区规划环评的工作重点,建议规划环评完善评价内容,在原有评价体系中融入园区温室气体排放特征、设定低碳发展评价指标、优化设计能源结构、构建低碳产业体系、低碳发展替代方案以及碳排放跟踪评价等内容,以达到规划环评指导工业园区按低碳路径发展的目的。     

基于元素毒性赋值的模糊数学环境质量评价

利用模糊数学方法,根据元素毒性的大小进行权重赋值,对成都经济区近地表大气尘进行地球化学环境质量评价。结果显示：不同城市中,成都、乐山、眉山的大气环境质量较好,处于一级清洁级别;眉山、雅安的大气环境质量处于二级安全级别;德阳的大气环境质量已经处于三级警戒级。不同地区中,绵阳和眉山的大气环境质量较好,处于一级清洁级别;德阳和雅安处于二级安全级别,成都和乐山处于三级警戒级.     

上海霾气候数据序列重建及其时空特征

利用上海11个气象站点1960～2008年日均相对湿度、能见度以及天气现象资料,重建了上海近50a霾气候数据序列,并从时间和空间两个方面分析了上海霾日数的气候特征和变化规律。结果表明,上海霾气候数据序列重建值与报表记录值之间变化形态存在着较好的一致性,重建值较记录值偏高。1960～2008年,上海霾日数以9.7d/10a的线性趋势显著增加,2002年以后霾日数总体上呈减少趋势。上海多年平均霾日数以冬季最多而夏季最少。近50a,上海霾日数呈现出西南部最多-市区较多-东北和东南部最少的空间分布,霾日数的空间变化趋势则表现为西南部增加较多而东部增加较少。1981～2008年,上海霾日数在西部和南部都增加,东部则减少。     

基于GIS的景观生态功能指标分析

针对当前我国规划及战略环评指标体系中缺乏直接反映生态功能指标的问题,提出可通过系统研究区域景观生态结构与景观功能变化间的关系,由斑块面积指数计算生物生产力、由景观香农多样性指数和景观香农均匀度指数反映生态质量,以此表征景观生态功能。以地理信息系统（GIS）为平台,提出了利用基于斑块面积而得到的景观要素转移矩阵及基于年鉴统计而得到的景观单位面积生物生产力的转移矩阵来计算生物生产力的方法,并在统计若干研究流域景观格局异质性指数文献的基础上发掘了景观多样性指数、景观均匀度指数与生态质量间的关系。最后,以江苏省沿江地区2000、2004年的数据开展了实例分析,结果表明,提出的生物生产力和生态质量这两个指标确实能反映区域景观功能的变化,在今后的规划和战略环评中具有一定的应用前景.     

资源型城市贵阳市的生态可持续发展研究

生态可持续发展是资源型城市可持续发展的基础。应用生态足迹的方法,对资源型城市贵阳市的生态可持续发展做了定量评估,并分析了影响贵阳市生态可持续发展的社会经济驱动力。贵阳市1999年-2007年间生态足迹从1.447 hm2/cap增长到2.472hm2/cap,而生态承载力从0.551 hm2/cap下降至0.509 hm2/cap,生态足迹远超出生态承载力,生态系统处于不可持续发展状况。但贵阳市生态效率在不断改善,从1999年的0.500万元GDP/hm2生态足迹增长到2007年的0.787万元GDP/hm2生态足迹,生态系统改善仍存在一定契机。人口增加、能耗增加等因素会导致贵阳市生态足迹增加,而增加农作物播种面积则可减少生态足迹。应用生态足迹的方法,有利于分析资源型城市可持续发展的相关问题,最后就如何缓解贵阳市生态系统压力,促进贵阳市生态可持续发展进行了探讨。     

Simulation of biological uptake of uranium and radium in an industrially polluted area

Distribution of ²³⁸U and ²²⁶Ra in soils and plants of an industrially polluted area are considered. The dependence between the biological uptake coefficients (BUCs) for the plant species studied and the radionuclide concentrations in soil can be approximated by a decreasing power function. Species differences in radionuclide uptake are demonstrated.