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971.
Adsorption of Ammonium by Graphene Oxide-Based Composites Prepared by UV Irradiation and Using as Slow-Release Fertilizer 总被引:1,自引:0,他引:1
Chengyi Wu Xu Zhang Cong Li Chao Cheng Yin Zheng 《Journal of Polymers and the Environment》2018,26(12):4311-4320
A novel sodium alginate-grafted poly(acrylic acid)/graphene oxide (NaAlg-g-PAA/GO) composite hydrogel was prepared via ultraviolet irradiation, and characterized by infrared spectroscopy spectrometer. X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. It was employed to adsorb NH4+ from aqueous solution and used as slow-release nitrogen fertilizers (SNFs). Result indicated that the adsorption process for NH4+ reached equilibrium within 50 min, with the adsorption capacity of 6.6 mmol g?1 even if 30 wt% GO was incorporated. The results of adsorption kinetic and isotherm were well described by the pseudo-second-order and Freundlich model. The thermodynamics analysis showed the adsorption process was spontaneous. The study indicated excellent water-holding ratio of soil with 2 wt% SNFs was 81.2%, and nitrogen release was up to 55.1% within 40 days in soil. Overall, NaAlg-g-PAA/GO could be considered as an efficient adsorbent for the recovery of nitrogen with the agronomic reuse as a fertilizer. 相似文献
972.
Summary. Although terrestrial turtles have served as a model for studies of olfactory neurophysiology, little is known about how they
use chemical information in an ecological sense. We tested whether box turtles (Terrapene carolina) use chemical information to distinguish between predatory and nonpredatory mammals. Box turtles in our study exhibited more
escape behavior when exposed to urine from a predator (coyote, Canis latrans) than when exposed to urine from a nonpredator (white-tailed deer, Odocoileus virginianus) or a blank control. Escape behavior is consistent with an antipredator response. In addition, the turtles decreased their
handling time for food when in the presence of urine from either species of mammal in comparison to the blank, indicating
that chemical cues from mammals in general may result in increased vigilance by terrestrial turtles. Examination of a variety
of response variables may be important for adequate assessment of the ecological role of chemosensory behavior. 相似文献
973.
Teru Yamamoto Kazuo Higashino Tamae Abe Takumi Takasuga Hiroaki Takemori Roland Weber Yuko Sasaki 《Environmental science and pollution research international》2018,25(32):31874-31884
Studies on the formation of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) during the electrolysis of sodium chloride solution (brine) using graphite or titanium electrodes were carried out at a laboratory scale. High concentrations of PCDFs but no PCDDs were formed in tests using graphite electrodes. With titanium electrodes, PCDFs were only formed when tar pitch was added and mainly originated from the dibenzofuran present in the tar. For the first time, a detailed assessment of the formation of mono- to octachlorinated PCDD/PCDF from tar pitch was investigated. The assessment included of the chlorination steps proved that PCDFs were formed by successive lateral chlorinated from dibenzofuran to MonoCDFs, DiCDFs, and TriCDFs to form the typical known “chlorine pattern” of TetraCDF to OctaCDF with a dominance of 1,2,7,8- and 2,3,7,8-TetraCDFs, 1,2,3,7,8-PentaCDF, and 1,2,3,4,7,8-HexaCDF as marker congeners. The final homologue distributions depended on reaction time and reaction temperature. In addition, electrolysis with non-chlorinated dibenzo-p-dioxins, dibenzofuran, and biphenyl was carried out. As a result, PCDDs, PCDFs, and PCB were formed at comparable yields. Congener patterns in soil samples from a PCDD/F-contaminated site where chlor-alkali electrolysis had been operated for decades in Japan had identical isomer distribution demonstrating the source and contamination potential and risk of these processes. Therefore, sites where in the past 120 years chlor-alkali electrolysis has been operated or where residues from chlor-alkali production or other chlorine using industries have been disposed should be assessed for their pollution level and exposure relevance. The assessment of total organohalogen content revealed that PCDF is only a small fraction of organohalogens in the contaminated soils. For an appropriate risk assessment, also other chlorinated aromatic compounds such as PCBs or PCNs need to be considered. 相似文献
974.
Renan Felinto dos Santos Heloisa Ramlow Neseli Dolzan Ricardo Antonio Francisco Machado Catia Rosana Lange de Aguiar Cintia Marangoni 《Environmental monitoring and assessment》2018,190(11):693
Textile industry needs to recover and reuse its wastewater as to fulfil the demand of increasingly strict regulations. The characterization of dyeing wastewater samples according to textile fiber and final textile effluent enables the application of different treatment methods. This study aims to characterize dyeing wastewater in black color of polyamide, polyester, and viscose fibers and final textile effluent. Samples were collected and characterized completely for major pollution indicator parameters. Dyeing wastewater of polyester showed higher values for some parameters, e.g., 4994.44% (49,944,400 mg L?1 and 917 NTU) of turbidity and 4100.00% of phenol when compared to dyeing wastewater of other fibers. Other parameters such as pH, alkalinity, color, phosphorus, nitrogen, sulfides, chlorides, oil and grease, dissolved solids, and chemical and biochemical oxygen demand were also assessed. In addition to individual characterization, this study also presents a correlation of the contribution of each parameter to the final textile effluent. Although dyeing wastewater of polyamide contributes the most in terms of quantity for the final effluent, this study revealed that dyeing wastewater of polyester influenced the most on the final composition of the textile wastewater when evaluating color, turbidity, total iron, biochemical oxygen demand, chemical oxygen demand, phenol, mercury, oil and grease, and total phosphorus. The present study is focused on bringing new insights to provide future research with other strategies to improve the treatment of dyeing wastewater. In addition, some suggestions are also given for wastewater treatments according to type of textile fiber. 相似文献
975.
Akshay A. Gowardhan Michael J. Brown Eric R. Pardyjak 《Environmental Fluid Mechanics》2010,10(3):311-328
This work describes and evaluates a pressure solver that has been incorporated into a fast response three-dimensional building-resolving
diagnostic wind modeling system. The solver computes the three-dimensional pressure field around buildings and on exterior
walls in terms of a coefficient of pressure by solving a simplified pressure Poisson equation (that neglects turbulence stresses
in the Navier-Stokes) for incompressible flow. The input to the solver is the three-dimensional mean wind field obtained from
a fast response empirical-diagnostic urban wind model. The present study is an evaluation of the pressure solver using wind-tunnel
data for flow normal to and at a 45° angle to an isolated cubical building. Results for the normal incident wind angle case
indicate that the model satisfactorily reproduces the general spatial patterns and the magnitude of the pressure difference
around much of the cube. Details of the flow field that are not satisfactorily predicted include the spatial distribution
of pressure on the roof and the lower half of the front side of the building and the magnitude along the sidewalls where pressures
are over predicted. The results for the 45° case show reasonable agreement between the model and experiments on the front
and the back walls, but over predict pressures on the leading edge of the rooftop. Regions with poor pressure predictions
appear to be a result of unsatisfactory mean wind modeling. 相似文献
976.
Cynthia A. Ursino María C. De Mársico Mariela Sued Andrés Farall Juan C. Reboreda 《Behavioral ecology and sociobiology》2011,65(12):2279-2286
Obligate avian brood parasites lay their eggs in nests of other species (hosts), which raise parasitic young. Parasitic nestlings
are likely to influence host’s parental behaviours as they typically beg for food more vigorously than young host for a given
hunger level. However, few studies have tested this idea, with conflicting results. These prior studies were largely limited
to biparental hosts, but little is known about the effect of brood parasitism on parental behaviours in hosts that breed cooperatively.
We followed a multimodel approach to examine the effect of brood parasitism on nest provisioning and helper recruitment in
the baywing (Agelaioides badius), a cooperative breeder parasitised by screaming (Molothrus rufoaxillaris) and shiny (Molothrus bonariensis) cowbirds. Multimodel inference results indicated that feeding visits increased with nestling age, cooperative group size
and number of cowbird nestlings in the brood. Brood size had little influence on feeding visits, which further suggests that
baywings adjusted their provisioning effort in response to cowbird parasitism. In addition, nests parasitised artificially
with shiny cowbird eggs or hatchlings recruited more helpers than unmanipulated nests having only host or screaming cowbird
young. Our results provide novel evidence that brood parasitism and cooperative breeding interact in determining the levels
of nest provisioning. 相似文献
977.
The Mytilus species complex consists of three closely related mussel species: Mytilus trossulus, Mytilus edulis, and Mytilus galloprovincialis, which are found globally in temperate intertidal waters. Introduction of one or more of these species have occurred world-wide
via shipping and aquaculture. Stable hybrid zones have developed in areas where these species have come into contact, making
the invasion process complex. On the east coast of Vancouver Island (VI), British Columbia (BC), Canada, the native (M. trossulus) and introduced species (M. edulis and M. galloprovincialis), as well as their hybrid offspring, occur sympatrically. This study used a common environment experiment to quantify growth
and survival differences among native, introduced, and introgressed mussels on VI. Mussels were collected from an area of
known hybridization and reared in cages from May to August 2006. The cages were deployed at a local site as well as a remote
site (approximately 150 km apart), and the mussels were genotyped at two species-specific loci. Growth and survival, as fitness
measures, were monitored: native, introduced, and introgressed individuals were compared between and within sites to determine
whether growth and survival were independent of site and genotype. Overall, mussels reared at Quadra Island performed better
than locally-reared mussels at Ladysmith. Specifically, introgressed mussels reared at Quadra Island performed better than
all genotypes reared at Ladysmith, as well as better than native mussels reared at Quadra Island. Differences in survival
and growth among the native, introduced and introgressed mussels may serve to explain the complex hybridization patterns and
dynamics characteristic of the VI introgression zone. 相似文献
978.
Mark S. Handcock 《Environmental and Ecological Statistics》2007,14(3):267-284
Evolutionary improvements in Geographic Information Systems (GIS) now routinely allow the management and mapping of spatial-temporal
information. In response, the development of statistical models to combine information of different types and spatial support
is of vital importance to environmental science. In this paper we develop a hierarchical spatial statistical model for environmental
indicators of stream and river systems in the United States Mid-Atlantic Region by combining information from separate monitoring
surveys, available contextual information on hydrologic units and remote sensing information. These models are used to estimate
the indicators throughout the riverine system based on information from multiple sources and aggregate scales. The analysis
is based on information underlying the Landscape Atlas of the mid-Atlantic region produced by the US Environmental Monitoring
and Assessment Program (EMAP). We also combine information from two overlapping separate monitoring surveys, the EMAP Stream
and River Survey and the Maryland Biological Streams Survey. We present a general framework for comparative distributional
analysis based on the concept of a relative spatial distribution. As an application, the spatial model is used to predict
spatial distributions and relative spatial distributions for a watershed. 相似文献
979.
An active ethically conscious consumer has been acclaimed as the new hero and hope for an ethically improved capitalism. Through
consumers’ “voting” at the checkout, corporations are supposed to be held accountable for their conduct. In the literature
on political consumerism, this has mainly been approached as political participation and governance. In this article, we do
a critical review of this literature. We do so by questioning the existence of what we call a “generic active consumer model.”
At the core of this position, there is a belief that the active consumer is a universal entity, available across nations and
time. Instead we call for an approach that takes accord of the ways consumers and consumer roles are framed in interactive
processes in markets, governance structures, and everyday life. Consumers in different countries assess their responsibilities
and their powers as consumers differently due to different institutionalizations within distinctive contexts. We also must take into account how the inertia
of ordinary consumption and the moral complexities of everyday life restrict the adoption of an active consumerist role. Hence,
the debate on political consumerism should make for a more realistic notion of ethical consumer-sovereignty and its role in
improving the workings of capitalism. In our view, these findings have severe implications for understanding both theories
of political consumption and the dynamics of political consumption per se. 相似文献
980.
Current political conditions, primarily budgetary uncertainty, and the related reluctance to make funding commitments for
future generations, have raised questions about the costs of conservation and environmental protection that have not previously
been asked. As Federal investments are scrutinized and budgets become ever more constrained, the costs associated with environmental
requirements could begin to be of greater importance and to influence decisions on Federal projects. In response to concerns
about the U.S. Army Corps of Engineers (Corps) spending under the Endangered Species Act (P.L. 93-205) (ESA), a limited investigation
was performed to determine the accuracy of reported Corps expenditures. The investigation showed that, for particular groups
of species, actual conservation costs for threatened and endangered species may be twice the amounts previously reported in
the annual ESA expenditure reporting to the U.S. Fish and Wildlife Service. In light of this finding, the Corps has sought
a means to provide more accurate and consistent reporting of expenditures for addressing threatened and endangered species.
A Species Costs Template (template) has been developed to identify the types and magnitude of costs related to the ESA and
to counteract the impediments (legal, institutional, and practical) to underreporting costs. The template will be used by
the Corps for reporting ESA costs beginning with Fiscal Year 2005 (FY05) (reported in January 2006). Five broad categories
of expenditures (effects determination costs, ESA protection and conservation costs, equipment costs, opportunity costs, and
other species costs) are identified by the template. 相似文献