Use of different soft tissues of Perna viridis a s biomonitors of bioavailability and contamination by heavy metals (Cd,Cu, Fe,Pb, Ni,and Zn) in a semi-enclosed intertidal water,the Johore Straits

Green-lipped mussels, Perna viridis, were collected from the eastern and western parts of the Johore Straits in September 2004 and January 2005. Based on the heavy metal concentrations in the different soft tissues (gonad, foot, mantle, gills, muscle, and remaining soft tissues) of these mussel samples, the eastern part of the Johore Straits (which is divided into two portions by a causeway), recorded higher levels of bioavailability and contamination by Cd, Cu, Fe, Ni, and Zn when compared to the western part, while Kg. Pasir Puteh in the eastern part was found to record the highest bioavailability and contamination by heavy metals. The use of different soft tissues of P. viridis as biomonitors of bioavailability and contamination by Cd, Cu, Fe, Pb, Ni, and Zn in the semi-enclosed Johore Straits is proposed, since erroneous results due to spawning and the problem of defecation before dissection could be overcome. Hence, a more accurate interpretation of the bioavailability and contamination by heavy metals in coastal waters could be obtained. To our knowledge, this is the most detailed study on the bioavailability and contamination of heavy metals in the Johore Straits on the Malaysian side of the waterway carried out by using the different soft tissues and metal distribution based on the Mussel Watch approach.     

Improved desalination by polyamide membranes containing hydrophilic glutamine and glycine

Environmental Chemistry Letters - Water desalination and recycling of wastewater is a key challenge to meet water shortage issues. Thin film composite polyamide membranes are widely used for...     

Nanocarrier-mediated co-delivery systems for lung cancer therapy: recent developments and prospects

Environmental Chemistry Letters - Research has recently focused on combinational therapy using nanocarriers to overcome the obstacles associated with conventional therapy of lung cancer. The...     

Carbofuran-induced effects on acetylcholinesterase (AChE) in erythrocytes and liver of Cyprinus carpio

A study was conducted to determine the effects of long-term exposure to carbofuran on erythrocyte and liver acetylcholinesterase (AChE) activity in Cyprinus carpio, and assess which tissue was more sensitive to pesticide exposure examining this enzyme. Fish were allowed to accilimatize in toxicant-free water for 24 days after 60-day exposure. AChE activity was determined with a spectrophotometer using acetylthiocholine iodide as a substrate in erythrocytes and liver. Enzymic activity of erythrocytes and liver decreased over time. A higher degree of enzyme inhibition was observed in erythrocyte compared to liver. The degree of enzyme inhibition was positively correlated with exposure time. When exposed fish were transferred to clean water, recovery was greater in erythrocytes than liver. Erythrocyte AChE activity recovered after 18 days, while it required 21 days in liver. The findings of this study indicate that erythrocyte AChE is more sensitive to carbofuran than liver. The greater sensitivity of erythrocyte AChE suggests that it may be more useful as a biomarker for monitoring status of pollution in freshwater bodies.     

Study of heavy metals in some environmental samples

Fuels like coal and rubber are frequently used for brick burning. However, both coal and rubber contain heavy metals. These heavy metals may elutriate in the wake of fly ash or may adsorb or absorb in the product. The present work deals with the analysis of heavy metals in some samples collected from brick burning industries located in the vicinity of a metropolitan city, Peshawar, Pakistan. Samples from raw clay, product, chimney scale and fossil fuel & rubber were collected and leached with acid mixture. The leachates were concentrated and analyzed by atomic absorption spectrophotometer for the determination of chromium (Cr), lead (Pb), cadmium (Cd) and antimony (Sb). It was observed that heavy metals are present in clay, brick and chimney scale. However, significant amount of these metals was observed in chimney scale. It is inferred that such emanations laden with heavy metals are accompanying the stack gases which are being dumped in to the environment. In order to avoid environmental problems, strict environmental regulations shall be enforced and a constant check on these emanations to the environment must be made to ensure clean air act.     

Anthropogenic impacts on heavy metal concentrations in the coastal sediments of Dumai, Indonesia

Concentrations of Cd, Cu, Pb, Zn, Ni and Fe were determined in the surface sediments to investigate the distributions, concentrations and the pollution status of heavy metals in Dumai coastal waters. Sediment samples from 23 stations, representing 5 different site groups of eastern, central and western Dumai and southern and northern Rupat Island, were collected in May 2005. The results showed that heavy metal concentrations (in microg/g dry weight; Fe in %) were 0.88 (0.46-1.89); 6.08 (1.61-13.84); 32.34 (14.63-84.90); 53.89 (31.49-87.11); 11.48 (7.26-19.97) and 3.01 (2.10-3.92) for Cd, Cu, Pb, Zn, Ni and Fe, respectively. Generally, metal concentrations in the coastal sediments near Dumai city center (eastern and central Dumai) which have more anthropogenic activities were higher than those at other stations. Average concentration of Cd in the eastern Dumai was slightly higher than effective range low (ERL) but still below effective range medium (ERM) value established by Long et al. (Environmental Management 19(1):81-97, 1995; Environmental Toxicology Chemistry 17(4):714-727, 1997). All other metals were still below ERL and ERM. Calculated enrichment factor (EF), especially for Cd and Pb, and the Pollution load index (PLI) value in the eastern Dumai were also higher than other sites. Cd showed higher EF when compared to other metals. Geo-accumulation indices (I(geo)) in most of the stations (all site groups) were categorized as class 1 (unpolluted to moderately polluted environment) and only Cd in Cargo Port was in class 2 (moderately polluted). Heavy metal concentrations found in the present study were comparable to other regions of the world and based on the calculated indices it can be classified as unpolluted to moderately polluted coastal environment.     

Evaluation of existing equations for temporal scour depth around circular bridge piers

Scour is defined as the processes of removal of sediment particles from water stream bed by the erosive action of activated water, and also carries sediment away from the hydraulic structures. Scour is the main cause of pier failure. Numerous equations are available for estimating temporal and equilibrium scour depth. The present study describes the phenomenon of temporal scour depth variation at bridge piers and deals with the methods for its estimation. The accuracy of six temporal scour depth equations are also checked in this study. After graphical and statistical analysis, it was found that the relationship proposed by Oliveto and Hager (J Hydraul Eng (ASCE) 128(9):811–520, 2002) predicts temporal scour depth better than other equations. Three equations of equilibrium time of scour are also used for computing equilibrium time. Equilibrium time equation proposed by Choi and Choi (Water Environ J 30(1–2):14–21, 2016) gives better agreements with observed values.     

Measurement of soil radioactivity levels and radiation hazard assessment in southern Rechna interfluvial region, Pakistan

Rechna interfluvial region is one of the main regions of Punjab, Pakistan. It is the area which is lying between River Ravi and River Chenab, alluvial-filled. Radioactivity levels in soil samples, collected from southern Rechna interfluvial region, Pakistan, have been estimated by using gamma-ray spectrometric technique. ²²⁶Ra, ²³²Th, the primordial radionuclide ⁴⁰K, and the artificial radionuclide ¹³⁷Cs have been measured in the soil of the study area. The mean radioactivity levels of ²²⁶Ra, ²³²Th, ⁴⁰K, and ¹³⁷Cs were found to be 50.6 ± 1.7, 62.3 ± 3.2, 662.2 ± 32.1, and 3.1 ± 0.3 Bq kg^???1, respectively. The mean radium equivalent activity (Ra_eq), outdoor radiation hazard index (H _out), indoor radiation hazard index (H _in), and terrestrial absorbed dose rate for the area under study were determined as 190.8 ± 8.7 Bq kg^???1, 0.52, 0.65, and 69.8 nGy h^???1, respectively. The annual effective dose to the general public was found to be 0.43 mSv. This value lies well below the limit of 1 mSv for general public as recommended by the International Commission on Radiological Protection. The measured values are comparable with other global radioactivity measurements and are found to be safe for the public and the environment.