Desorption characteristics of kaolin clay contaminated with zinc from electrokinetic soil processing

A number of bench scale laboratory column tests were carried out using a newly designed and developed electrokinetic cell to investigate the fundamental behavior of zinc-spiked kaolin clay subjected to an electric field. Laboratory investigations focused on (i) zinc migration by the combined effects of electromigration and electro-osmosis and (ii) the electrically induced desorption characteristics of zinc-contaminated kaolin that occurred during processing. The correlations of the applied voltage gradient, electro-osmotic flow rate, and the development of a pH gradient were examined and evaluated. The results showed that the removal efficiency was high during the early stage of processing due to rapid desorption by electrokinetic effects in the cathode region. However, the majority of zinc migrating from the anode was precipitated due to the high pH environment in the cathode region.     

Preliminary evaluation of septic-system absorption-field architecture types in a profile-limited soil

Managing household wastewater is an issue that affects hundreds of thousands of people in rural communities nationwide, many of whom rely on septic systems as their primary means of household wastewater disposal. Septic system absorption field products with architectures quite different from traditional pipe-and-gravel systems are being installed in many states with variances from initial design specifications. The objective of this study was to evaluate the performance, as measured by the in-product height of stored solution, of four differing absorption-field product architecture types in a profile-limited soil that was loaded at the maximum allowable rate based on soil morphology. Five chamber, two gravel-less pipe, two polystyrene aggregate, and four pipe-and-gravel systems were installed in a profile-limited, Captina silt loam soil (fine-silty, siliceous, active, mesic Typic Fragiudult) and dosed with raw effluent at rates determined by current State of Arkansas regulations via individual peristaltic pumps. Free-solution monitoring ports were installed within each product, where the depth to free solution was measured periodically and used to evaluate product performance. Data collected from January through August 2009 indicated that preliminary system performance was unaffected by product architecture type. All products performed similarly under dry soil conditions. However, differences among individual products were observed during periods of hydrologic stress (i.e., wet soil conditions). Surfacing of effluent was not observed atop any product, indicating that the current loading rate design method is functioning properly. Preliminary results indicate that some alternative absorption-field products perform similarly to the traditional pipe-and-gravel system, thus providing flexibility and options for homeowners.     

Open and closed seascapes: where does habitat patchiness create populations with high fractions of self-recruitment?

Which populations are replenished primarily by immigrants (open) and which by local production (closed) remains an important question for management with implications for response to exploitation, protection, and disturbance. However, we lack methods for predicting population openness. Here, we develop a model for openness and show that considering habitat isolation explains the existence of surprisingly closed populations in high-dispersal species, including many marine organisms. Relatively closed populations are expected when patch spacing is more than twice the standard deviation of a species'. dispersal kernel. In addition, natural scales of habitat patchiness on coral reefs are sufficient to create both largely open and largely closed populations. Contrary to some previous interpretations, largely closed marine populations do not require mean dispersal distances that are unusually short, even for species with relatively long pelagic larval durations. We predict that habitat patchiness has strong control over population openness for many marine and terrestrial species with a highly dispersive life stage and relatively sedentary adults. This information can be used to make initial predictions about where populations will be more or less resilient to local exploitation and disturbance.     

Chip-scale calorimeters: Potential uses in chemical engineering

This work illustrates the potential use of chip-scale calorimeters in typical applications found in chemical engineering including thermal hazard screening, material characterization, and mixing compatibility screening. Experimental results were obtained from two liquid nanocalorimeters and one thermal conductivity sensor designed and commercialized by Xensor Integration, and from two microfabricated calorimeter prototypes developed at Texas A&M University and University of Louisiana at Lafayette.     

Runoff of trifluralin,metolachlor, and metribuzin from a clay loam soil of Louisiana

Trifluralin[2,6-dinitro-N,N-dipropyl-4-(trifluormethyl)benzenamine], metolachlor[2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamide] and metribuzin[4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)one] were applied as pre-emergent herbicides to soybean plots in Louisiana (LA) at the rate of 1683 g/ha, 2759 g/ha and 609 g/ha, respectively. The concentrations of trifluralin in the runoff water ranged between 0.09 ng/mL and 0.02 ng/mL, which is lower than the 2 ng/mL US Environmental Protection Agency (EPA) advisory level for trifuralin in drinking water. Metolachlor concentrations in the runoff water ranged from 9.0 ng/mL to 221.5 ng/mL, which is both lower and higher than the 175 ng/mL EPA advisory level for metolachlor. Similarly, metribuzin concentrations in the runoff water ranged between 1.5 ng/mL and 56.2 ng/mL, which is also lower and higher than the 10 ng/mL EPA advisory level for metribuzin. Accordingly, from the field plots located on a Commerce clay loam soil in LA, although the concentration of trifluralin in runoff water were substantially lower than the EPA advisory level, metolachlor and metribuzin concentrations are likely to exceed the EPA advisory levels early on in the application season with a subsequent rapid decrease to safe levels. The total loss of trifluralin in runoff water was 0.005% of the applied amount over an 89 day period after application. The total loss of metolachlor and metribuzin in the runoff water was 4.67% and 5.36% of the applied amount, respectively, over a 22 day period after application. As such, there was almost no movement of trifluralin in the runoff water, whereas metolachlor and metribuzin were much more easily moved.     

One size fits all: stability of metabolic scaling under warming and ocean acidification in echinoderms

Responses by marine species to ocean acidification (OA) have recently been shown to be modulated by external factors including temperature, food supply and salinity. However the role of a fundamental biological parameter relevant to all organisms, that of body size, in governing responses to multiple stressors has been almost entirely overlooked. Recent consensus suggests allometric scaling of metabolism with body size differs between species, the commonly cited ‘universal’ mass scaling exponent (b) of ¾ representing an average of exponents that naturally vary. One model, the Metabolic-Level Boundaries hypothesis, provides a testable prediction: that b will decrease within species under increasing temperature. However, no previous studies have examined how metabolic scaling may be directly affected by OA. We acclimated a wide body-mass range of three common NE Atlantic echinoderms (the sea star Asterias rubens, the brittlestars Ophiothrix fragilis and Amphiura filiformis) to two levels of pCO₂ and three temperatures, and metabolic rates were determined using closed-chamber respirometry. The results show that contrary to some models these echinoderm species possess a notable degree of stability in metabolic scaling under different abiotic conditions; the mass scaling exponent (b) varied in value between species, but not within species under different conditions. Additionally, we found no effect of OA on metabolic rates in any species. These data suggest responses to abiotic stressors are not modulated by body size in these species, as reflected in the stability of the metabolic scaling relationship. Such equivalence in response across ontogenetic size ranges has important implications for the stability of ecological food webs.     

Prediction models for the flash point of pure components

The flash point for a liquid is defined as the lowest temperature at which its vapor forms a spontaneously ignitable mixture when brought in contact with air. Having a good estimation of the flash point temperature at normal conditions is relevant because it is one of the main properties used to characterize fire and explosion hazards for liquids. Most of predictive correlations in the literature include a physical effect by including the normal boiling temperature in their formulation. To achieve combustion, sufficient evaporation is required and then a part of the liberated energy from the combustion is used to support the evaporation. Thus the evaporation energy and a chemical effect given by the heat of reaction are incorporated in this work. It is firstly verified that the relation between the flash point temperature and the normal boiling temperature tends to be a constant. Thus a heuristic approach based on 611 chemical species of diverse families indicates that this relation is around 0.75. The dispersion of the error has been reduced by using two proposed correlations where both physical and chemical properties are included in the model. In particular, the second equation is based on the group contributions method, which has been developed for alkanes. This method is in fact a combination of the group contributions method and the first model to overcome the difficulties in predicting isomeric differences.