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141.
Inorganic arsenic induces a variety of toxicities including cancer. The mode of action for cancer and non-cancer effects involves the metabolic generation of trivalent arsenicals and their reaction with sulfhydryl groups within critical proteins in various cell types which leads to the biological response. In epithelial cells, the response is cell death with consequent regenerative proliferation. If this continues for a long period of time, it can result in an increased risk of cancer. Arsenicals do not react with DNA. There is evidence for indirect genotoxicity in various in vitro and in vivo systems, but these involve exposures at cytotoxic concentrations and are not the basis for cancer development. The resulting markers of genotoxicity could readily be due to the cytotoxicity rather than an effect on the DNA itself. Evidence for genotoxicity in humans has involved detection of chromosomal aberrations, sister chromatid exchanges in lymphocytes and micronucleus formation in lymphocytes, buccal mucosal cells, and exfoliated urothelial cells in the urine. Numerous difficulties have been identified in the interpretation of such results, including inadequate assessment of exposure to arsenic, measurement of micronuclei, and potential confounding factors such as tobacco exposure, folate deficiency, and others. Overall, the data strongly supports a non-linear dose response for the effects of inorganic arsenic. In various in vitro and in vivo models and in human epidemiology studies there appears to be a threshold for biological responses, including cancer. 相似文献
142.
Fate of polybrominated diphenyl ethers in the environment of the Pearl River Estuary, South China 总被引:1,自引:0,他引:1
Yu-Feng Guan O.S. Samuel Sojinu Eddy Y. Zeng 《Environmental pollution (Barking, Essex : 1987)》2009,157(7):2166-2172
Ninety-six riverine runoff samples collected at eight major outlets in the Pearl River Delta (PRD), South China, during 2005-2006 were analyzed for 17 brominated diphenyl ether (BDE) congeners (defined as Σ17PBDE). Fourteen and 15 congeners were detected, respectively, in the dissolved and particulate phases. These data were further used to elucidate the partitioning behavior of BDE congeners in riverine runoff. Several related fate processes, i.e. air-water exchange, dry and wet deposition, degradation, and sedimentation, within the Pearl River Estuary (PRE), were examined to estimate the inputs of Σ10PBDE (sum of the target BDE congeners, BDE-28, -47, -66, -85, -99, -100, -138, -153, -154, and -183) and BDE-209 from the PRD to the coastal ocean based on mass balance considerations. The results showed that annual outflows of Σ10PBDE and BDE-209 were estimated at 126 and 940 kg/year, respectively from the PRE to coastal ocean. Besides sedimentation and degradation, the majority of Σ10PBDE and BDE-209 discharged into the PRE via riverine runoff was transported to the coastal ocean. 相似文献
143.
144.
Attraction of two lacewing species to volatiles produced by host plants and aphid prey 总被引:1,自引:0,他引:1
Zhu J Obrycki JJ Ochieng SA Baker TC Pickett JA Smiley D 《Die Naturwissenschaften》2005,92(6):277-281
It is well documented that host-related odors enable many species of parasitoids and predatory insects to locate their prey and prey habitats. This study reports the first characterization of prey and prey host odor reception in two species of lacewings, Chrysoperla carnea (Say) and Chrysopa oculata L. 2-Phenylethanol, one of the volatiles emitted from their preys host plants (alfalfa and corn) evoked a significant EAG response from antennae of C. carnea. Traps baited with this compound attracted high numbers of adult C. carnea, which were predominantly females. One of the sex pheromone components (1R,4aS,7S,7aR)-nepetalactol of an aphid species, Acyrthosiphon pisum (Harris) attracted only C. oculata adults. Single sensillum recordings showed that the olfactory neurons of C. carnea responded to both 2-phenylethanol and aphid sex pheromone components, but those of C. oculata only responded to the latter. 相似文献
145.
Arsenic and chromium speciation in an urban contaminated soil 总被引:1,自引:0,他引:1
The distribution and speciation of As and Cr in a contaminated soil were studied by synchrotron-based X-ray microfluorescence (μ-XRF), microfocused X-ray absorption spectroscopy (μ-XAS), and bulk extended X-ray absorption fine structure spectroscopy (EXAFS). The soil was taken from a park in Wilmington, DE, which had been an important center for the leather tanning industry along the Atlantic seaboard of the United States, until the early 20th century. Soil concentrations of As, Cr, and Pb measured at certain locations in the park greatly exceeded the background levels of these heavy metals in the State of Delaware. Results show that Cr(III) and As(V) species are mainly present in the soil, with insignificant amounts of Cr(VI) and As(III). Micro-XRF maps show that Cr and Fe are distributed together in regions where their concentrations are diffuse, and at local spots where their concentrations are high. Iron oxides, which can reduce Cr(VI) to Cr(III), are present at some of these hot spots where Cr and Fe are highly concentrated. Arsenic is mainly associated with Al in the soil, and to a minor extent with Fe. Arsenate may be sorbed to aluminum oxides, which might have transformed after a long period of time into an As-Al precipitate phase, having a structure and chemical composition similar to mansfieldite (AlAsO(4)?2H(2)O). The latter hypothesis is supported by the fact that only a small amount of As present in the soil was desorbed using the characteristic toxicity leaching procedure tests. This suggests that As is immobilized in the soil. 相似文献
146.
Understanding the extent to which people are being exposed to environmental contaminants helps to identify those populations which may be disproportionately exposed to the contaminants of potential public health concern. This study represents the first report of a comparison of heavy metal arsenic (As), mercury (Hg), cadmium (Cd), cobalt (Co), copper (Cu), lead (Pb), platinum (Pt), zinc (Zn), and manganese (Mn) concentrations in the blood of residents of mining and non-mining communities in Ghana. Blood sampling, health records, and interviews were used in this study to establish the links between the levels of contaminants and health effects in humans within a mining and non-mining community in Ghana. Results of this study show that mean concentration of As in blood in Tarkwa Nsuaem Municipality/Prestea-Huni Valley District (TNMA/PHVD) (mining communities) and Cape Coast Metropolis (CCMA) (non-mining community) was 18- and 2-fold higher, respectively, than the WHO guideline value of 0.002?mg?L?1. The mean concentrations of As, Cd, Pb, Hg, and Mn were elevated up to 20-fold higher in the blood of resident adults and children in TNMA/PHVD than in CCMA. The risk of acute respiratory infections in the exposed populations of TNMA and PHVD were approximately 41- and 12-fold greater than the unexposed group. The risk of diabetes mellitus in the exposed populations of TNMA and PHVD were also approximately 20- and 4-fold higher than the unexposed group. In TNMA and PHVD, 40 blood donors were suffering from hyperkeratosis or pigmentation unlike their CCMA counterparts. Data suggest a potential association between mining activities and the levels of these heavy metals. However, the proportion of anthropogenic contribution to the levels of these metals in the blood remains uncertain. This uncertainty seems to be the umbrella under which both government and mining companies continue to hide, leading to inaction. 相似文献
147.
This study examines the role of neighborhood effects in the spatial distributions of selected bird species in Navarre, Spain. We employed a geographic information system (GIS) to organize the data on bird distributions and relevant environmental variables and to analyze their spatial patterns. Three bird species were selected for analysis: the European honey-buzzard (Pernis apivorus), the Eurasian hobby (Falco subbuteo), and the European pied flycatcher (Ficedula hypoleuca). Selected environmental variables of the study area were digitized to create a comprehensive data base and logistic regression models were used to evaluate the significance of each variable in the spatial distribution. The spatial patterns of bird distributions were used to extract topological relationships and to identify neighborhood effects. Although all the selected species illustrate a pattern of positive spatial autocorrelation in their distributions, the significance of neighborhood effects varies from species to species. Among the selected species, neighborhood effects are most evident in the distribution of the European pied flycatcher and are significant for the Eurasian hobby. The distribution of the European honey-buzzard is not much affected by neighborhood effects. The results suggest that examination of neighborhood effects is a prerequisite for modeling bird distributions. 相似文献
148.
Peter W. Anderson Samuel D. Faust 《Journal of the American Water Resources Association》1972,8(4):750-760
ABSTRACT. New Jersey, together with other states in the northeast, was stricken with drought during 1961-66. The effect of this drought was most severe in the northern part of the State. The water quality of the Passaic River, which drains the urban, industrialized northeast, perhaps deteriorated the most among the major drainage systems. This river system is used as a raw-water source by 10 water suppliers. The impact of the drought upon the water supply of the Passaic Valley Water Commission, the most downstream of the basin's suppliers, which supplies an average of about 90 million gallons a day to more than 650,000 persons, is evaluated herein. The drought's impact on the raw-water quality is appraised by the comparison of before-and-after qualities of dissolved solids, dissolved oxygen, biochemical-oxygen demand, turbidity, and hardness. For example, at the worst point during the drought, monthly average dissolved-solids content in the raw water were about 210 percent, hardness, about 167 percent, and biochemical-oxygen demand about 270 percent higher than antecedent values. In general, the study concludes that the drought produced a deterioration in both raw and finished water quality, and is estimated to have increased chemical-treatment costs during the drought by about $650,000. 相似文献
149.
Conflict on the Coast: Using Geographic Information Systems to Map Potential Environmental Disputes in Matagorda Bay,Texas 总被引:1,自引:0,他引:1
Brody SD Highfield W Arlikatti S Bierling DH Ismailova RM Lee L Butzler R 《Environmental management》2004,34(1):11-25
The sustainable management of coastal natural resources inevitably involves identifying stakeholder conflicts and developing planning processes that prevent these conflicts from becoming intractable disputes. This study links environmental conflict to specific areas within a large ecological system. Specifically, we use Geographic Information Systems (GIS) to map potentially competing stakeholder values associated with establishing protected areas in Matagorda Bay, Texas. By overlaying multiple values associated with a range of stakeholders across space, we are able to identify hotspots of potential conflict as well as areas of opportunity for maximizing joint gains. Mapping stakeholder conflict is an approach to proactively locate potential controversy in response to a specific environmental management proposal and guide decision makers in crafting planning processes that mitigate the possibility of intractable disputes and facilitate the implementation of sustainable coastal policies. Results indicate that under different management scenarios, protected area proposals will generate more conflict in specific areas. Most notably, regulated uses would produce the greatest degree of conflict on or near shore, particularly at the mouth of the Colorado River. Additionally, of all the management scenarios evaluated, the prohibition of coastal structural development would generate the overall highest level of conflict within the Bay. Based on the results, we discuss the policy implications for environmental managers and provide guidance for future research on location-based conflict management within the coastal margin. 相似文献
150.
de Abreu Íthalo Barbosa Silva de Sousa Maria Helena da Silva Andressa Pereira de Araújo Padilha Carlos Eduardo Sales Aldo Torres da Silva Antonio Samuel Alves Dutra Emmanuel Damilano Menezes Rômulo Simões Cezar 《Journal of Material Cycles and Waste Management》2023,25(3):1309-1324
Journal of Material Cycles and Waste Management - The use of food waste (FW) for the production of biofuels and value-added compounds is growing worldwide. However, the significant chemical... 相似文献