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Metasedimentary garnet-mica schists are interlayered with metabasic garnet–omphacite schists and enclose eclogite boudins in the high-pressure metamorphic Maksyutov complex in the Southern Urals, Russia. These three rock types were investigated in one outcrop and compared chemographically and thermobarometrically. The Fe/Mg distributions between garnet rim–omphacite and garnet rim–phengite pairs indicate different equilibration temperatures for the three samples, with the lowest temperature (500°C, >1.5 GPa) for the eclogite boudin, an intermediate temperature (630°C, >1.7 GPa) for the foliated eclogite and the highest temperature (650°C, >1.7 GPa) for the garnet-mica schist. The garnets in garnet-mica schist enclose abundant chloritoid relics and the Fe/Mg distribution between chloritoid and garnet records an earlier high-temperature stage (650°C, >2.0 GPa) before the garnet rim–phengite temperatures were reached. Together with some minimum- and maximum-pressure estimates three different prograde pressure–temperature paths and a common retrograde metamorphic evolution are interpreted from the chemographic and thermobarometric data. The different early metamorphic evolutions and conditions confirm the variability of protoliths, which are also indicated by different U/Pb zircon and rutile ages.  相似文献   
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Present knowledge assumes that different mechanisms acting downstream in high temperature processes lead to the formation of polychlorinated dibenzo(p)dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). Concerning the 17 2,3,7,8-Cl-substituted PCDD/F congeners in particular, there is new evidence for a single-step reaction type (recently reported in this publication series, of. also parts 1 and 2). A formation based on a combination of the several mechanisms, which have been proposed and discussed since 1985, becomes more and more unlikely. Qualitatively the PCDD/F formation downstream from high temperature processes depends rather on a thermodynamically forced single reaction step, and on pure statistical distribution quantitatively. This may be a new ‘Thermostat Synthesis’ instead of ‘de novo’.  相似文献   
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This contribution highlights the role and importance of ecotoxicology in regulatory decisions of chemicals legislation focussing on the responsibilities of the German Federal Environmental Agency (UBA). Therefore, organisational structures and processes relevant for making decisions concerning the risks of chemicals to men and the environment are described. As any regulatory decision starts with scientific findings, a brief overview of UBA’s activities with regard to own research and to initiate research in the area of ecotoxicology is provided. In addition, the vast importance of standardisation and international harmonisation of guidelines for testing and assessment of chemicals is illustrated, including the time- and ressource consuming character of these harmonisation processes. Subsequently, the involvement of regulatory decision making in intense and controversial scientific and political debates is emphasised. The transparency of these discussions and the independence of science is critically addressed in this context. In a final chapter the job requirements and options for qualification in Germany are described, ending up with a brief summary of the positive experiences with UBA’s contribution to the new advanced training course in ecotoxiciology realised by GDCh/SETAC GLB. A summary of the discussions on these different topics emphasises the specific challenge in regulatory ecotoxicology: To generate knowledge relevant for decision making, while acting in an area of conflict between scientific demands and economical as well as political interests.  相似文献   
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Abstract: Past and present pressures on forest resources have led to a drastic decrease in the surface area of unmanaged forests in Europe. Changes in forest structure, composition, and dynamics inevitably lead to changes in the biodiversity of forest‐dwelling species. The possible biodiversity gains and losses due to forest management (i.e., anthropogenic pressures related to direct forest resource use), however, have never been assessed at a pan‐European scale. We used meta‐analysis to review 49 published papers containing 120 individual comparisons of species richness between unmanaged and managed forests throughout Europe. We explored the response of different taxonomic groups and the variability of their response with respect to time since abandonment and intensity of forest management. Species richness was slightly higher in unmanaged than in managed forests. Species dependent on forest cover continuity, deadwood, and large trees (bryophytes, lichens, fungi, saproxylic beetles) and carabids were negatively affected by forest management. In contrast, vascular plant species were favored. The response for birds was heterogeneous and probably depended more on factors such as landscape patterns. The global difference in species richness between unmanaged and managed forests increased with time since abandonment and indicated a gradual recovery of biodiversity. Clearcut forests in which the composition of tree species changed had the strongest effect on species richness, but the effects of different types of management on taxa could not be assessed in a robust way because of low numbers of replications in the management‐intensity classes. Our results show that some taxa are more affected by forestry than others, but there is a need for research into poorly studied species groups in Europe and in particular locations. Our meta‐analysis supports the need for a coordinated European research network to study and monitor the biodiversity of different taxa in managed and unmanaged forests.  相似文献   
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The impacts of strategically located contour prairie strips on sediment and nutrient runoff export from watersheds maintained under an annual row crop production system have been studied at a long-term research site in central Iowa. Data from 2007 to 2011 indicate that the contour prairie strips utilized within row crop-dominated landscapes have greater than proportionate and positive effects on the functioning of biophysical systems. Crop producers and land management agencies require comprehensive information about the Best Management Practices with regard to performance efficacy, operational/management parameters, and the full range of financial parameters. Here, a farm-level financial model assesses the establishment, management, and opportunity costs of contour prairie strips within cropped fields. Annualized, depending on variable opportunity costs the 15-year present value cost of utilizing contour prairie strips ranges from $590 to $865 ha?1 year?1 ($240–$350 ac?1 year?1). Expressed in the context of “treatment area” (e.g., in this study 1 ha of prairie treats 10 ha of crops), the costs of contour prairie strips can also be viewed as $59 to about $87 per treated hectare ($24–$35 ac?1). If prairie strips were under a 15-year CRP contract, total per acre cost to farmers would be reduced by over 85 %. Based on sediment, phosphorus, and nitrogen export data from the related field studies and across low, medium, and high land rent scenarios, a megagram (Mg) of soil retained within the watershed costs between $7.79 and $11.46 mg?1, phosphorus retained costs between $6.97 and $10.25 kg?1, and nitrogen retained costs between $1.59 and $2.34 kg?1. Based on overall project results, contour prairie strips may well become one of the key conservation practices used to sustain US Corn Belt agriculture in the decades to come.  相似文献   
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