Rapid reductive dechlorination of atrazine by zero-valent iron under acidic conditions

The dechlorination of atrazine (2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazine) via reaction with metallic iron under low-oxygen conditions was studied using reaction mixture pH values of 2.0, 3.0, and 3.8. The pH control was achieved through addition of sulfuric acid throughout the duration of the reaction. The lower the pH of the reaction mixture, the faster the degradation of atrazine. The surface area of the sulfuric acid-treated iron particles was 0.31 (+/- 0.01) m2 g-1 and the surface area normalized initial pseudo-first order rate constants (kSA, where rate = kSA x (surface area/l) x [Atrazine]) at pH values of 2.0, 3.0, and 3.8 were equal to, respectively, 3.0 (+/- 0.4) x 10(-3) min-1 m-2 l, 5 (+/- 3) x 10(-4) min-1 m-2 l, and 1 (+/- 1) x 10(-4) min-1 m-2 l. The observed products of the degradation reaction were dechlorinated atrazine (2-ethylamino-4-isopropylamino-1,3,5-triazine) and possibly hydroxyatrazine (2-ethylamino-4-isopropylamino-6-hydroxy-s-triazine). Triazine ring protonation may account, at least in part, for the observed effect of pH on atrazine dechlorination via metallic iron.     

RESERVOIR MANAGEMENT RULES DERWED WITH THE AID OF MULTIPLE OBJECTIVE DECISION MAKING TECHNIQUES1

ABSTRACT: The determination of optimum reservoir operating rules for reservoirs with multiple conflicting objectives is still a difficult task - despite many publications in this field. In this paper a three-step Multi Objective Decision Making (MODM) method is presented, the emphasis of which is placed on the necessity to make the work easy for the decision maker, which many MODM techniques fail to achieve. The method is applied to the development of a compromise optimum operating rule for a multi-purpose reservoir. In the first step of the method stochastic DP is chosen which is combined with the “weighting method” allowing combination of various objectives into one objective function. By systematically varying the weights for the objectives a large number of pareto optimum reservoir operating rules is generated. In the second step of the method the performance of all these operating rules is tested with the aid of a model simulating reservoir operation. The results are statistically analyzed and the reliabilities for attaining the various objectives are computed. The third step of the model applies another MODM technique which allows the decision maker - in a computer dialog - to select his optimum reservoir operating rule from the large number of pareto optimum solutions generated in step 1. Here he can specify his preferences for the various objectives. For this purpose two alternative MODM techniques are offered: Compromise Programming and the SEMOPS method. Their performance is shown along with the generation and selection of operating rules for the multi-objective Wupper reservoir system in Germany.     

RIPARIAN LAND USES AND PRECIPITATION INFLUENCES ON STREAM BANK EROSION IN CENTRAL IOWA1

Human alterations to the Iowa landscape, such as elimination of native vegetation for row crop agriculture and grazing, channelization of streams, and tile and ditch drainage, have led to deeply incised channels with accelerated streambank erosion. The magnitude of streambank erosion and soil loss were compared along Bear Creek in central Iowa. The subreaches are bordered by differing land uses, including reestablished riparian forest buffers, row crop fields, and continuously grazed riparian pastures. Erosion pins were measured from June 1998 to July 2002 to estimate the magnitude of streambank erosion. Total streambank soil loss was estimated by using magnitude of bank erosion, soil bulk density, and severely eroded bank area. Significant seasonal and yearly differences in magnitude of bank erosion and total soil loss were partially attributed to differences in precipitation and associated discharges. Riparian forest buffers had significantly lower magnitude of streambank erosion and total soil loss than the other two riparian land uses. Establishment of riparian forest buffers along all of the nonbuffered subreaches would have reduced stream‐bank soil loss by an estimated 77 to 97 percent, significantly decreasing sediment in the stream, a major water quality problem in Iowa.     

Potential,constrains and solutions for marine aquaculture in Kiel Bay & Fjord

Marine aquaculture is facing a variety of competing uses in densely populated coastal areas such as the coast of Kiel Bay. Thus, a major barrier for extending the marine aquaculture business could be the lack of suitable space for “offshore farming”. Moreover, in public opinion the aquaculture sector is often associated with a negative image derived from environmental concerns. It might therefore be expected that planning aquaculture installations in Kiel Bay & Fjord would face resistance both from other offshore stakeholders and the public. This study therefore addressed the question whether arguments and criteria can be found that may contribute to a greater support and positive image of local aquaculture enterprise, thus fostering political support for this sector as well. Indeed, a widespread regional survey showed less public reservation towards aqua-cultural business in Kiel Fjord than initially expected. However, expanding the entrepreneurship in the regional aqua-cultural sector will only be successful if the installations can avoid a significant deterioration of the water quality in Kiel Fjord, e.g. through excessive emissions of nutrients from net cages. An important step forward toward this goal is the concept of IMTA = Integrated Multi-Trophic Aquaculture. The IMTA concept spatially integrates nutrient emitting installations such as fish net cages with installations of nutrient extracting organisms, e.g. mussels and algae. Based on spatial analyses of marine environmental parameters and through modelling of nutrient mass balances (emitted versus extracted nutrient quantities) possible locations, types and sizes of aquaculture installations can be determined.     

A critique of EPA's index of watershed indicators

Numerous indices have been developed to assess water quality and the impact of programs to improve quality. The Index of Watershed Indicators (IWI) is one such index created by the US Environmental Protection Agency to assess watershed vulnerability and condition in the United States. The credibility and applicability of subjective indices such as IWI depends upon their ability to withstand tests that challenge their internal consistency and interpretation. This paper critiques IWI on the basis of these tests and other considerations, and suggests that explicitly basing the index on multiattribute utility theory and methods could help resolve many of these difficulties.     

New stem-sauropodomorph (Dinosauria,Saurischia) from the Triassic of Brazil

Post-Triassic theropod, sauropodomorph, and ornithischian dinosaurs are readily recognized based on the set of traits that typically characterize each of these groups. On the contrary, most of the early members of those lineages lack such specializations, but share a range of generalized traits also seen in more basal dinosauromorphs. Here, we report on a new Late Triassic dinosaur from the Santa Maria Formation of Rio Grande do Sul, southern Brazil. The specimen comprises the disarticulated partial skeleton of a single individual, including most of the skull bones. Based on four phylogenetic analyses, the new dinosaur fits consistently on the sauropodomorph stem, but lacks several typical features of sauropodomorphs, showing dinosaur plesiomorphies together with some neotheropod traits. This is not an exception among basal dinosaurs, the early radiation of which is characterized by a mosaic pattern of character acquisition, resulting in the uncertain phylogenetic placement of various early members of the group.