Groundwater Impacts on Surface Water and Sediment—Gowanus Canal,Brooklyn, New York

The Gowanus Canal Superfund Site in Brooklyn, New York, is an approximately 1.5‐mile (1.61‐km) long estuary that was historically converted into a canal for industrial and commercial purposes. Three manufactured gas plants (MGPs) were formerly located on the Gowanus Canal and discharged waste into it. Surface sediments remain highly contaminated with polycyclic aromatic hydrocarbons (PAHs) long after the MGPs were razed. A hydrogeologic assessment indicates that groundwater passes through the deeper coal tar–contaminated sediment prior to discharging to the canal. This study was undertaken to investigate if groundwater passing through coal tar–contaminated sediment could be responsible for the ongoing contamination of both surface sediments and surface water in the canal. PAH compound distributions in surface water samples collected from the tidal canal at low tide were compared with PAH compounds found in adjacent groundwater‐monitoring wells, point sources (combined sewer overflows [CSOs]), and surface sediments. The results indicate a strong correlation between PAH contaminant distributions in groundwater, sediment, and surface water, indicating that contaminated groundwater passing through the deeper coal tar–contaminated sediments is the primary mechanism contributing to the contamination of both surface sediment and surface water in the canal. Therefore, any sediment remediation efforts in the Gowanus Canal that fail to evaluate and control the upward transport processes have a high chance of failure due to recontamination from below.  ©2016 Wiley Periodicals, Inc.     

Rangeland dynamics in southern Ethiopia: (3). Assessment of rangeland condition in relation to land-use and distance from water in semi-arid Borana rangelands

The condition of the semi-arid Borana rangeland in southern Ethiopia was assessed by studying different land-use systems (communal land, a government ranch and a traditional grazing reserve enclosure) and along a distance gradient (near, middle and far) from water sources. The assessment incorporated the soil, herbaceous and woody plant layers. Two methods were employed to evaluate the grass layer, viz. ecological condition index (ECI) and weighted palatability composition (WPC). The ECI on the government ranch was 21.7% and 26% greater than that of the traditional reserve and the communal land, respectively. The WPC on the government ranch was 83.3% and 48.6% greater than that of the communal area and the traditional reserve, respectively. Both ECI and WPC values were similar for all distance sites from water. Tree equivalent (TE) density, of all encroaching woody plants combined, was higher on the communal land (504 TE ha(-1)) than the government ranch (373 TE ha(-)1) and traditional grazing reserve (118 TE ha(-1)), but with no marked variations in the distance sites from water. Height class distribution of encroaching woody plants in the study areas showed the largest abundance (range: >50-100%) at the height class >0-2m. Tree equivalents per hectare of encroaching woody plants were negatively correlated (r = -0.60) with ECI and WPC and positively correlated (r=0.87) with percentage bare ground. The correlation (r = 0.50) between percentage bare ground and soil compaction was positive and low. Although the government ranch had a greater composition of highly palatable grass species than the other land uses, the rangeland was not in good condition due to severe bush encroachment. The communal land was generally in poor condition. In the traditional grazing reserve, bush encroachment was not a problem, but the productivity of the grass layer was poor when assessed on the basis of ecological and palatability merits. The negative interaction of TE density of all encroaching woody plants combined with ECI or WPC and the positive interaction with bare ground, may suggest that the abundance of these species is more critical in aggravating deterioration in grassland productivity. Therefore, the priority of any bush control program must be towards minimizing the abundance of these woody plants.     

Bottomfast Ice Mapping and the Measurement of Ice Thickness on Tundra Lakes Using C‐Band Synthetic Aperture Radar Remote Sensing1

Abstract: Industrial activity in Canada’s north is increasing, placing demands on the use of water from lakes to build ice roads. Winter water withdrawal from these lakes has the potential to impact overwintering fish. Removal of water from small lakes can decrease oxygen and habitat available to fish. To address this issue, a protocol has been developed by the Department of Fisheries and Oceans outlining water withdrawal thresholds. Bathymetric surveys are the traditional method to determine lake depth, but are costly given the remoteness of northern lakes. This paper investigates the use of satellite C‐band synthetic aperture radar (SAR) remote sensing technology as a potential alternative or complement to traditional survey methods. Previous research has shown that a SAR can detect the transition from grounded to floating ice on lakes, or if a lake is completely frozen. Grounded ice has a dark signature while floating ice appears very bright in contrast. Similar results were observed for the datasets acquired in the study area. This suggests that lakes that freeze completely to the bottom can be identified using SAR. Such water bodies would not be viable fish overwintering habitat and can therefore be used as water sources without thresholds necessary. However, attempts to accurately calculate the depth of the ice at the grounded‐floating ice boundary using bathymetric profiles acquired in the summer and lake ice thickness measurements from a reference lake near Inuvik proved to be unreliable.     

Spatial Variation of Airborne Lead Concentration in an Urban Area

Ambient lead level concentrations have been measured during a three month period at 21 sampling sites in and near Champaign-Urbana, Illinois. Concentrations were determined at downtown, university, residential, suburban, and rural locations. The individual contributions from local sources and background to the Pb concentration in the urban area were determined from measurements and a mathematical model. From a statistical analysis of the data, it is shown that there are no significant differences among the nine residential sites. The group means of residential, university, and downtown stations are significantly different.     

The fate and persistence of trifluoroacetic and chloroacetic acids in pond waters

The environmental fate of trichloro-, dichloro-, and monochloroacetic acids, and trifluoroacetic acid was investigated using field aquatic microcosms and laboratory sediment-water systems. Trifluoroacetic acid was extremely persistent and showed no degradation during a one-year field study, though it appeared to undergo transient partitioning within an unknown pond phase as the temperature of the surroundings was reduced. Of the three chloroacetic acids, trichloro had the longest residence time (induction and decay) (approximately 40 d), dichloro the shortest (approximately 4 d), and monochloro an intermediate residence time (approximately 14 d). Laboratory studies suggest that the biodegradation of trichloro-, dichloro-, and monochloroacetic acids leads primarily to the formation of chloride and oxalic, glyoxalic, and glycolic acids, respectively.     

Airborne observations of vegetation and implications for biogenic emission characterization

Measuring hydrocarbons from aircraft represents one way to infer biogenic emissions at the surface. The focus of this paper is to show that complementary remote sensing information can be provided by optical measurements of a vegetation index, which is readily measured with high temporal coverage using reflectance data. We examine the similarities between the vegetation index and in situ measurements of the chemicals isoprene, methacrolein, and alpha-pinene to estimate whether the temporal behavior of the in situ measurements of these chemicals could be better understood by the addition of the vegetation index. Data were compared for flights conducted around Houston in August and September 2000. The three independent sets of chemical measurements examined correspond reasonably well with the vegetation index curves for the majority of flight days. While low values of the vegetation index always correspond to low values of the in situ chemical measurements, high values of the index correspond to both high and low values of the chemical measurements. In this sense it represents an upper limit when compared with in situ data (assuming the calibration constant is adequately chosen). This result suggests that while the vegetation index cannot represent a purely predictive quantity for the in situ measurements, it represents a complementary measurement that can be useful in understanding comparisons of various in situ observations, particularly when these observations occur with relatively low temporal frequency. In situ isoprene measurements and the vegetation index were also compared to an isoprene emission inventory to provide additional insight on broad issues relating to the use of vegetation indices in emission database development.     

Development of an energy discriminate CR-39(®) nuclear track etch dosimeter for Radon-220 gas measurements

An energy discriminate CR-39^® nuclear track etch dosimeter for use in a ²²⁰Rn and ²²²Rn gas monitor has been developed and experimentally assessed. It utilises a thin film of Mylar^® C to attenuate the alpha particle energies to allow only the damage tracks created by the 8.785 MeV alpha particles emitted from ²¹²Po of the ²³²Th decay chain to be registered in the CR-39^® plaque, allowing for the direct measurement of ²²⁰Rn gas concentrations. The dosimeter was developed through a combination of experimental investigations and theoretical simulations using the Monte Carlo ion transport modelling program Stopping and Range of Ions in Materials (SRIM 2008). A film thickness of 54 μm has been shown to attenuate all alpha energies less then 7.7 MeV.