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171.
The structure of Zn(II) complexes with dissolved organic matter (DOM) is an important consideration in developing molecular-level models of Zn(II) speciation, but recent reports favoring the tetrahedral geometry differ from earlier findings that geometry was largely octahedral. In general, the presence of thiolate ligands favors the tetrahedral geometry, while O and N ligands favor the octahedral geometry. This work presents extended X-ray absorption fine structure (EXAFS) and X-ray absorption near-edge structure (XANES) spectroscopic results, indicating an octahedral geometry over the pH range of 5–9 for a freshwater DOM isolate. Changes in XANES derivatives as a function of pH can be explained in terms of ligand protonation and/or changing ligand groups. Tetrahedral Zn(II)–DOM geometry may be restricted to binding environments containing thiol groups. 相似文献
172.
Homayon Ahmad Panahi Alireza Feizbakhsh Rozita Abdolahi Fard Elham Moniri 《毒物与环境化学》2013,95(8):1279-1289
Quantitative analysis of cadmium in environmental samples was achieved with a polymeric sorbent synthesized by copolymerization of N,N-dimethylacrylamide and allyl glycidyl ether/iminodiacetic acid as chelating monomers with N,N′-methylenebisacrylamide as cross-linker. The polymer was characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis, and scanning electron microscopy. The sorption capacity of the functionalized sorbent was 70 mg g?1. The equilibrium sorption data of Cd(II) on polymeric sorbent were analyzed using Langmuir, Freundlich, Temkin, and Redlich–Peterson models. Based on equilibrium adsorption data, the constants at pH 4.2 and 20 °C were determined for the first three as 0.33 (L mg?1), 17.5 (mg g?1) (L mg?1)1/n, and 12.9 (J mol?1). Recovery of 94% of the metal ion was obtained with 0.5 mol L?1 nitric acid as an eluting agent. 相似文献
173.
Seyed Majid Mousavi Babak Motesharezadeh Hossein Mirseyed Hosseini Hoseinali Alikhani Ali Asghar Zolfaghari 《Environmental geochemistry and health》2018,40(4):1221-1235
Many studies have conducted to determine the best management practice to reduce the mobility and phytoavailability of the trace metals in contaminated soils. In this study, geochemical speciation and phytoavailability of Zn for sunflower were studied after application of nanoparticles (SiO2 and zeolite, with an application rate of 200 mg kg?1) and bacteria [Bacillus safensis FO-036b(T) and Pseudomonas fluorescens p.f.169] to a calcareous heavily contaminated soil. Results showed that the biotic and abiotic treatments significantly reduced the Zn concentration in the aboveground to non-toxicity levels compared to the control treatment, and the nanoparticle treatments were more effective than the bacteria and control treatments. The concentration of CaCl2-extractable Zn in the treated soils was significantly lower than those of the control treatment. The results of sequential extraction showed that the maximum portion of total Zn belonged to the fraction associated with iron and manganese oxides. On the contrary, the minimum percent belonged to the exchangeable and water-soluble Zn (F1). From the environmental point of view, the fraction associated with iron and manganese oxides is less bioavailable than the F1 and carbonated fractions. On the basis of plant growth promotion, simultaneous application of the biotic and abiotic treatments significantly increased the aboveground dry biomass yield and also significantly reduced the CaCl2-extractable form, uptake by aboveground and translocation factor of Zn compared to the control treatment. Therefore, it might be suggested as an efficient strategy to promote the plant growth and reduce the mobile and available forms of toxic metals in calcareous heavily contaminated soils. 相似文献
174.
Ahmed A. Nassr Kamran Hessami Nikan Zargarzadeh Eyal Krispin Shayan Mostafaei Mounira A. Habli Ramesha Papanna Stephen P. Emery Alireza A. Shamshirsaz 《黑龙江环境通报》2023,43(9):1229-1238
To investigate the outcomes of asymptomatic stage I twin-to-twin transfusion syndrome (stage I TTTS) among patients treated with fetoscopic laser photocoagulation (FLP) versus expectant management. Databases such as PubMed, Web of Science and Scopus were systematically searched from inception up to March 1st, 2022. The primary outcome was at least one fetal survival at birth and secondary outcomes included gestational age at delivery, preterm premature rupture of membranes < 32 weeks, preterm birth < 32 weeks, and single and dual fetal survival. Five studies were included in the meta-analysis. There was no significant difference in terms of at least one survival (odds ratio (OR) = 1.40, 95%CI= (0.26, 7.43), P = 0.70), single survival (OR = 0.87, 95%CI= (0.51, 1.48), P = 0.60) and dual survival (OR = 1.63, 95%CI= (0.74, 3.62), P = 0.23) among FLP and expectant groups. Gestational age at delivery (mean difference = 1.19, 95%CI= (−0.25, 2.63), P = 0.10), the risk of PTB<32 weeks (OR = 0.88, 95%CI= (0.50, 1.54), P = 0.65), and pPROM<32 weeks (OR = 1.80, 95% CI= (0.41, 7.98), P = 0.44) were also comparable between the groups. Routine FLP of the placental anastomoses before 26 weeks of gestation is unlikely to be beneficial among asymptomatic stable stage I TTTS patients without cervical shortening as the procedure does not offer a survival advantage compared with expectant management. 相似文献
175.
Ershadi Mohammad Javad Qhanadi Taghizadeh Omid Hadji Molana Seyyed Mohammad 《Environmental science and pollution research international》2021,28(23):29394-29411
Environmental Science and Pollution Research - Nowadays budget and schedule constraints have forced organizations to select six sigma projects based on pre-defined success criteria. Also,... 相似文献
176.
Seidavi Alireza Tavakoli Masomeh Slozhenkina Marina Gorlov Ivan Hashem Nesrein M. Asroosh Fariborz Taha Ayman E. Abd El-Hack Mohamed E. Swelum Ayman A 《Environmental science and pollution research international》2021,28(35):47856-47868
Environmental Science and Pollution Research - Improving poultry production, increasing poultry immunity, and reducing the disease spreading can be achieved by adding various potentially valuable... 相似文献
177.
Aghamiri SM Ghorbani Z Darafsheh A Torabzadeh H Fathivand AA Minuchehr A Jalinoos A 《Journal of environmental radioactivity》2006,89(3):212-218
The level of natural radiation in some regions of Ramsar, a northern coastal city of Iran, is known to be among the highest levels of natural radiation in the world. 226Ra existing in high concentrations in the soil of this region is washed by underground water and transferred to the surface. In this way, 226Ra enters the food chain of residents and substitutes within the hard body tissues of humans. 226Ra is one of the so-called bone seekers as its metabolic processes in the human body are similar to calcium and remains in hard tissues of body because of its long half-life, and being an alpha emitter causes dangerous effects on human health. The purpose of this study is to determine the concentration of 226Ra in the teeth of residents of these high-level natural radiation areas, compared with a control group. Thirteen teeth in five groups were studied as the case group and thirteen teeth in five corresponding control groups were inspected. The mean values of the activity of 226Ra in the case group and in the control group were 0.32 and 0.18mBqg(-1), respectively. 相似文献
178.
Alireza A. Shamshirsaz Ramen H. Chmait Julien Stirnemann Mounira A. Habli Anthony Johnson Kamran Hessami Shayan Mostafaei Ahmed A. Nassr Roopali V. Donepudi Magdalena Sanz Cortes Jimmy Espinoza Eyal Krispin Michael A. Belfort 《黑龙江环境通报》2023,43(1):72-83
This meta-analysis aims to compare the perinatal outcome of twin-twin transfusion syndrome (TTTS) pregnancies undergoing selective versus vascular equator (Solomon) fetoscopic laser photocoagulation (FLP). We performed a systematic search in PubMed and Web of Science from inception up to 25 July 2021. Studies comparing the Solomon and selective techniques of FLP for treatment of TTTS pregnancies were eligible. Random-effects or fixed-effect models were used to pool standardized mean differences (SMD) and log odds ratio. Seven studies with a total of 1664 TTTS pregnancies (n = 671 undergoing Solomon and n = 993 selective techniques) were included. As compared to the selective FLP, Solomon was associated with a lower risk of recurrent TTTS compared to the selective technique (Log odds ratio [OR]: −1.167; 95% credible interval [CrI]: −2.01, −0.33; p = 0.021; I2: 67%). In addition, Solomon was significantly associated with a higher risk of placental abruption than the selective technique (Log [OR]: 1.44; 95% CrI: 0.45, 2.47; p = 0.012; I2: 0.0%). Furthermore, a trend for the higher risk of preterm premature rupture of membranes was observed among those undergoing Solomon (Log [OR]: 0.581; 95% CrI: −0.43, 1.49; p = 0.131; I2: 17%). As compared to selective FLP, the Solomon technique for TTTS pregnancies is associated with a significantly lower recurrence of TTTS; however, it significantly increases the risk of placental abruption. 相似文献
179.
Talaei Aisona Ashori Alireza Heydari Vahid 《Journal of Polymers and the Environment》2022,30(10):4263-4270
Journal of Polymers and the Environment - This study aims to make environment-friendly plywood panels acceptable in terms of both mechanical and physical properties using chitosan as a natural... 相似文献
180.
Pandiselvam Ravi Kaavya Rathnakumar Khanashyam Anandu Chandra Divya Valarivan Abdullah Sajeeb Khan Aurum Fawzan Sigma Dakshyani Rajendran Kothakota Anjineyulu Ramesh Shunmugiah Veluchamy Mousavi Khaneghah Amin 《Environmental science and pollution research international》2022,29(30):45131-45149
Environmental Science and Pollution Research - The application of pesticides enhances food production vastly, and it cannot be prevented; longer fresh produce is contaminated with... 相似文献