Modification of ferrite–manganese oxide sorbent by doping with cerium oxide

Fe–Mn oxide and Ce-doped Fe–Mn oxide sorbents were studied on the structural and desulfurization behavior in COS removal from syngas. The effects of cerium oxide on the Fe–Mn oxides have been investigated by XRD, BET, TPR, XPS and TEM methods. Analysis data show that the Ce-doped sorbent has larger specific surface area and better particles’ dispersion compared with non-modified Fe–Mn sorbent. The addition of Ce improves the reduction performance of Fe–Mn species. The desulfurization experiments show that the desulfurization activity of sorbent can be increased because of the promotion of the structural and redox properties by ceria doped. The Ce-doped sorbent can reduce COS from 15,000 ppmv to less than 0.1 ppmv at 325 °C and a space velocity of 1000 h⁻¹.     

河流水环境可视化仿真系统的开发

为了对河流进行有效管理,必须建立完善的河流水环境管理系统。计算机技术已广泛用于水环境管理。开发河流水环境可视化仿真系统是推进河流水环境管理科学化的主要工作之一。本文基于GIS平台,结合Vega虚拟现实仿真工具开发河流水环境可视化系统,不仅能够将各监测站点地理信息、河流水质信息等在GIS上展示,还实现了河流虚拟现实漫游的功能,为提升河流水环境管理水平提供基本的软件保障。     

中水回用工程投建与运行实践

沈阳理工大学学生城中水设施的建设，不仅提高了水资源的重复利用率，创造良好的环境效益和经济效益，同时也为中水回用工作的推广实施积累了经验。尤其是采用比较简单的污水处理工艺达到中水回用的标准，其中最主要的部分是沉淀和生物接触氧化以及最后的过滤和消毒，这样的工艺比较适合中等规模的投资，从回用水的经济效益上看这样的中水回用系统还是比较适合推广。     

渣油－水乳化液作为路面抑尘剂的研究

为了有效抑制汽车运输路面的扬尘，选择低浓度渣油－水乳化液作为抑尘剂，通过在实验室大量的试验，掌握了一组渣油乳化的最佳配方及其制备工艺，即渣油３％－６％，乳化剂约０．５％，水９３．５％－９６．５％，制备温度＞７０℃．经过室内和现场大规模试验表明，当路面喷洒量达到２．２ｋｇ／ｍ２时，其有效抑生时间达到１０ｄ以上，并且在一定程度起到养路的作用，长期使用可取得显著的综合经济效益．     

杭州交通噪声投诉点污染现状调查与防治

近年来杭州交通噪声投诉点主要分布在高架道路、立交桥和绕城高速附近的高层住户。对其中9个交通噪声投诉点的监测表明,昼间超4 a类标准的有4个,超标范围为0.1~7.6 dB;夜间9个点全部超4 a标准,超标范围为5.4~17.4 dB,夜间噪声超标特别严重。采用低噪声路面,设置隔声屏障,对敏感点安装通风隔声窗以及加强交通噪声管理等对策,可减轻交通噪声对敏感点的影响,从而减少交通噪声的投诉。     

Identification of close relationship between atmospheric oxidation and ozone formation regimes in a photochemically active region

Understanding ozone (O₃) formation regime is a prerequisite in formulating an effective O₃ pollution control strategy. Photochemical indicator is a simple and direct method in identifying O₃ formation regimes. Most used indicators are derived from observations, whereas the role of atmospheric oxidation is not in consideration, which is the core driver of O₃ formation. Thus, it may impact accuracy in signaling O₃ formation regimes. In this study, an advanced three-dimensional numerical modeling system was used to investigate the relationship between atmospheric oxidation and O₃ formation regimes during a long-lasting O₃ exceedance event in September 2017 over the Pearl River Delta (PRD) of China. We discovered a clear relationship between atmospheric oxidative capacity and O₃ formation regime. Over eastern PRD, O₃ formation was mainly in a NO_x-limited regime when HO₂/OH ratio was higher than 11, while in a VOC-limited regime when the ratio was lower than 9.5. Over central and western PRD, an HO₂/OH ratio higher than 5 and lower than 2 was indicative of NO_x-limited and VOC-limited regime, respectively. Physical contribution, including horizontal transport and vertical transport, may pose uncertainties on the indication of O₃ formation regime by HO₂/OH ratio. In comparison with other commonly used photochemical indicators, HO₂/OH ratio had the best performance in differentiating O₃ formation regimes. This study highlighted the necessities in using an atmospheric oxidative capacity-based indicator to infer O₃ formation regime, and underscored the importance of characterizing behaviors of radicals to gain insight in atmospheric processes leading to O₃ pollution over a photochemically active region.     

洗涤法处理含油土壤的研究

研究了用洗涤法处理含油土壤，考察了洗涤剂种类与浓度、洗涤温度、液固比、洗涤时间、表面活性剂、洗涤液直接循环使用次数对洗涤效果的影响，结果表明：当混合减浓度为10000mg／L、洗涤温度为70℃、液固比2：1、洗涤时间20min时，可将含油量为30％的土壤洗至残油率仅为0．3％左右。OP、EL型表面活性剂的加入对洗涤效果没有改善，特别有意义的是洗涤液能够直接循环使用而对洗涤效果基本无影响，这不仅能够减少用水量，还可以大大减少废水的排放量，降低操作费用及废水处理费用。该洗涤法不涉及物质的相变过程，混合碱由廉价的无机碱和无机盐组成，故能量消耗低，处理费用也低，且洗脱下来的原油可回收。     

光助-Fenton法处理均酐生产废水的实验研究

采用光助-Fenton处理均苯四甲酸二酐生产废水。以废水的TOC去除率为指标,通过单因素试验和正交试验,对影响光助-Fenton的因素进行分析。结果表明:室温下,在反应初始pH=3.5,[H2O2]=12mmol/L,[Fe2+]=1.5mmol/L,反应时间为80min,光源为500W汞灯的条件下,TOC的去除率NN达到76%。     

采取多种手段综合整治圆明园防渗工程

圆明园是北京市享誉中外的世界文化遗产公园，园内有140hm^2湖面，因湖水渗漏严重，每年要进行大量补水。为此圆明园管理处投资数千万，进行了湖底铺膜防渗工程，2005年4月份，接近完工的防渗工程被国家环保总局紧急停止。该项工程如何走出困境，本文从湖底开孔建渗水井，引进中水，以及湖水活化等多方面，提出一些合理化建议，希望以此构建一个水资源节约利用，而且可持续发展的湖区水生生态系统和一个和谐的园区人文景观。     

Seasonal variation and size distribution of biogenic secondary organic aerosols at urban and continental background sites of China

Size-resolved biogenic secondary organic aerosols(BSOA) derived from isoprene and monoterpene photooxidation in Qinghai Lake, Tibetan Plateau(a continental background site) and five cities of China were measured using gas chromatography/mass spectrometry(GC/MS). Concentrations of the determined BSOA are higher in the cities than in the background and are also higher in summer than in winter. Moreover, strong positive correlations(R2= 0.44–0.90) between BSOA and sulfate were found at the six sites,suggesting that anthropogenic pollution(i.e., sulfate) could enhance SOA formation,because sulfate provides a surface favorable for acid-catalyzed formation of BSOA. Size distribution measurements showed that most of the determined SOA tracers are enriched in the fine mode( 3.3 μm) except for cis-pinic and cis-pinonic acids, both presented a comparable mass in the fine and coarse( 3.3 μm) modes, respectively. Mass ratio of oxidation products derived from isoprene to those from monoterpene in the five urban regions during summer are much less than those in Qinghai Lake region. In addition, in the five urban regions relative abundances of monoterpene oxidation products to SOA are much higher than those of isoprene. Such phenomena suggest that BSOA derived from monoterpenes are more abundant than those from isoprene in Chinese urban areas.