Variance Design and Air Pollution Control

Confronted with shortages of low sulfur content residual fuel oil and, consequently, faced with the threat of social and economic upheaval, several air pollution control authorities in the Northeastern states were forced to relax hard-won air quality standards during the winter of 1972. The authorities did so by granting variances to their sulfur content standards for residual fuel oil. This paper examines the institutional characteristics of these variance policies from an economic incentive standpoint. After setting up desirable structural criteria for institutional design of such crisis policies, the authors examine the experience of the winter of 1972 and arrive at policy guidelines which recommend themselves for consideration in future periods of fuel oil shortages.     

Status and Problems of Regenerable Flue Gas Desulfurization Processes

Fourteen sulfur and/or sulfuric acid producing regenerate FGD processes were discussed at the 1974 FGD Symposium in Atlanta. During the period elapsed since then, considerable status change has occurred on many of these regenerable processes. Other regenerable processes which were not as well known during 1974 have surfaced in 1975. The problems of obtaining reducing gases (hydrogen sulfide, carbon monoxide, and hydrogen) for the reduction of sulfur dioxide product streams to elemental sulfur have become severe due to shortages of natural gas or other petroleum based feedstock. A new sulfur producing process which employs CO and H₂ directly (rather than the H₂S required for liquid and vapor base Claus reactions) is gaining attention. This paper discusses briefly: (1) the announced status of the many regenerable FGD processes, (2) the problem of reductant gas supply, and (3) the effect on FGD processes of using coal based reducing gas instead of reformed natural gas.     

Characterization of Particulates from Power Plants

The emphasis on participate control from industrial processes has been shifted recently towards fine particulates, having diameters less than 3 microns. There exists an urgent need for more scientific information of fine particle characterization.^1,2 Coal and oil fired power plants are among the largest anthropogenic point sources of particulate matter.³ Limited knowledge is available on particle size distribution and trace metal composition in power plant emissions.^4-7 The morphological properties of particle emissions have been largely neglected. In this report we present some information on particle characteristics for an oil-fired and coal-fired power plant.     

Desulfurization of Flue Gases in A Fluidized Bed of Modified Limestone

This publication concerns the dry removal of SO₂ from gases using limestone absorbents. It reports bench-scale experiments made with commercial samples of powdered limestone (CaCO₃) activated by addition of a cheap substance, namely CaCl₂. The absorption was carried out in a fluidized bed traversed by the flue gases, between 600° and 900° C. The degree and rate of transformation of CaCO₃ to CaSO₄ in the presence of SO₂ and air have been compared for unmodified and modified absorbents. Initial rates of reaction, and the variation of the rate of absorption with time have been measured. The influence of the SO₂ content of the gas has been assessed. At 700° C, the maximum degree of transformation of activated limestone to sulfate exceeds 90%, whereas untreated CaCO₃ transforms only to 16–20%. At the same temperature, more than 90% of SO₂ contained In a gas carrying 0.35% SO₂ is removed. Because of the much smaller quantity of solid absorbent required, dry absorption processes based on the modified absorbents might get renewed interest. The modified absorbents might also be used for in situ absorption in fluidized bed combustion, in which the temperatures are in the range studied in the present paper.     

The Effects of Precipitation on Aquatic and Terrestrial Ecosystems: A Proposed Precipitation Chemistry Network

Precipitation is one of the most important factors determining the nature and productivity of terrestrial and aquatic ecosystems. Detailed historical and contemporary records are available indicating the amount of water deposited at thousands of locations throughout the world. Comparatively, however, knowledge of the changing chemistry of precipitation has developed only recently and is still very fragmentary. Our present ignorance of the total impact of changes in precipitation quality on the productivity and stability of ecosystems is especially profound. This paper has a fourfold purpose: (1) to describe the myriad of trace chemical constituents transferred from the atmosphere into the biosphere of the earth; (2) to define the range of beneficial and injurious ecological effects of perturbations in atmospheric deposition; (3) to explain the concepts of sensitive areas, life stages, and life forms; and (4) to describe briefly plans for a National Deposition Network and associated research on the terrestrial and aquatic ecosystems of the United States.     

Urban-Center CO Air Quality Projections

The distribution of mutagenic activity and nitroaromatic components of polycyclic organic matter (POM) in ambient air at industrial, urban, suburban, rural, and remote sites was studied using organic extracts from high volume aerosol samples. Direct-acting mutagens including 1-nitropyrene (1-NP), dinitropyrenes (DNP), and hydroxynitropyrenes (HNP) were measured by high performance liquid chromatography while the mutagenicity was determined in the Salmonella bioassay with strain TA-98. Benzo(a)pyrene (BaP), one of the possible precursors of nitroaromatic compounds in POM, was also measured. In comparing samples from a range of sites, TSP and the concentration of BaP per mass of particulate matter decreased, as expected, at greater distances from urban and industrial combustion sources. However, the concentrations of polar nitroaromatic POM compounds per mass of particles were higher at a remote site than in nonindustrial urban and suburban areas. The mutagenicity in particulate matter extracts from the remote area was predominantly (>90 percent) in the very polar fractions. There were also high atmospheric levels of nitroaromatic compounds and mutagenicity in heavily industrialized areas. These observations may reflect the influences of source emissions, atmospheric transformations of POM compounds, and ther atmospheric processes on the composition of ambient suspended particulate matter.     

A Comparison of Mass,Lead, Sulfate,and Nitrate Concentrations in a Field Study Using Dichotomous,Size-Selective,and Standard Hi-Vol Samplers

Air monitoring In the San Francisco Bay Area was carried out to measure outdoor community air concentrations of poly cyclic aromatic hydrocarbons (PAH) and mutagenlc activity (mutagenlclty) In participate organic matter (POM). Monitoring began In 1979 and Is currently conducted at six stations. PAH and mutagenlclty tests were performed on organic extracts prepared from high volume (hl-vol) filters composited every four months, by meteorological season. PAH were determined by high pressure liquid chromatography (HPLC) with fluorescence and ultraviolet detection. Mutagenlclty was measured In the Ames Salmonella bloas-say using strain TA98 with and without metabolic activation. The nine-year mean concentration of benzo(a)pyrene (BaP) was 0.4 ng/m³. The mutagenlcfty of this amount of BaP accounted for only about 0.2% of the observed mutagenicity In POM and other measured PAH accounted for even less. Concentrations of PAH and mutagenlclty were three to nine times higher during the winter than during other seasons. Year-to-year wintertime trends In several PAH were also seen. Early In the 1980s, winter concentrations of BaP and benzo (g,h,i)perylene Increased. However since the mld-1980’s, their concentrations have fallen. The decrease In PAH concentrations may be the result of an Increasing proportion of vehicles with relatively low organic emissions. In contrast to PAH, mutagenlcfty did not show significant year-to-year time trends.     

The Inadequacy of PSD Increments to Protect Visibility in Class I Areas

This study includes an application of the first two phases of a new three-phased decision-making structure that was developed to overcome the problems related to ecological safety and social justice in site selection applications. It was conducted on a current site selection problem related to the municipal solid waste disposal facilities in Kocaeli, the most industrialized region of Turkey. In order to assess the deficiencies of the legal site selection procedures related to ecological safety, two different decision tree modes were applied separately. The first mode (“Legislation”) concerns the current buffer zone applications given in the regulations, while the second one (“Proposed”) includes the applications of the new decision-making structure proposed in this study. Since it was assumed that the subjective tendencies of the decision makers on the weightings would have a significant effect on the final decision, these two modes were assessed by employing two different weighting models. The results were obtained from all of the scenarios related to selection of suitable sites with three different area requirements (15, 250, and 500 acres) for the solid wastes generated in the Kocaeli region. The results showed that the possible changes in the decision structure could cause significant differences in the final decision related to selection of the most suitable sites. The most highest and lowest differences were at the “Legislation” mode for 15 acres and 500 acres, respectively. Furthermore, the results obtained in the study showed that the possible differentiations in the criteria weightings could also cause significant differences in the suitability ranking. Therefore, to get a reliable final decision, a statistical assessment of these differentiations should be made.

Implications: The results showed that the possible changes in the decision structure could cause significant differences in the final decision related to selection of the most suitable sites. Furthermore, the results obtained in the study showed that the possible differentiations in the criteria weightings could also cause significant differences in the suitability ranking. Therefore, to get a reliable final decision, a statistical assessment of these differentiations should be made.     

Interregional Exchanges of Air Pollution: Model Types and Applications

Regional scale air quality simulation models covering spatial scales of thousands of kilometers are finding increasing applications in studies of acid deposition and other air pollution problems. The purpose of this paper is to familiarize the nonexpert with the characteristics of the major types of interregional air quality models currently in use: Eulerian grid, statistical trajectory, and Lagrangian trajectory. The basic features, advantages, and disadvantages of each of these modeling approaches are summarized, as are the important limitations and problems associated with interregional modeling in general. Typical applications are illustrated using examples from the use of a representative Lagrangian trajectory model, ENAMAP, over the eastern North American area.