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Status of trace elements in paddy soil and sediment in Taihu Lake region 总被引:14,自引:0,他引:14
Thirteen paddy soil profiles and river sediments which are sources of irrigation water were collected around the Taihu Lake, and the trace elements were estimated. The content of La and Ce in paddy soil and sediment were 39.3 and 68.6 mg/kg soil and 36.9 and 65.1 mg/kg soil, being within the range of background values. The values for Pb, Cu, Ni, Cr, Co, Mn, Zn, Se in paddy soil were 23.3, 27.8, 25.5, 63.5, 10.2, 386, 68.7 and 0.25 mg/kg soil respectively, all below the national permission level. There was a decline of Zn in paddy soil. Some of the river sediments were seriously polluted. The river in Yangjin site was most contaminated with 5.47 g Cu/kg and 7.4 g Zn/kg. The high concentration of Pb and Ni also was observed in this sediment. River in Weitang, Huashi, Xinzhuang and Meiyan were contaminated with Pb, Cu and Ni to some extent. Zn, Cu and Pb were the main pollutants in present experiment sites. The fast development of village/township industries have caused severe environmental pollution in the Taihu Lake region, especially irrigation river sediments. Se content in plant and seed was 0.04 and 0.03 mg/kg respectively, showed Se-deficiency in paddy soil in the Taihu Lake region. 相似文献
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Ling R. Zeng Li H. Shi Xin G. Meng J. Xu Gui F. Jia T. Gui 《Journal of environmental science and health. Part. B》2019,54(4):317-325
This study evaluated the hydrolysis and photolysis kinetics of pyraclostrobin in an aqueous solution using ultra-high-performance liquid chromatography–photodiode array detection and identified the resulting metabolites of pyraclostrobin by hydrolysis and photolysis in paddy water using high-resolution mass spectrometry coupled with liquid chromatography. The effect of solution pH, metal ions and surfactants on the hydrolysis of pyraclostrobin was explored. The hydrolysis half-lives of pyraclostrobin were 23.1–115.5?days and were stable in buffer solution at pH 5.0. The degradation rate of pyraclostrobin in an aqueous solution under sunlight was slower than that under UV photolysis reaction. The half-lives of pyraclostrobin in a buffer solution at pH 5.0, 7.0, 9.0 and in paddy water were less than 12?h under the two light irradiation types. The metabolites of the two processes were identified and compared to further understand the mechanisms underlying hydrolysis and photolysis of pyraclostrobin in natural water. The extracted ions obtained from paddy water were automatically annotated by Compound Discoverer software with manual confirmation of their fragments. Two metabolites were detected and identified in the pyraclostrobin hydrolysis, whereas three metabolites were detected and identified in the photolysis in paddy water. 相似文献
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Ting Gui Gui F. Jia Jin Xu Shi J. Ge Xiao F. Long 《Journal of environmental science and health. Part. B》2019,54(4):326-335
A modified quick, easy, cheap, effective, rugged and safe (QuEChERS) method was developed for the determination of thiamethoxam and its metabolite clothianidin in citrus (including the whole citrus, peel and pulp) and soil samples by liquid chromatography-tandem mass spectrometry. The sample was extracted with acetonitrile and purified with octadecylsilane. The detection limits of both compounds were 0.0001–0.0002?mg kg–1, while the limit of quantification of thiamethoxam was 0.002?mg kg–1 and the limit of quantitation of metabolites was 0.001?mg kg–1. The recovery was 70.37%–109.76%, with inter-day relative standard deviations (RSD) (n?=?15) values ≤9.46% for the two compounds in the four matrices. The degradation curve of thiamethoxam in whole citrus and soil was plotted using the first-order kinetic model. The half-life of the whole citrus was 1.9–6.2?days, and the half-life of the soil was 3.9–4.2?days. The terminal residue of thiamethoxam (the sum of thiamethoxam and clothianidin, expressed as thiamethoxam) was found to be concentrated on the peel. The final residual amount of thiamethoxam in the edible portion (pulp) was less than 0.061?mg kg–1. The risk quotient values were all below 1, indicating that thiamethoxam as a citrus insecticide does not pose a health risk to humans at the recommended dosage. 相似文献
55.
Guo Jun-Xiong Pan Jie Wang Jing Wang Fei Shi Hong-Xin 《Environmental science and pollution research international》2019,26(20):20499-20509
Environmental Science and Pollution Research - Drinking water containing environmental endocrine disruptor compounds (EDCs) endangers human health, and researching the purification process of... 相似文献
56.
Shen Yanru Zhao Wenyan Zhang Chunling Shan Yujie Shi Junxian 《Environmental science and pollution research international》2017,24(16):14337-14345
Environmental Science and Pollution Research - Streptomycin used in human and veterinary medicine is released into the environment mainly through excretions. As such, its elimination in water... 相似文献
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生态滤池处理城市污水小试研究 总被引:2,自引:0,他引:2
生态滤池(MEEF)是利用由微生物和蚯蚓为代表的微型动物共同组成的人工生态系统,对城镇污水中的污染物进行降解处理的新型污水处理技术。采用单层滤池和复合床滤池进行实验,在相同的实验条件下,对生态滤池和无蚯蚓滤池的运行效果进行了比较。运行初期,生态滤池的出水水质稍优于无蚯蚓滤池,特别是悬浮物浓度低;运行半月后,无蚯蚓滤池表面积泥,出现厌氧情况,出水水质变差,而生态滤池至少正常运行1个月。复合床生态滤池连续进水运行,水力负荷达到2.0m3/m2·d,COD去除率达80%以上,出水SS浓度<5mg/L。结果表明,蚯蚓在维持滤池的正常运行起着重要作用。最后介绍了生态滤池中各种生物的作用及生态滤池的工作原理。 相似文献