全文获取类型
收费全文 | 446篇 |
免费 | 26篇 |
国内免费 | 233篇 |
专业分类
安全科学 | 36篇 |
废物处理 | 35篇 |
环保管理 | 38篇 |
综合类 | 266篇 |
基础理论 | 85篇 |
污染及防治 | 178篇 |
评价与监测 | 25篇 |
社会与环境 | 18篇 |
灾害及防治 | 24篇 |
出版年
2023年 | 15篇 |
2022年 | 17篇 |
2021年 | 20篇 |
2020年 | 22篇 |
2019年 | 20篇 |
2018年 | 24篇 |
2017年 | 24篇 |
2016年 | 35篇 |
2015年 | 51篇 |
2014年 | 38篇 |
2013年 | 54篇 |
2012年 | 50篇 |
2011年 | 38篇 |
2010年 | 33篇 |
2009年 | 29篇 |
2008年 | 26篇 |
2007年 | 39篇 |
2006年 | 17篇 |
2005年 | 16篇 |
2004年 | 10篇 |
2003年 | 13篇 |
2002年 | 20篇 |
2001年 | 8篇 |
2000年 | 10篇 |
1999年 | 17篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 1篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
排序方式: 共有705条查询结果,搜索用时 125 毫秒
51.
Sulfur poisoning of V_2O_5/BaSO_4–TiO_2(VBT),V_2O_5/WO_3–TiO_2(VWT) and V_2O_5/BaSO_4–WO_3–TiO_2(VBWT) catalysts was performed in wet air at 350℃ for 3 hr,and activities for the selective catalytic reduction of NO_x with NH_3 were evaluated for 200–500℃.The VBT catalyst showed higher NO_x conversions after sulfur poisoning than the other two catalysts.The introduction of barium sulfate contributed to strong acid sites for the as-received catalyst,and eliminated the redox cycle of active vanadium oxide to some extent,which resulted in a certain loss of activity.Readily decomposable sulfate species formed on VBT-S instead of inactive sulfates on VWT-S.These decomposable sulfates increased the number of strong acid sites significantly.Some sulfate species escaped during catalyst preparation and barium sulfate was reproduced during sulfur poisoning,which protects vanadia from sulfur oxide attachment to a great extent.Consequently,the VBT catalyst exhibited the best resistance to sulfur poisoning. 相似文献
52.
Rice husk with high volatile content was burned in a pilot scale vortexing fluidized bed incinerator. The fluidized bed incinerator was constructed of 6 mm stainless steel with 0.45 m in diameter and 5 m in height. The emission characteristics of CO, NO, and SO2 were studied. The effects of operating parameters, such as primary air flow rate, secondary air flow rate, and excess air ratio on the pollutant emissions were also investigated. The results show that a large proportion of combustion occurs at the bed surface and the freeboard zone. The SO2 concentration in the flue gas decreases with increasing excess air ratio, while the NOx concentration shows reverse trend. The flow rate of secondary air has a significant impact on the CO emission. For a fixed primary air flowrate, CO emission decreases with the secondary air flowrate. For a fixed excess air ratio, CO emission decreases with the ratio of secondary to primary air flow. The minimum CO emission of 72 ppm is attained at the operating condition of 40% excess air ratio and 0.6 partition air ratio. The NOx and SO2 concentrations in the flue gas at this condition are 159 and 36 ppm, which conform to the EPA regulation of Taiwan. 相似文献
53.
Bacterial strain Enterobacter aerogenes TJ-D capable of utilizing 2-methylquinoline as the sole carbon and energy source was isolated from acclimated activated sludge under denitrifying conditions. The ability to degrade 2-methylquinoline by E. aerogenes TJ-D was investigated under denitrifying conditions. Under optimal conditions of temperature (35℃) and initial pH 7, 2-methylquinoline of 100 mg/L was degraded within 176 hr. The degradation of 2-methylquinoline by E. aerogenes TJ-D could be well described by the Haldane model (R2 > 0.91). During the degradation period of 2-methylquinoline (initial concentration 100 mg/L), nitrate was almost completely consumed (the removal efficiency was 98.5%), while nitrite remained at low concentration (< 0.62 mg/L) during the whole denitrification period. 1,2,3,4-Tetrahydro-2-methylquinoline, 4-ethyl-benzenamine, N-butyl-benzenamine, N-ethyl-benzenamine and 2,6-diethyl-benzenamine were metabolites produced during the degradation. The degradation pathway of 2-methylquinoline by E. aerogenes TJ-D was proposed. 2-Methylquinoline is initially hydroxylated at C-4 to form 2-methyl-4-hydroxy-quinoline, and then forms 2-methyl-4-quinolinol as a result of tautomerism. Hydrogenation of the heterocyclic ring at positions 2 and 3 produces 2,3-dihydro-2-methyl-4-quinolinol. The carbon-carbon bond at position 2 and 3 in the heterocyclic ring may cleave and form 2-ethyl-N-ethyl-benzenamine. Tautomerism may result in the formation of 2,6-diethyl-benzenamine and N-butyl-benzenamine. 4-Ethyl-benzenamine and N-ethyl-benzenamine were produced as a result of losing one ethyl group from the above molecules. 相似文献
54.
55.
56.
Shiping Zhou Changqun Duan Wong Hang Gi Michelle Fazhong Yang Xuehua Wang 《环境科学学报(英文版)》2011,23(4):676-680
Toxicities were assessed for a pyrethroid (cypermethrin) and an organophosphate insecticide (chlorpyrifos) individually and in
combination. A series of tests were conducted on di erent responses (acute, chronic, behavioral) of earthworms of species Eisenia
fetida andrei in the ecological risk assessment of these pesticides. The results showed that the toxicity of the mixture of cypermethrin
and chlorpyrifos was significantly higher than either of these pesticides individually, especially on the earthworm’s chronic responses.
At a concentration of 5 mg/kg, the mixture caused significant reductions on the growth and reproduction rates of earthworms, but did
not cause any significant e ect when the individual was tested. The increase in toxicity of the pesticide mixture means that the use of
toxicity data obtained exclusively from single-pesticide experiments may underestimate the ecological risk of pesticides that actually
present in the field. 相似文献
57.
Potassium-modified ceria-zirconia catalyst was synthesized by wetness impregnation method. The ageing treatment was performed in static air at 800℃ for 20 hr to evaluate the thermal stability of the catalyst. The catalysts were characterized by X-ray diffraction,BET surface area, oxygen storage capacity, NOx-temperature programmed desorption and soot-temperature programmed oxidation measurements. By introduction of potassium, the maximum soot oxidation rate temperature (Tm) of the ceria-zirconia based catalyst decreased from 525 to 428℃ in the presence of NO under a loose contact mode. The shift of Tm of the K-modified catalyst after ageing is only 15℃. The enhanced activity of the aged catalyst mainly lies in the promotional effect of potassium on the NOx/oxygen storage cacity as well as the soot-catalyst contact. 相似文献
58.
Preliminary report on methane emissions from the Three Gorges Reservoir in the summer drainage period 总被引:3,自引:0,他引:3
Fei Lu Le Yang Xiaoke Wang Xiaonan Duan Yujing Mu Wenzhi Song Feixiang Zheng Junfeng Niu Lei Tong Hua Zheng Yongjuan Zhou Jiangxiao Qiu Zhiyun Ouyang 《环境科学学报(英文版)》2011,23(12):2029-2033
Considerable variations may exist in CH4 emissions from the Three Gorges Reservoir. 相似文献
59.
应用氢化物原子荧光法,测定鲤鱼肝脏中痕量Hg和As,该法具有原子吸收和原子发射光谱两种技术优势,同时它具有分析灵敏度高,干扰少,线性范围宽,可多元素同时测定等优点;在KBH4-酸还原体系中同时测定鱼肝中Hg和As,方法检出限分别为Hg:0.33ng/ml和As0.36ng/ml,线性范围分别为:0.1-2.0ng/ml和1.0-20.0ng/ml。加标回收率分别为Hg:96.0%和As:100.6%。分析结果可靠,方法令人满意,并适合大批量样品的分析。 相似文献
60.