Evaluating peats for their capacities to remove odorous compounds from liquid swine manure using headspace “solid‐phase microextraction”

Abstract

This paper reports on research designed to investigate the capacities of different highly characterized peats to remove odorous compounds from liquid swine manure (LSM). Peat types representing a wide range of properties were tested in order to establish which chemical and physical properties might be most indicative of their capacities to remediate odors produced by LSM. Eight percent slurries (of peat/LSM) were measured for odor changes after 24 hours using odor panel and GC/MS‐Solid‐phase microextraction (GC/MS‐SPME) analysis.

The GC/MS‐SPME and odor panel results indicated that, although all peats tested in this study were found to be effective at removing odor‐causing compounds found in LSM, some peats tended to work better than others. Overall, the peats that were the most effective at removing odor‐causing compounds tended to have lower bulk densities, ash contents, fulvic acids contents, and guaiacyl lignins contents,and higher water holding capacities, hydraulic conductivities, “total other lignins”; contents, hydrogen contents, carbon contents, and total cellulose contents.

GC/MS‐SPME analysis was found to be a reasonably inexpensive and efficient way of conducting this type of research. It allows one to identify a large number of the odor‐causing compounds found in LSM, and more importantly, to detect with some precision specific differences in the amounts of these compounds between peat types.     

Household Valuation of Curbside Recycling

This paper looks at the willingness to pay for, and participate in, a curbside recycling programme based on a survey of 401 residents in Ogden, Utah. Modifying the Cameron & James (1987) econometric model to fit ordered-interval data, we estimate that the mean willingness to pay for curbside recycling is US $2.05 per month, and that 72% of the residents would willingly participate in such a programme. Furthermore, females, young people, college-educated, those currently recycling without monetary reward, those regarding recycling as beneficial to the community and nation, and those with relatively high incomes are willing to pay the most for curbside recycling.     

WATER QUALITY MANAGEMENT: THE CASE FOR RIVER BASIN AUTHORITIES1

ABSTRACT: There is a lamentable absence of comprehensive planning in the current cursade to improve water quality. A serious shortcoming is the lack of evaluation of the effects of waste water treatment upon environmental quality. At some point in time the public may ask what they have obtained for their money. The nature of pollution in a river basin demands a coordinated attack against it. Engineering and economic criteria suggest that a properly empowered river basin authority would be the logical organization to plan and operate a water quality management system. Several forms of such authorities have operated effectively and efficiently for many years in the United States and other industrialized countries. Examples of successful river basin authorities and their advantages and methods of operation are discussed.     

QUALITY ASSURANCE TECHNIQUES FOR ELECTRONIC DATA ACQUISITION1

ABSTRACT: Electronic instruments are increasingly being used to gather water quality data. Quality assurance protocols are needed which provide adequate documentation of the procedures followed in calibration, collection, and validation of electronically acquired data. The level of precision of many data loggers exceeds the technology which is commonly used to make field measurements. Overcoming this problem involves using laboratory quality equipment in the field or enhanced quality control at the time of instrument servicing. Time control procedures for data loggers are needed to allow direct comparisons of data between instruments. Electronic instruments provide a mechanism to study transient events in great detail, but, without time controls, multiple loggers produce data which contain artifacts due to timing errors. Individual sensors deployed with data loggers are subject to different degrees of drift over time. Certain measurements can be measured with defined precision and accuracy for long periods of time, while other sensors are subject to loss of both precision and accuracy with increasing time of use. Adequate quality assurance requires the levels of precision and accuracy be documented, particularly those which vary with increasing time deployment.     

WATERSHED MANAGEMENT MANPOWER AND EMPLOYER SURVEY1

ABSTRACT: Two surveys were conducted to determine the supply and demand for students trained in watershed management in the United States. The first survey of 23 educational institutions was conducted in 1978. Annual production of about 100 watershed graduates and employment success greater than 85 percent at all degree levels was indicated. The second survey of watershed employment within the U.S. Forest Service (conducted in 1979) indicated one-third of the annual supply of watershed graduates could be employed by the agency; a fact verified by employment data supplied by educational institutions.     

Environmental problem-solving and land-use management: A proposed structure for Australia

A three-tiered structure of land-use and environmental management is here proposed for Australia. The structure is based on the idea that environment means the environment of people, and that environmental problems arise when a change in the interaction between people and their environment leads to conflicts about the use of land and resources. The heterogeneity of society means that a range of human aspirations and value systems must be satisfied by environmental managers. Existing methods of environmental management fail to achieve these objectives, due to inadequate perception of environmental problems by decision-makers, and the inability of currently available impact assessment techniques to resolve human conflicts associated with the use of land and resources. The main work of planning and managing land use and the environment would be carried out by regional authorities, supported by federal and state policy. Examples are given of moves towards regional administration in England and Wales, Western Australia, Australia and New Zealand. Community participation in the decision-making process is essential and can be achieved by electoral representation to the authoritative bodies and through procedures that ensure informed public comment on planning proposals.     

IMPACT OF THERMAL STANDARDS ON POWER PLANT WATER CONSUMPTION1

Power plant water consumption (evaporative water loss) for various river temperature standards is presented for existing and proposed power plants located along the Missouri and Upper Mississippi Rivers in the MAPP geographical area. Thermodynamic and economic models are combined to evaluate the cooling related water consumption at various river thermal standards. The existing thermal standards and a number of other hypothetical thermal regulations including the extreme cases of no thermal standards and no allowable heated discharges are examined to show the dependence on thermal standards of power production related water consumption. A critical appraisal of the cost of thermal standards in terms of water consumption is thereby possible so that subjective assessments of the standards can proceed with full knowledge of the tradeoffs involved between the “water costs” of power production and environmental enhancement.     

INCREASES IN SODIUM AND CHLORIDE IN THE MOHAWK RIVER,NEW YORK,FROM THE 1950'S TO THE 1970'S ATTRIBUTED TO ROAD SALT1

Regression analyses of major ion concentration in relation to specific conductance of water from the Mohawk River during two separate periods, 1951–53 and 1970–74, indicate statistically insignificant changes in the linear relationship of all constituents studied except chloride. Mean values and changes in the slopes of these relationships indicate that sodium and chloride have had consistently higher yields, in kilograms per square kilometer per year, than the other ions, although all ions show a general 20 percent increase in yields during the two decades. This general increase in ion yields is attributed to an accelerated transport rate of ions out of the basin as a result of a 19 percent increase in mean stream discharge. Transport rates of sodium and chloride have increased by 72 and 145 percent, respectively, in the Mohawk River since the early 1950's. Analysis of the sodium and chloride sources indicates rock salt used as a road deicei to be the primary source. This salt use accounts for 96 percent of the sodium transport increase and 69 percent of the chloride transport increase within the basin during the last two decades.     

ANALYSIS OF WASTE LOAD ALLOCATION PROCEDURES1

A study was made to analyze and modify procedures used for stream assimilation capacity and point source wasteload allocation calculations. This paper describes the sources and types of information collected and the analysis of alternative computation methods developed during the study. The calculation of stream assimilation capacity or Total Maximum Daily Load (TMDL), will depend upon assumed stream flows, quality standards, reaction rates, and modeling procedures. The “critical conditions” selected for TMDL calculations usually are low flows and warm temperatures. The complexity of water quality models used for TMDL and allocation calculations can range from simple, complete mixing to calibrated and verified mathematical models. A list of 20 wasteload allocation (WLA) methods was developed. Five of these WLA's were applied to an example stream to permit comparisons based on cost, equity, efficient use of stream assimilation capacity, and sensitivity to fundamental stream quality data. Based on insensitivity to data errors and current use by several states, the WLA method of “equal percent treatment” was preferable in the example stream.