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661.
Kukkola J Knuutinen J Paasivirta J Herve S Pessala P Schultz E 《Environmental science and pollution research international》2011,18(7):1049-1056
Background, aims, and scope
Currently, elemental chlorine-free (ECF) and totally chlorine-free (TCF) bleaching systems are widely used for pulp production. Low and medium molecular weight lignin break-down products are known to have harmful effects on the environment. According to some recent results, also high molecular weight (HMW) material consisting mainly of lignin and carbohydrates may cause toxic effects to the environment. For these reasons, toxicity and structure studies of HMW materials are of great importance. This investigation is a part of a larger project to obtain more structure information of HMW materials and toxicity of ECF and TCF bleaching effluents. Size-exclusion chromatography (SEC) has been commonly used for the characterization of organic macromolecules such as lignin, but to our knowledge, no reports have appeared dealing with the comparison of SEC of ECF and TCF bleaching liquors. The aim of the present study was to get more information about the molecular weight distribution (MWD) of HMW fractions of waste liquors from ECF and TCF bleaching sequences by SEC. 相似文献662.
Lu Q He ZL Graetz DA Stoffella PJ Yang X 《Environmental science and pollution research international》2011,18(6):978-986
Background, aim and scope
Water quality impairment by heavy metal contamination is on the rise worldwide. Phytoremediation technology has been increasingly applied to remediate wastewater and stormwater polluted by heavy metals. 相似文献663.
Ventura-Lima J Ramos PB Fattorini D Regoli F Ferraz L de Carvalho LM Monserrat JM 《Environmental science and pollution research international》2011,18(8):1270-1278
Introduction
This study aimed to analyze antioxidant responses and oxidative damage induced by two inorganic forms of arsenic (As; AsIII and AsV) in an estuarine polychaete species, Laeonereis acuta (Nereididae). The capacity of arsenic biotransformation was also evaluated through the methylation process considering the activity of a key enzyme involved in the metabolization process. 相似文献664.
Zhang XL Luo XJ Liu J Luo Y Chen SJ Mai BX 《Environmental science and pollution research international》2011,18(4):556-565
Purpose
Birds have been used successfully for biomonitoring of the levels and effects of persistent organic pollutants (POPs) in the environments; however, there is exceedingly little data on organochlorinated pesticide (OCPs) and polychlorinated biphenyls (PCBs) residues in bird inhabiting in China. In the present study, we detected the concentrations of PCBs, dichlorodiphenyltrichloroethane and its metabolites (DDTs) and hexachlorocyclohexanes (HCHs) in muscle, liver and kidney of birds that inhabit in an e-waste recycling site. Associated with the stable isotope ratio (δ 15N), we investigated the effect of trophic level on the body burdens of persistent contaminants in birds. The tissue distributions of contaminants in these birds were examined, and a preliminary risk assessment was also conducted. 相似文献665.
Yuan-yuan Wei Yan Liu Yun Zhang Rui-hua Dai Xiang Liu Jin-jian Wu Qiang Zhang 《Environmental science and pollution research international》2011,18(1):46-50
Introduction
Effluent organic matter from biological wastewater treatment plants is composed of degradation products and soluble microbial products (SMP). Protein, polysaccharide, humic acid, and DNA were major biomolecules of SMP. Little is known about the effects of SMP as microbially derived precursors on disinfection byproduct formation and speciation in biologically treated wastewater. In addition, there has never been any attempt to directly chlorinate the major biomolecules of SMP. 相似文献666.
Purpose
The most significant application of polychlorinated biphenyls (PCBs) is in transformers and capacitors. Therefore, power plants are important suspected sources for entry of PCBs into the environment. In this context, the levels and distribution of PCBs in sediment, soil, ash, and sludge samples were investigated around Seyitömer thermal power plant, Kütahya, Turkey. Moreover, identity and contribution of PCB mixtures were predicted using the chemical mass balance (CMB) receptor model.Methods
United States Environmental Protection Agency methods were applied during sample preparation, extraction (3540C), cleanup (3660B, 3665A, 3630C), and analysis (8082A).Results
ΣPCB concentrations in the region ranged from not detected to 385 ng/g dry weight, with relatively higher contamination in sediments in comparison to soil, sludge, and ash samples collected from around the power plant. Congener profiles of the sediment and soil samples show penta-, hexa-, and hepta-chlorobiphenyls as the major homolog groups. The results from the CMB model indicate that PCB contamination is largely due to Clophen A60/A40 and Aroclor 1254/1254(late)/1260 release into the sediment and sludge samples around the thermal power plant.Conclusions
Since there are no other sources of PCBs in the region and the identity of PCB sources estimated by the CMB model mirrors PCB mixtures contained in transformers formerly used in the plant, the environmental contamination observed especially in sediments is attributed to the power plant. Release of PCBs over time, as indicated by the significant concentrations observed even in surface samples, emphasizes the importance of the need for better environmental management.667.
Trier X Granby K Christensen JH 《Environmental science and pollution research international》2011,18(7):1108-1120
Introduction
In this study, we explore the identity of a range of polyfluorinated surfactants (PFS) used for food contact materials, primarily to impart oil and water repellency on paper and board. PFS are of interest, as they can be precursors of poly- and perfluorinated alkyl substances (PFAS), of which several are persistent and are found worldwide in human blood and in the environment. 相似文献668.
Burskyte V Belous O Stasiskiene Z 《Environmental science and pollution research international》2011,18(5):716-726
Introduction
In 2003, the Japan International Cooperation Agency carried out a development feasibility study of Klaipeda Seaport (Lithuania). The focus in this study was the evaluation of environmental impacts of the port expansion because it is located in an ecologically sensitive area. While the Japanese researchers focused on the environmental impact analysis, they did not provide unambiguous conclusions. The problems remained unresolved and required further, more detailed consideration and deeper analysis. 相似文献669.
Stefanie Grund Eric Higley René Schönenberger Marc J-F. Suter John P. Giesy Markus Hecker Henner Hollert 《Environmental science and pollution research international》2011,18(3):446-460
Introduction
The present study was part of a comprehensive weight-of-evidence approach with the goal of identifying potential causes for the declines in fish populations, which have been observed during the past decades in the Upper Danube River. 相似文献670.