Instrumenting Light Aircraft for Air Pollution Research

Light aircraft and helicopters have been occasionally used to conduct aerial traverses for a single pollutant or atmospheric tracer. The continuous analyzer or sample collector is temporarily tied down with a seat belt or hand held. Flight variables are visually observed and written on the recorder chart, a notebook or possibly voice-recorded on a portable tape recorder. The versatile airborne instrumentation package described can measure and record up to 27 pollutant and flight variables from a Cessna Skymaster center-line thrust, light twin. Real-time analysis instrumentation include non-dispersive infrared analyzers for CO₂, CO, and hydrocarbons, conductivity and coulometric analyzers for sulfur dioxide and sulfur-containing gases, and Charlson-Ahlquist visual range nephelometer. A Battelle “bulk sampler” is used to collect particulates for weighing and microscopic examination. Indicated air speed, altitude, rate of climb, magnetic heading, temperature, and relative humidity are continuously measured. All variables are sequentially recorded on a 7-track, 200 bit per second, 27-channel, magnetic tape data logging system. Measured variables are recorded once each 0.3 to 0.8 sec—equivalent to 33-100 ft of traversedepending upon the number of variables recorded (i.e., between 9 and 27) when flying at 90 mph. Tape data are reduced directly by IBM 360 computer to a digital print-out or from tape to an X-Y analog plot.     

Annotated Bibliography for Air Pollution Meteorology

This annotated bibliography was prepared for the purpose of directing interested persons to some of the more helpful references in the field of air pollution meteorology. It obviously is not a complete listing. The reader who requires more information is directed to the references in the articles listed.     

Appraisal of Odor-Measurement Techniques

All odor measurement methods may be conveniently grouped into three categories: (1) threshold; (2) suprathreshold; and (3) analytical. The threshold techniques include such methods as syringe dilution, scentometer, and osmoscope. Suprathreshold techniques include direct comparison methods and dilution methods involving subjective ratings of preference as opposed to intensity. Analytical techniques involve the use of physicochemrcal methods, e.g., for monitoring of process streams or identification of individual odorants. The relative advantages and disadvantages of each method, as presently used, are discussed. Recommended applications for the various methods and suggested modifications are also presented.     

A Comparative Study of Particulate Loadings in Plumes Using Multiple Sampling Devices

Particle size distributions, particulate concentrations, and particle identities must be known to relate effluents to reduction in visibility and soiling. Similar types of emissions were measured with cascade impactor, membrane filter, and rotorod samplers. The different particle size distributions, concentrations, and identifications are reported. Discussion of and recommendations for utilization of these three methods of sampling are made.     

Tracer Study In an Urban Valley

Results of a series of nighttime tracer experiments conducted during the Autumn of 1966 in the industrialized valley of Johnstown, Pa., are discussed. Quite atypical meteorology and dispersion occur within a classical drainage flow framework. An urban heat island effect is observed creating uniform temperature and wind structures within a layer of air flowing through the valley. Dispersion in the valley at night is comparable to that of neutral conditions over open country.     

The Effects of Some Air Pollutants and Meteorological Conditions on Airborne Algae and Protozoa

The purpose of this investigation was to determine the effects of meteorological conditions and specific air pollutants on the viability of airborne algae and protozoa. Such investigations will be of interest to medical researchers because these organisms are the source of many allergies. The three air pollutants that were continuously measured and recorded were sulfur, hydrocarbons, and particulate maiter. During the experiment, 25 different species of algae and 19 species of protozoa were collected from the atmosphere and cultured at the Westinghouse Environmental Station Laboratory in Raleigh, North Carolina. The algae and protozoa were collected over a one-year period (Jan-Dec 1971) by using a sequential sampler that moved air through a membrane filter at the rate of 15 ft³/hr. Every two hours a new filter was sequentially moved in to replace the old one. The results indicated a relationship between wind speed, wind direction, temperature, dew-point, particulate matter, barometric pressure, and rainfall to the percent frequency of positive culture tubes and number of cells/ft³ of air. Further studies are necessary to determine the interrelationships between the physical and chemical character of various air masses and their effect on the survival of algae and protozoa.     

The Effect of Fuel Composition on Atmospheric Aerosol Due to Auto Exhaust

Aerosols attributable to automobile exhaust can be classified as two types—primary aerosol (initially present in the exhaust) and secondary aerosol (generated photochemically from hydrocarbons and nitrogen oxides in the exhaust). In this study, investigation was made of possible effects of motor-fuel composition on the formation of these aerosols. Secondary aerosol, of principal interest in this work, was produced by irradiating auto exhaust in Battelle-Columbus’ 610 ft³ environmental chamber. A limited number of determinations of primary aerosol in diluted auto exhaust was made at the exit of a 36 ft dilution runnel. Determination of both primary and secondary aerosol was based on light-scattering measurements.

Exhaust was generated with seven full-boiling motor gasolines, both leaded and nonleaded, in a 1967 Chevrolet which was not equipped with exhaust-emission control devices. Changes in fuel composition produced a maximum factor of three difference in light scattering due to primary aerosol. Aerosol yields, for consecutive driving cycles on the same fuel, vary considerably; as a result, ranking the fuels on the basis of average primary aerosol yield was not very meaningful. In addition to fuel composition, the more important independent variables are initial SO₂ concentration, relative humidity and initial hydrocarbon concentration. Statistical analysis of the data indicates that the seven test fuels can be divided into two arbitrary groups with regard to secondary aerosol-forming potential. The fuels in the lower light-scattering group had aromatic contents of 15 and 21%, while those in the higher light-scattering group had aromatic contents of 25, 48, and 55%. Although the fuels can be grouped on the basis of a compositional factor, the grouping of fuels with aromatic content ranging from 25 to 55% indicates that this compositional factor cannot be equated simply with aromatic content. In an associated study of the aerosol-forming potential of individual hydrocarbons prominent in auto exhaust, it was observed that aromatics produce substantially more photochemical aerosol than olefins and paraffins. However, experiments with binar/hydrocarbon mixtures containing aromatjcs, as well as in these exhaust experiments, a strong dependence of aerosol yield on the aromatic components is is not observed. Thus, the data indicate that the dependence of secondary aerosol formation on fuel factors is a complex one and cannot be predicted solely on the basis of a sirigle hydrocarbon component reactivity scale.

The two types of automobile aerosol did not have the same dependence on fuel, composition. The variation in total light scattering attributable to primary plus secondary aerosol was less than that due to either component alone. It therefore was concluded that the light scattering due to automobile exhaust emissions in these experiments was not significantly affected by changing fuel composition.     

On the Relation Between the Indoor and Outdoor Concentrations of Nitrogen Oxides

Simultaneous measurements were made of the concentrations of NO, NO₂, and CO inside and outside of a building. The building is located in the Los Angeles area, which is heavily polluted by photochemical smog, and the experiments were conducted at a time of the year when the pollutants in question tend to be high. The results shows that there is a direct relationship between the inside and outside concentrations, and that the phase lag between the concentrations depends principally on the ratio of the building volume to the ventilation rate. Although the outside concentrations of the pollutants in question did not follow the same pattern every day, peak concentrations seemed to be related to “rush-hour” traffic. By reducing ventilation rates during these periods, it may be possible to reduce the concentration peaks inside of the building. The building involved in the current study was not located in the immediate vicinity of heavy traffic, and the indoor concentrations of NO, NO₂, and CO did not appear to be very severe when compared to those defined by present air quality standards. Finally, the results support the belief that NO and O₃ do not co-exist indoors except in very small quantities.     

Evaluation of the Effectiveness of The Lead Peroxide Method for Atmospheric Monitoring of Sulfur Dioxide

This paper presents a simplified analysis to determine the variables that affect the empirical correlation factor used in the lead peroxide method. The rate of sulfation has been determined from two different models. In the first model, the mass transfer rate is calculated from the gas phase resistance alone whereas in the second model, the diffusion resistance in the gel phase is assumed to be the rate limiting step. Although the gas phase and the gel phase resistances may be both important in the actual case, it has been found that the correlation factor based on the first model is adequate to describe general experimental observations. Reasonable agreement has been obtained between the measured and the calculated va|ue of the correlation factor.