A model for positive environmental control

In the control of pollution, two apparently important facts are often negelected: (1) removal of a particular pollutant from a particular source and location may merely result in transforming it into a pollutant, or pollutants of different forms, in other locations; (2) the activity of pollution control itself requires inputs, the production of which may generate additional pollutants. In order to achieve positive environmental control, these two facts must be considered in selecting control processes and in determining optimum control standards. It is necessary that an integrated approach to pollution control be taken, making allowances for ecological inter-relations. As practiced today, pollution control is handled as separate problems of disposing gas, liquid and solid wastes. This paper proposes a model for evaluating the total environmental impact of a pollution control process or method. Theoretical criteria for determining an optimum control level with or without resource constraint are also derived.     

Water and soil pollution by Spent lubricating oils

This paper shows that spent lubricating oils from automobile engines generate carboxylic acids on environmental exposure. Samples of exposed oils, isolated from polluted river water and shore muds obtained from various locations, showed a direct proportionality between carboxylic acid content and time of exposure. Carboxylic acids were isolated by solvent extraction and studied by infrared spectroscopy.     

Implications of Land Use Changes on Carbon Dynamics and Sequestration—Evaluation from Forestry Datasets, India

Forests and soils are a major sink of carbon, and land use changes can affect the magnitude of above ground and below ground carbon stores and the net flux of carbon between the land and the atmosphere. Studies on methods for examining the future consequences of changes in patterns of land use change and carbon flux gains importance, as they provide different options for CO₂ mitigation strategies. In this study, a simulation approach combining Markov chain processes and carbon pools for forests and soils has been implemented to study the carbon flows over a period of time. Markov chains have been computed by converting the land use change and forestry data of India from 1997 to 1999 into a matrix of conditional probabilities reflecting the changes from one class at time t to another class time t+1. Results from Markov modeling suggested Indian forests as a potential sink for 0.94 Gt carbon, with an increase in dense forest area of about 75.93 Mha and decrease of about 3.4 Mha and 5.0 Mha in open and scrub forests, if similar land use changes that occurred during 1997–1999 would continue. The limiting probabilities suggested 34.27 percent as dense forest, 6.90 as open forest, 0.4 percent mangrove forest, 0.1 percent scrub and 58 percent as non-forest area. Although Indian forests are found to be a potential carbon sink, analysis of results from transition probabilities for different years till 2050 suggests that, the forests will continue to be a source of about 20.59 MtC to the atmosphere. The implications of these results in the context of increasing anthropogenic pressure on open and scrub forests and their contribution to carbon source from land use change and forestry sector are discussed. Some of the mitigation aspects to reduce greenhouse gas emissions from land use change and forestry sector in India are also reviewed in the study.     

Developmental Processes, Changing Lifestyle and Traditional Wisdom: Analyses from Western Himalaya

Traditional knowledge and practices are important in prudent resource use and biodiversity conservation. The implications of modernization and changing lifestyle are discussed in the context of agriculture and resource use, the two sectors in which maximum modernization has occurred. The information was gathered through observations and structured interviews over three years (July 1996 to July 1999) of field work in the western Himalaya. It was observed that forest based subsistence agriculture has given way to the market dependant cash crop cultivation. That apart from loss of genetic diversity, has also resulted in the degradation of forests. The use of wild plants in the day-to-day activities has also declined and dependence on high value market products has increased. Currently, wild plants are used only if no other cheap substitute is available in the market or if the use is economically beneficial to the people. Thus, the knowledge gathered through ages of experience is eroding because of the activities geared for short-term economic benefits which, in long run, may not be sustainable.     

Occurence and Distribution of Polycyclic Aromatic Hydrocarbons in Ankara Precipitation

Urban atmospheric environment contains many trace organic pollutants that are related to the incomplete fuel combustion in domestic heating, industrial plants and automobile traffic. Removal of these pollutants from the atmosphere takes place through wet and dry deposition as well as chemical transformations. In this study, concentrations of polycyclic aromatic hydrocarbons (PAHs) in wet deposition samples were determined at an urban site of Turkey. Wet and dry deposition samples were collected using Andersen Rain Sampler. The sampler was modified accordingly for the collection of organic pollutants. Collected samples were preconcentrated by using solid phase extraction (SPE) disks and consecutively analyzed by Gas Chromatography-Mass Spectrometry (GC-MS). Among the 13 compounds quantified in this study, anthracene, fluoranthene, and pyrene were found more frequently and at elevated concentrations (202, 271 and 260 ng L^-1 mean concentrations, respectively).Concentrations of PAHs were found to be high in winter period.     

The Role of Soil Organic Carbon in Maintaining Surface Elevation in Rapidly Subsiding U.S. Gulf of Mexico Coastal Marshes

Subsidence is a primary factor governing marsh deterioration in Mississippi River deltaic plain coastal marshes. Marsh surface-water level relationships are maintained primarily through soil organic matter accumulation and inorganic sediment input. In this study we examined the role of soil organic matter accumulation in maintaining marsh elevation in a brackish Spartina patens marsh. Measured rates of soil organic accumulation were compared to plant biomass production and soil respiration (carbon dioxide and methane emission) at the study sites. The study demonstrated the importance of plant biomass production to soil organic carbon accumulation in maintaining viable Spartina patens marshes in sediment-deficient coastal environments. The role of Mississippi River freshwater reintroduction in maintaining conditions for organic accretion is discussed.     

Starch, Poly(lactic acid), and Poly(vinyl alcohol) Blends

Research on biodegradable materials has been stimulated due to concern regarding the persistence of plastic wastes. Blending starch with poly(lactic acid) (PLA) is one of the most promising efforts because starch is an abundant and cheap biopolymer and PLA is biodegradable with good mechanical properties. Poly(vinyl alcohol) (PVOH) contains unhydrolytic residual groups of poly(vinyl acetate) and also has good compatibility with starch. It was added to a starch and PLA blend (50:50, w/w) to enhance compatibility and improve mechanical properties. PVOH (M_W 6,000) at 10%, 20%, 30%, 40%, 50% (by weight) based on the total weight of starch and PLA, and 30% PVOH at various molecular weights (M_W 6,000, 25,000, 78,000, and 125,000 dalton) were added to starch/PLA blends. PVOH interacted with starch. At proportions greater than 30%, PVOH form a continuous phase with starch. Tensile strength of the starch/PLA blends increased as PVOH concentration increased up to 40% and decreased as PVOH molecular weight increased. The increasing molecular weight of PVOH slightly affected water absorption, but increasing PVOH concentration to 40% or 50% increased water absorption. Effects of moisture content on the starch/PLA/PVOH blend also were explored. The blend containing gelatinized starch had higher tensile strength. However, gelatinized starch also resulted in increased water absorption.     

Drying of granulated wood ash by flue gas from saw dust and natural gas combustion

At the district heating plant of Kalmar, Sweden an on-line unit for production of granulated wood ash for nutrient recycling on forest soils is being applied. Currently, the granules are dried by hot air from an oil-fired burner. The objective of this work was to investigate how drying by flue gas affects the hardening of granules, or impacts their chemical composition and properties. Ninety-six granule samples were treated by flue gas from natural gas combustion in a laboratory pilot scale flue gas generator. CO₂, CO, O₂, C₃H₈ and NO concentrations were varied during the experiment. Additionally, some samples were treated by flue gas from combustion of sawdust at the heating plant in Kalmar. Drying by flue gases did not affect the chemical composition of granules, but minor effects were seen in their mineralogy. The carbonate content was slightly higher in granules treated with flue gas from natural gas combustion compared to the granules dried by hot air only, when measured by wet chemical methods. Results from XRD analysis imply that the calcite content is higher and the portlandite and arcanite content slightly less in granules treated with flue gas from sawdust combustion compared to the granules dried by hot air only. The results from this investigation showed no negative effects on ash granule composition or physical structure by the use of a flue as a drying medium.     

Regional Variations in the Implementation of the Local Air Quality Management Process within Great Britain

The UK National Air Quality Strategy has required local authorities to review and assess air quality in their area of jurisdiction and determine locations in their areas where concentrations of specific air quality pollutants are predicted to exceed national air quality objectives in the future. Statutory air quality management areas (AQMAs) are designated where air quality is predicted to be above specified objective concentrations by specific target dates, and statutory air quality action plans will be necessary to improve the local air quality within these areas. Over 124 local authorities in England (including London), Wales and Scotland anticipate declaring AQMAs following the conclusion of the statutory air quality review and assessment process. However, other influences are being exerted on the local air quality management process and AQMA decision-making processes. Such influences include regional and sub- regional collaborative working between local authorities and government agencies and wider political decision-making processes. Some regions of Great Britain (encompassing England (including London), Scotland and Wales) anticipate many AQMA designations, whilst other regions are not anticipating any such designations despite apparently similar air quality circumstances. Evidence for regional or sub-regional variations in the locations of anticipated AQMAs are examined through an evaluation of the outcomes of the scientific review and assessment process undertaken by local authorities declaring AQMAs, and through a local authority survey to identify influences on decision-making processes at a level above that of the local authority. Regional variation is reported in the type of pollutant causing AQMAs to be declared, in the numbers of AQMAs in regions and in the spatial distribution of AQMAs across Great Britain.