Eco-industrial zones in the context of sustainability development of urban areas

Industry is one of the main activities in the city and in many cities of the world, and the dominant industrial zones are the most significant morphological forms of concentration of industrial facilities in the city and are concentrated industrial and business activity. Industrial parks combine activities related to energy and resource consumption, emissions, waste generation, economic benefits, and regional development. The focus of this work is the path of transformation between the present and the vision of a sustainable city in the future. The problem and the subject of research related to two related objects of research: the city and sustainable development. In this paper, the co-author’s industrial symbiosis parks, modern tendencies of the spatial distribution of productive activities, circular economy, to attract leading corporations and open the way for new ventures while preserving the living environment in an urban area.

     

One step forward toward characterization: some important material properties to distinguish biochars

Terra Preta research gave evidence for the positive influence of charred organic material (biochar) on infertile tropical soils. Facing global challenges such as land degradation, fossil energy decline, water shortage, and climate change, the use of biochar as a soil amendment embedded into regional matter cycles seems to provide an all-round solution. However, little is known about biochar effects on individual ecosystem processes. Besides, the term is used for a variety of charred products. Therefore, the aim of this study was to investigate principal material properties of different chars to establish a minimum set of analytical properties and thresholds for biochar identification. For this purpose, chars from different production processes (traditional charcoal stack, rotary kiln, Pyreg reactor, wood gasifier, and hydrothermal carbonization) were analyzed for physical and chemical properties such as surface area, black carbon, polycyclic aromatic hydrocarbons, and elemental composition. Our results showed a significant influence of production processes on biochar properties. Based on our results, to identify biochar suitable for soil amendment and carbon sequestration, we recommend using variables with the following thresholds: O/C ratio <0.4, H/C ratio <0.6, black carbon >15% C, polyaromatic hydrocarbons lower than soil background values, and a surface area >100 m g.     

Forest Fragmentation and Landscape Transformation in a Reindeer Husbandry Area in Sweden

Reindeer husbandry and forestry are two main land users in boreal forests in northern Sweden. Modern forestry has numerous negative effects on the ground-growing and arboreal lichens that are crucial winter resources for reindeer husbandry. Using digitized historical maps, we examined changes in the forest landscape structure during the past 100 years, and estimated corresponding changes in suitability of forest landscape mosaics for the reindeer winter grazing. Cover of old coniferous forests, a key habitat type of reindeer herding system, showed a strong decrease during the study period, whereas clear-cutting and young forests increased rapidly in the latter half of the 20th century. The dominance of young forests and fragmentation of old-growth forests (decreased patch sizes and increased isolation) reflect decreased amount of arboreal lichens as well as a lowered ability of the landscape to sustain long-term persistence of lichens. The results further showed that variation in ground lichen cover among sites was mainly related to soil moisture conditions, recent disturbances, such as soil scarification and prescribed burning, and possibly also to forest history. In general, the results suggest that the composition and configuration of the forest landscape mosaic has become less suitable for sustainable reindeer husbandry.     

Combined effects of life-history traits and human impact on extinction risk of freshwater megafauna

Megafauna species are intrinsically vulnerable to human impact. Freshwater megafauna (i.e., freshwater animals ≥30 kg, including fishes, mammals, reptiles, and amphibians) are subject to intensive and increasing threats. Thirty-four species are listed as critically endangered on the International Union for Conservation of Nature (IUCN). Red List of Threatened Species, the assessments for which are an important basis for conservation actions but remain incomplete for 49 (24%) freshwater megafauna species. Consequently, the window of opportunity for protecting these species could be missed. Identifying the factors that predispose freshwater megafauna to extinction can help predict their extinction risk and facilitate more effective and proactive conservation actions. Thus, we collated 8 life-history traits for 206 freshwater megafauna species. We used generalized linear mixed models to examine the relationships between extinction risk based on the IUCN Red List categories and the combined effect of multiple traits, as well as the effect of human impact on these relationships for 157 classified species. The most parsimonious model included human impact and traits related to species’ recovery potential including life span, age at maturity, and fecundity. Applying the most parsimonious model to 49 unclassified species predicted that 17 of them are threatened. Accounting for model predictions together with IUCN Red List assessments, 50% of all freshwater megafauna species are considered threatened. The Amazon and Yangtze basins emerged as global diversity hotspots of threatened freshwater megafauna, in addition to existing hotspots, including the Ganges-Brahmaputra and Mekong basins and the Caspian Sea region. Assessment and monitoring of those species predicted to be threatened are needed, especially in the Amazon and Yangtze basins. Investigation of life-history traits and trends in population and distribution, regulation of overexploitation, maintaining river connectivity, implementing protected areas focusing on freshwater ecosystems, and integrated basin management are required to protect threatened freshwater megafauna in diversity hotspots.     

Stoichiometric controls of nitrogen and phosphorus cycling in decomposing beech leaf litter

Resource stoichiometry (C:N:P) is an important determinant of litter decomposition. However, the effect of elemental stoichiometry on the gross rates of microbial N and P cycling processes during litter decomposition is unknown. In a mesocosm experiment, beech (Fagus sylvatica L.) litter with natural differences in elemental stoichiometry (C:N:P) was incubated under constant environmental conditions. After three and six months, we measured various aspects of nitrogen and phosphorus cycling. We found that gross protein depolymerization, N mineralization (ammonification), and nitrification rates were negatively related to litter C:N. Rates of P mineralization were negatively correlated with litter C:P. The negative correlations with litter C:N were stronger for inorganic N cycling processes than for gross protein depolymerization, indicating that the effect of resource stoichiometry on intracellular processes was stronger than on processes catalyzed by extracellular enzymes. Consistent with this, extracellular protein depolymerization was mainly limited by substrate availability and less so by the amount of protease. Strong positive correlations between the interconnected N and P pools and the respective production and consumption processes pointed to feed-forward control of microbial litter N and P cycling. A negative relationship between litter C:N and phosphatase activity (and between litter C:P and protease activity) demonstrated that microbes tended to allocate carbon and nutrients in ample supply into the production of extracellular enzymes to mine for the nutrient that is more limiting. Overall, the study demonstrated a strong effect of litter stoichiometry (C:N:P) on gross processes of microbial N and P cycling in decomposing litter; mineralization of N and P were tightly coupled to assist in maintaining cellular homeostasis of litter microbial communities.     

Particulate Matter in New Technology Diesel Exhaust (NTDE) is Quantitatively and Qualitatively Very Different from that Found in Traditional Diesel Exhaust (TDE)

ABSTRACT

Diesel exhaust (DE) characteristic of pre-1988 engines is classified as a “probable” human carcinogen (Group 2A) by the International Agency for Research on Cancer (IARC), and the U.S. Environmental Protection Agency has classified DE as “likely to be carcinogenic to humans.” These classifications were based on the large body of health effect studies conducted on DE over the past 30 or so years. However, increasingly stringent U.S. emissions standards (1988–2010) for particulate matter (PM) and nitrogen oxides (NO_x) in diesel exhaust have helped stimulate major technological advances in diesel engine technology and diesel fuel/lubricant composition, resulting in the emergence of what has been termed New Technology Diesel Exhaust, or NTDE. NTDE is defined as DE from post-2006 and older retrofit diesel engines that incorporate a variety of technological advancements, including electronic controls, ultra-low-sulfur diesel fuel, oxidation catalysts, and wall-flow diesel particulate filters (DPFs). As discussed in a prior review (T. W. Hesterberg et al.; Environ. Sci. Technol. 2008, 42, 6437-6445), numerous emissions characterization studies have demonstrated marked differences in regulated and unregulated emissions between NTDE and “traditional diesel exhaust” (TDE) from pre-1988 diesel engines. Now there exist even more data demonstrating significant chemical and physical distinctions between the diesel exhaust particulate (DEP) in NTDE versus DEP from pre-2007 diesel technology, and its greater resemblance to particulate emissions from compressed natural gas (CNG) or gasoline engines. Furthermore, preliminary toxicological data suggest that the changes to the physical and chemical composition of NTDE lead to differences in biological responses between NTDE versus TDE exposure. Ongoing studies are expected to address some of the remaining data gaps in the understanding of possible NTDE health effects, but there is now sufficient evidence to conclude that health effects studies of pre-2007 DE likely have little relevance in assessing the potential health risks of NTDE exposures.

IMPLICATIONS Based on the distinct physical and chemical properties of New Technology Diesel Exhaust (NTDE), it has become clear that findings from the health effects studies conducted on traditional DE (TDE) over the last 30 years have little relevance to NTDE, which is more similar to the exhaust from compressed natural gas (CNG) or gasoline engine emissions than to traditional TDE. Once sufficient health effects data are available for NTDE, it will thus be necessary to conduct new hazard and risk assessments for NTDE that are independent of the DE toxicological database acquired on emissions from pre–2007 diesel technology.     

Measurement of particle concentrations in a dental office

Particles in a dental office can be generated by a number of instruments, such as air-turbine handpieces, low-speed handpieces, ultrasonic scalers, bicarbonate polishers, polishing cups, as well as drilling and air sprays inside the oral cavity. This study examined the generation of particles during dental drilling and measured particle size, mass, and trace elements. The air sampling techniques included both continuous and integrated methods. The following particle continuous measurements were taken every minute: (1) size-selective particle number concentration (Climet); (2) total particle number concentration (PTRAK), and; (3) particle mass concentration (DustTrak). Integrated particle samples were collected for about 5 h on each of five sampling days, using a PM_2.5 sampler (ChemComb) for elemental/organic carbon analysis, and a PM₁₀ sampler (Harvard Impactor) for mass and elemental analyses. There was strong evidence that these procedures result in particle concentrations above background. The dental procedures produced number concentrations of relatively small particles (<0.5 μm) that were much higher than concentrations produced for the relatively larger particles (>0.5 μm). Also, these dental procedures caused significant elevation above background of certain trace elements (measured by X-ray fluorescence) but did not cause any elevation of elemental carbon (measured by thermal optical reflectance). Dental drilling procedures aerosolize saliva and products of drilling, producing particles small enough to penetrate deep into the lungs. The potential health impacts of the exposure of dental personnel to such particles need to be evaluated. Increased ventilation and personal breathing protection could be used to minimize harmful effects.     

SMEs and voluntary environmental initiatives: a study of stakeholders' perspectives in Hong Kong

The environmental performance of Hong Kong's businesses is currently perceived as rather poor. Small and medium-sized enterprises (SMEs) in particular are mostly unaware of the environmental impact of their business. Government and professional bodies have recently started to develop various initiatives to improve the SME sector's awareness of environmental and social issues, and external factors such as supply chain requirements, consumer preferences and energy prices are also exerting a growing influence. Based on extensive interviews with representatives of seven key stakeholder groups, this paper explores the effectiveness of such drivers to engage SMEs with environmental change and corporate social responsibility (CSR). It finds that most existing efforts, such as environmental support programmes and award schemes, do not have a great impact on the environmental and social performance of Hong Kong's SMEs.     

N-methylcarbamate pesticides and their phenolic degradation products: hydrolytic decay,sequestration and metal complexation studies

We report on the rates of decomposition of a group of N-methylcarbamate (NMC) pesticides (carbaryl, carbofuran and propoxur) under pre-determined tropical field conditions. Rates of decomposition for three NMCs were determined at pH 7.08 and T?=?20?°C and pH 7.70 and T = 33?°C respectively, as follows: carbaryl (78?days and 69?days); carbofuran (143?days and 83?days) and propoxur (116?days and 79?days). Investigation on methods for removal of NMCs and their phenolic decomposition products shows that activated charcoal outperforms zeolite, alumina, diatomaceous earth, cellulose and montmorillonite clay in the removal of both NMCs and phenols from aqueous solution. Furthermore, metal complexation studies on the NMCs and phenols showed that Fe (III) forms a complex with isopropoxyphenol (IPP) within which the Fe:IPP ratio is 1:3, indicative of the formation of a metal chelate complex with the formula Fe(IPP)₃.     

Re-Meandering German Lowland Streams: Qualitative and Quantitative Effects of Restoration Measures on Hydromorphology and Macroinvertebrates

We investigated the effects of two river restoration projects on hydromorphology and macroinvertebrate fauna in two German lowland rivers, the Schwalm and the Gartroper Mühlenbach. The stream channels were re-meandered and the floodplain levels were lowered to better connect the streams to their floodplains. The restoration was performed 10 years ago in the Schwalm and 2 years ago in the Gartroper Mühlenbach. We compared the restored reaches to nearby anthropogenically straightened reaches. Twenty-five hydromorphological parameters were recorded on twenty transects; between nine and 23 substrate-specific macroinvertebrate samples were taken per reach. Several hydromorphological parameters, such as the number and width of channel features and the number of substrate types, were significantly higher in the restored reaches compared to nearby anthropogenically straightened reaches. Total numbers of invertebrate families, genera, and taxa were also higher in the restored reaches than in the anthropogenically straightened reaches. Biotic substrates like dead wood or macrophytes were more abundant in the restored reaches, and these substrates hosted 28 taxa not found in the straightened reaches. While diversity was high in both restored reaches, overall abundance increased only in the river that was restored 10 years ago. Using NMS-analysis, substrate-specific faunistic samples of the restored reaches were compared to those of the straightened reaches. Our results revealed different invertebrate communities on the same substrates in the recently restored river. In the 10-year-old restoration, however, the same substrates were similarly inhabited. This comparable colonization of substrates may reflect succession in the macroinvertebrate community. The results are discussed according to the re-colonization potentials of the upstream and downstream reaches and the dispersal capacity of taxa.