Allocation of Streamflow Depletion Impacts under Nonlinear Conditions

A method is proposed for the equitable allocation of impacts of groundwater pumping on streamflow. The method is intended for cases in which the pumping activity of multiple entities has impacts on streamflow and these impacts are computed by perturbation. It is shown that when the response of streamflow to pumping is nonlinear, simple methods for impact calculation can fail. The proposed method is developed for the case when there are four entities that impact streamflow. The method relies on the calculation of impacts by perturbation of the simulation model from different base pumping levels. When four entities are evaluated, 16 runs of the simulation model are required. It is shown the proposed method produces estimated impacts for each individual entity that are equitable because they meet the requirement that the impacts of each entity sum to the total impacts of all entities acting together and the impacts attributed to each entity do not depend on the order of calculation. A brief example demonstrates the approach.     

A chemox treatment for urea‐ and ammonium‐contaminated groundwater

In a pilot project performed at a fertilizer manufacturing facility, a one‐step chemical oxidation technique successfully treated urea‐ and ammonium‐contaminated groundwater. The oxidation reaction occurred in an 1,100‐gallon batch reactor. The contaminated inflow was buffered by the metered addition of sodium bicarbonate solution and subsequently treated with sodium hypochlorite in an 8:1 weight ratio of Cl₂:N. In an instantaneous reaction, the urea and ammo‐nium‐N were completely oxidized to nitrogen gas that was vented to the atmosphere during mixing. The pH of the reactor discharge was ?6.5. Sodium sulfite was used to reduce residual hypochlorite in the reactor effluent to chloride to provide process water with characteristics suitable for discharge. Oxidation rates were similar with different strengths of hypochlorite; however, a 5 to 6 percent sodium hypochlorite (as Cl₂) solution was the most stable. © 2005 Wiley Periodicals, Inc.