Tracking chlordane compositional and chiral profiles in soil and vegetation

The cycling of chlordane and other persistent organic pollutants through the environment must be comprehensively elucidated to assess adequately the human health risks posed from such contaminants. In this study the compositional and chiral profiles of weathered chlordane residues in the soil and vegetative compartments were investigated in order to provide details of the fate and transport of this persistent pesticide. Zucchini was planted in a greenhouse in three bays containing chlordane-contaminated soil. At harvest the vegetation and soil were extracted and analyzed for chlordane content using chiral gas chromatography/ion trap mass spectrometry. Both achiral and chiral chlordane components were quantified. The chlordane concentration in the rhizosphere (soil attached to roots) was significantly less than that in the bulk soil. However, the enantiomeric ratio of the chiral components and overall component ratios had changed little in the rhizosphere relative to the bulk soil. Significant levels of chlordane were detected in the vegetation, the amount varying in different plant tissues from a maximum in roots to a minimum in fruit. In addition to the chlordane concentration gradient in plant tissues, significant shifts in compositional profile, as indicated by the component ratios, and in chiral profile, as indicated by the enantiomeric ratio, of the contaminant were observed in the plant tissues. The data indicate that abiotic processes dominate the transport of the chlordane components through the soil to the plant. This is the first report of the effect of rapid biotic processes within the plant compartment on chlordane compositional and chiral profiles.     

Matching response to context in complex political emergencies: 'relief', 'development', 'peace-building' or something in-between?

There is an ongoing debate over the value and pitfalls of the policy and practice of 'linking relief and development' or 'developmental relief' in aid responses to complex political emergencies (CPEs). Driven by concerns about relief creating dependence, sometimes doing harm and failing to address root causes of emergencies despite its high cost, pursuit of both relief and development has become a dominant paradigm among international aid agencies in CPEs as in 'natural' disasters. In CPEs a third objective of 'peace-building' has emerged, along with the logic that development can itself help prevent or resolve conflict and sustain peace. However, this broadening of relief objectives in ongoing CPEs has recently been criticised on a number of counts, central concerns being that it leads to a dilution of commitment to core humanitarian principles and is overly optimistic. This paper addresses these issues in the light of two of the CPEs studied by the COPE project: Eritrea and Somalia/Somaliland. It is argued that the debate has so far suffered from lack of clarity about what we mean by 'relief', 'development' and, for that matter, 'rehabilitation' and 'peace-building'. The wide spectrum of possible aid outcomes does not divide neatly into these categories. The relief-development divide is not always as clear-cut, technically or politically, as the critics claim. Moreover such distinctions, constructed from the point of view of aid programmers, are often of little relevance to the concerns of intended beneficiaries. Second, there has been insufficient attention to context: rather than attempting to generalise within and across CPE cases, a more productive approach would be to examine more closely the conditions under which forms of aid other than basic life support can fruitfully be pursued. This leads to consideration of collective agency capacity to respond effectively to diverse needs in different and changing circumstances.     

FEASIBILITY OF INTERBASIN WATER TRANSFER1

ABSTRACT: Interbasin water transfer is one of the most controversial water-resources-planning topics. Local communities, particularly those from which the water is to be taken (donor regions), generate enough opposition to doom many projects to failure. The opposition often arises because planners have traditionally considered excess water a free commodity rather than a marketable resource. To make transfer schemes mutually acceptable to donor and recipient regions, visible benefits must be offered. Agreement must be made on an acceptable purchase price and/or on other benefits such as a substantial amount of low flow augmentation or possibly some degree of flood control on the donor source stream. The hydrologic and economic feasibility of water transfer from the East Susquehanna River basin to the Delaware Reservoir System for supplemental supply to the New York City area was investigated. Nine alternative schemes for diversions up to 400 cfs and compensations in the form of low flow augmentation and/or flood control were considered resulting in unit costs to the recipient region between $90 and $380/mg. If only the minimum state-mandated flow is released to the Susquehanna River, the savings to the water recipients would be sufficient to pay a purchase price of about $21/mg, which would be equivalent to a total amount of $420,000/year for an average export of 100 cfs.     

Fitting a Gamma Distribution Over a Synthetic Unit Hydrograph1

ABSTRACT: Several methods for synthetic unit hydrographs are available in the literature. Most of these methods involve the hand fitting of a curve over a set of a few hydrograph points, which can sometimes be a subjective task. Besides, the user often finds it difficult or simply neglects to adjust the generated unit graph to a runoff volume of one unit (inch, cm, or mm). It is the purpose of this paper to present to the design hydrologist a simple method to fit a smooth gamma distribution over a single point specified by the unit hydrograph peak and the time to peak with a guaranteed unit depth of runoff.     

NELUP: Some Reflections on Undertaking and Reporting InterdisciplinaryRiver Catchment Modelling

NELUP was a five-year academic research project into interdisciplinary river catchment modelling. The experience of staff involved offers useful insights into the intellectual and practical problems associated with interdisciplinary catchment management research and the dissemination and acceptance of results. In particular, it is suggested that: entrenched academic territories, derived from disciplinary and data differences, make managing an interdisciplinary team of researchers a non-trivial task; data errors, model complexity and model generality masked by a seductively sophisticated-looking DSS risk an illusion of technique; and that acceptance of decision support is hindered by practitionersand policy makers' suspicion of potential automated decision making by default.     

Using GIS to Generate Spatially Balanced Random Survey Designs for Natural Resource Applications

Sampling of a population is frequently required to understand trends and patterns in natural resource management because financial and time constraints preclude a complete census. A rigorous probability-based survey design specifies where to sample so that inferences from the sample apply to the entire population. Probability survey designs should be used in natural resource and environmental management situations because they provide the mathematical foundation for statistical inference. Development of long-term monitoring designs demand survey designs that achieve statistical rigor and are efficient but remain flexible to inevitable logistical or practical constraints during field data collection. Here we describe an approach to probability-based survey design, called the Reversed Randomized Quadrant-Recursive Raster, based on the concept of spatially balanced sampling and implemented in a geographic information system. This provides environmental managers a practical tool to generate flexible and efficient survey designs for natural resource applications. Factors commonly used to modify sampling intensity, such as categories, gradients, or accessibility, can be readily incorporated into the spatially balanced sample design.     

An Interpretive Study of Yosemite National Park Visitors’ Perspectives Toward Alternative Transportation in Yosemite Valley

The National Park Service (NPS) is increasingly focusing on alternative transportation systems in national parks to address environmental and social problems arising from a historical reliance on personal automobiles as the primary means of visitor access. Despite the potential advantages, alternative transportation may require a reorientation in the way that Americans have experienced national parks since the advent of auto-tourism in the early twentieth century. Little research exists, however, on visitor perspectives towards alternative transportation or the rationale underlying their perspectives. It remains unclear how transportation systems affect visitors’ experiences of the park landscape or the factors influencing their travel behavior in the parks. This report presents an interpretive study of visitor perspectives toward transportation management in the Yosemite Valley area of Yosemite National Park, California. Qualitative analysis of 160 semi-structured interviews identified individual psychological factors as well as situational influences that affect visitors’ behavior and perspectives. Individual psychological factors include perceived freedom, environmental values and beliefs, prior experience with Yosemite National Park and other national parks, prior experience with alternative transportation in national parks, and sensitivity to subjective perceptions of crowding. Situational factors included convenience, access, and flexibility of travel modes, as well as type of visit, type of group, and park use level. Interpretive communication designed to encourage voluntary visitor use of alternative transportation should focus on these psychological and situational factors. Although challenges remain, the results of this study suggest approaches for shaping the way Americans visit and experience their national parks to encourage environmental sustainability.