Optimal extension of the rain gauge monitoring network of the Apulian Regional Consortium for Crop Protection

The goal of this paper is to provide a methodology for assessing the optimal localization of new monitoring stations within an existing rain gauge monitoring network. The methodology presented, which uses geostatistics and probabilistic techniques (simulated annealing) combined with GIS instruments, could be extremely useful in any area where an extension of whatever existing environmental monitoring network is planned. The methodology has been applied to the design of an extension to a rainfall monitoring network in the Apulia region (South Italy). The considered monitoring network is managed by the Apulian Regional Consortium for Crop Protection (ARCCP), and, currently consists of 45 gauging stations distributed over the regional territory, mainly located on the basis of administrative needs. Fifty new stations have been added to the existing monitoring network, split in two groups: 15 fixed and 35 mobile stations. Two different methods were applied and tested: the Minimization of the Mean of Shortest Distances method (MMSD) and Ordinary Kriging (OK) whose related objective function is estimation variance. The MMSD, being a purely geometric method, produced a spatially uniform configuration of the gauging stations. On the contrary, the approach based on the minimization of the average of the kriging estimation variances, produced a less regular configuration, though a more reliable one from a spatial standpoint. Nevertheless, the MMSD approach was chosen, since the ARCCP's intention was to create a new monitoring network characterized by uniform spatial distribution throughout the regional territory. This was the most important constraint given to the project by the ARCCP, whose main objective was to accomplish a territorial network capable of detecting hazardous events quickly. A seasonal aggregation of the available rainfall data was considered. The choice of the temporal aggregation in quarterly averages allowed four different optimal configurations to be determined per season. The overlapping of the four configurations allowed a number of new station locations, which tended to remain fixed season after season, to be identified. Other stations, instead, changed their coordinates considerably over the four seasons. Constraints were defined in order to avoid placing new monitoring locations either near existing stations, belonging to other Agencies, or near the coast line.     

Spatial evaluation of the risk of groundwater quality degradation. A comparison between disjunctive kriging and geostatistical simulation

In some previous papers a probabilistic methodology was introduced to estimate a spatial index of risk of groundwater quality degradation, defined as the conditional probability of exceeding assigned thresholds of concentration of a generic chemical sampled in the studied water system. A crucial stage of this methodology was the use of geostatistical techniques to provide an estimation of the above-mentioned probability in a number of selected points by crossing spatial and temporal information. In this work, spatial risk values were obtained using alternatively stochastic conditional simulation and disjunctive kriging. A comparison between the resulting two sets of spatial risks, based on global and local statistical tests, showed that they do not come from the same statistical population and, consequently, they cannot be viewed as equivalent in a statistical sense. At a first glance, geostatistical conditional simulation may appear to represent the spatial variability of the phenomenon more effectively, as the latter tends to be smoothed by DK. However, a close examination of real case study results suggests that disjunctive kriging is more effective than simulation in estimating the spatial risk of groundwater quality degradation. In the study case, the potentially ‘harmful event’ considered, threatening a natural ‘vulnerable groundwater system,’ is fertilizer and manure application.     

Biological effects of diethylene glycol (DEG) and produced waters (PWs) released from offshore activities: A multi-biomarker approach with the sea bass Dicentrarchus labrax

Diethylene glycol (DEG) is largely used during oil and gas exploitation by offshore platforms. The aim of this work was to investigate if this compound induces direct molecular/cellular effects in marine organisms, or indirectly modulate those of produced waters (PWs). Sea bass (Dicentrarchus labrax) were exposed to DEG dosed alone or in combination with PWs from an Adriatic platform. A wide array of analysed biomarkers included cytochrome P450-dependent enzymatic activity, bile metabolites, glutathione S-transferases, acetylcholinesterase, peroxisomal proliferation, antioxidant defences (catalase, glutathione reductase, glutathione peroxidases, glutathione), total oxyradical scavenging capacity, malondialdehyde and DNA integrity (single strand breaks and frequency of micronuclei). Results did not reveal marked effects of DEG, while PWs influenced the biotransformation system, the oxidative status and the onset of genotoxic damages. Co-exposures caused only limited differences of biomarker responses at some experimental conditions, overall suggesting a limited biological impact of DEG at levels normally deriving from offshore activities.     

GC-MS analyses and chemometric processing to discriminate the local and long-distance sources of PAHs associated to atmospheric PM2.5

Purpose

This study presents a procedure to differentiate the local and remote sources of particulate-bound polycyclic aromatic hydrocarbons (PAHs).

Methods

Data were collected during an extended PM_2.5 sampling campaign (2009?C2010) carried out for 1?year in Venice-Mestre, Italy, at three stations with different emissive scenarios: urban, industrial, and semirural background. Diagnostic ratios and factor analysis were initially applied to point out the most probable sources. In a second step, the areal distribution of the identified sources was studied by applying the discriminant analysis on factor scores. Third, samples collected in days with similar atmospheric circulation patterns were grouped using a cluster analysis on wind data. Local contributions to PM_2.5 and PAHs were then assessed by interpreting cluster results with chemical data.

Results

Results evidenced that significantly lower levels of PM_2.5 and PAHs were found when faster winds changed air masses, whereas in presence of scarce ventilation, locally emitted pollutants were trapped and concentrations increased. This way, an estimation of pollutant loads due to local sources can be derived from data collected in days with similar wind patterns. Long-range contributions were detected by a cluster analysis on the air mass back-trajectories. Results revealed that PM_2.5 concentrations were relatively high when air masses had passed over the Po Valley. However, external sources do not significantly contribute to the PAHs load.

Conclusions

The proposed procedure can be applied to other environments with minor modifications, and the obtained information can be useful to design local and national air pollution control strategies.     

Vitellogenin gene expression in males of the Antarctic fish Trematomus bernacchii from Terra Nova Bay (Ross Sea): a role for environmental cadmium?

Synthesis of vitellogenin (VTG) in male fish is a widely recognized effect for estrogenic pollutants in temperate environments, while similar investigations are still lacking for Antarctic organisms. In this study, a preliminary characterization of vitellogenin gene expression was performed by RT-PCR in the key species Trematomus bernacchii sampled in different phases of reproductive cycle and food availability. Females exhibited the highest gene expression during the spawning period, but VTG mRNA was always detected also in males; a significant increase of gene expression was observed both in males and females at the end of the feeding season. These results were not fully supported by a differential exposure to phyto- or anthropogenic estrogens during the planctonic cycle; on the other side, the endocrine properties of cadmium, naturally elevated in Terra Nova Bay and increasing during algal bloom, would explain both the presence of VTG mRNA in males and the seasonal changes of gene induction. Laboratory exposures did not reveal short-term estrogenic effects of cadmium while an elevated responsiveness of T. bernacchii was observed toward a classical estrogenic receptor agonist (17beta-estradiol). Different hypotheses were considered to suggest delayed endocrine effects of cadmium, including the early interaction with other cellular detoxification systems or alterations at multiple levels of the hypothalamus-pituitary-gonad-liver axis. Although molecular mechanisms of VTG gene expression in males of T. bernacchii remain unclear, obtained results provide interesting insights on this species which should stimulate future research activities.     

Ecological risk assessment of organic waste amendments using the species sensitivity distribution from a soil organisms test battery

Safe amendment rates (the predicted no-effect concentration or PNEC) of seven organic wastes were estimated from the species sensitivity distribution of a battery of soil biota tests and compared with different realistic amendment scenarios (different predicted environmental concentrations or PEC). None of the wastes was expected to exert noxious effects on soil biota if applied according either to the usual maximum amendment rates in Europe or phosphorus demands of crops (below 2 tonnes DM ha⁻¹). However, some of the wastes might be problematic if applied according to nitrogen demands of crops (above 2 tonnes DM ha⁻¹). Ammonium content and organic matter stability of the studied wastes are the most influential determinants of the maximum amendment rates derived in this study, but not pollutant burden. This finding indicates the need to stabilize wastes prior to their reuse in soils in order to avoid short-term impacts on soil communities.     

Characterising the hydrological regime of an ungauged temporary river system: a case study

Temporary streams are characterised by specific hydrological regimes, which influence ecosystem processes, groundwater and surface water interactions, sediment regime, nutrient delivery, water quality and ecological status. This paper presents a methodology to characterise and classify the regime of a temporary river in Southern Italy based on hydrological indicators (HIs) computed with long-term daily flow records. By using a principal component analysis (PCA), a set of non-redundant indices were identified describing the main characteristics of the hydrological regime in the study area. The indicators identified were the annual maximum 30- and 90-day mean (DH4 and DH5), the number of zero flow days (DL6), flow permanence (MF) and the 6-month seasonal predictability of dry periods (SD6). A methodology was also tested to estimate selected HIs in ungauged river reaches. Watershed characteristics such as catchment area, gauging station elevation, mean watershed slope, mean annual rainfall, land use, soil hydraulic conductivity and available water content were derived for each site. Selected indicators were then linked to the catchment characteristics using a regression analysis. Finally, MF and SD6 were used to classify the river reaches on the basis of their degree of intermittency. The methodology presented in this paper constitutes a useful tool for ecologists and water resource managers in the Water Framework Directive implementation process, which requires a characterisation of the hydrological regime and a ‘river type’ classification for all water bodies.     

A methodology for rapid assessment of the environmental status of the shallow aquifer of ��Tavoliere di Puglia�� (Southern Italy)

Anticipating the European Water Framework Directive (2000/60/EC), the Italian Government issued Legislative Decree n.152/99 which sets out rules for classifying the environmental status of national water bodies in order to achieve specific qualitative objectives by 2016. The most recent European Groundwater Directive (2006/118/EC), which was only recognized by Italy in early 2009 (Legislative Decree 30/09), requires such resources to be characterized from a qualitative standpoint and the risk of their being polluted by individual pollutants or groups of pollutants to be evaluated. This paper reports a simple methodology, based on easy-to-apply rules, for the rapid classification of groundwater, and the results of its application to the shallow aquifer of the plain of Tavoliere delle Puglie located in south Italy. Data collected during well-water monitoring campaigns carried out from 2002 to 2003 made it possible to assess the environmental status of the Tavoliere which, unfortunately, was found to be characterized by ??significant anthropic pressures on quality and/or quantity of groundwater and necessitating specific improvement actions??.     

Insights into the Porretta Terme (northern Apennines,Italy) hydrothermal system revealed by geochemical data on presently discharging thermal waters and paleofluids

Environmental Geochemistry and Health - This study focuses on the geochemical features of the presently discharging thermal and cold springs and on paleofluids from the upstream portion of the Reno...