Bed Stability and Sedimentation Associated With Human Disturbances in Pacific Northwest Streams1

Abstract: To evaluate anthropogenic sedimentation in United States (U.S.) Pacific Northwest coastal streams, we applied an index of relative bed stability (LRBS*) to summer low flow survey data collected using the U.S. Environmental Protection Agency’s Environmental Monitoring and Assessment Program field methods in a probability sample of 101 wadeable stream reaches. LRBS* is the log of the ratio of bed surface geometric mean particle diameter (D_gm) to critical diameter (D*_cbf) at bankfull flow, based on a modified Shield’s criterion for incipient motion. We used a formulation of LRBS* that explicitly accounts for reductions in bed shear stress that result from channel form roughness due to pools and wood. LRBS* ranged from ?1.9 to +0.5 in streams within the lower quartile of human riparian and basin disturbance, and was substantially lower (?4.2 to ?1.1) in streams within the upper quartile of human disturbance. Modeling results suggest that the expected range of LRBS* in streams without human disturbances in this region might be generally between ?0.7 and +0.5 in either sedimentary or volcanic lithology. However, streams draining relatively soft, erodible sedimentary lithology showed greater reductions in LRBS* associated with disturbance than did those having harder, more resistant volcanic (basalt) lithology with similar levels of basin and riparian disturbance. At any given level of disturbance, smaller streams had lower LRBS* than those with larger drainages. In sedimentary lithology (sandstone and siltstone), high‐gradient streams had higher LRBS* than did low‐gradient streams of the same size and level of human disturbance. High gradient streams in volcanic lithology, in contrast, had lower LRBS* than low‐gradient streams of similar size and disturbance. Correlations between D_gm and land disturbance were stronger than those observed between D*_cbf and land disturbance. This pattern suggests that land use has augmented sediment supplies and increased streambed fine sediments in the most disturbed streams. However, we also show evidence that some of the apparent reductions in LRBS*, particularly in steep streams draining small volcanic drainages, may have resulted in part from anthropogenic increases in bed shear stress. The synoptic survey methods and designs we use appear adequate to evaluate regional patterns in bed stability and sedimentation and their general relationship to human disturbances. More precise field measurements of channel slope, cross‐section geometry, and bed surface particle size would be required to use LRBS* in applications requiring a higher degree of accuracy and precision, such as site‐specific assessments at individual streams.     

The potential of willow for remediation of heavy metal polluted calcareous urban soils

Growth performance and heavy metal uptake by willow (Salix viminalis) from strongly and moderately polluted calcareous soils were investigated in field and growth chamber trials to assess the suitability of willow for phytoremediation. Field uptakes were 2-10 times higher than growth chamber uptakes. Despite high concentrations of cadmium (≥80 mg/kg) and zinc (≥3000 mg/kg) in leaves of willow grown on strongly polluted soil with up to 18 mg Cd/kg, 1400 mg Cu/kg, 500 mg Pb/kg and 3300 mg Zn/kg, it is unsuited on strongly polluted soils because of poor growth. However, willow proved promising on moderately polluted soils (2.5 mg Cd/kg and 400 mg Zn/kg), where it extracted 0.13% of total Cd and 0.29% of the total Zn per year probably representing the most mobile fraction. Cu and Pb are strongly fixed in calcareous soils.     

Oxygen,carbon, and nutrient exchanges at the sediment–water interface in the Mar Piccolo of Taranto (Ionian Sea,southern Italy)

In the shallow environment, the nutrient and carbon exchanges at the sediment–water interface contribute significantly to determine the trophic status of the whole water column. The intensity of the allochthonous input in a coastal environment subjected to strong anthropogenic pressures determines an increase in the benthic oxygen demand leading to depressed oxygen levels in the bottom waters. Anoxic conditions resulting from organic enrichment can enhance the exchange of nutrients between sediments and the overlying water. In the present study, carbon and nutrient fluxes at the sediment–water interface were measured at two experimental sites, one highly and one moderately contaminated, as reference point. In situ benthic flux measurements of dissolved species (O₂, DIC, DOC, N-NO₃ ^?, N-NO₂ ^?, N-NH₄ ⁺, P-PO₄ ^3?, Si-Si(OH)₄, H₂S) were conducted using benthic chambers. Furthermore, undisturbed sediment cores were collected for analyses of total and organic C, total N, and biopolymeric carbon (carbohydrates, proteins, and lipids) as well as of dissolved species in porewaters and supernatant in order to calculate the diffusive fluxes. The sediments were characterized by suboxic to anoxic conditions with redox values more negative in the highly contaminated site, which was also characterized by higher biopolymeric carbon content (most of all lipids), lower C/N ratios and generally higher diffusive fluxes, which could result in a higher release of contaminants. A great difference was observed between diffusive and in situ benthic fluxes suggesting the enhancing of fluxes by bioturbation and the occurrence of biogeochemically important processes at the sediment–water interface. The multi-contamination of both inorganic and organic pollutants, in the sediments of the Mar Piccolo of Taranto (declared SIN in 1998), potentially transferable to the water column and to the aquatic trophic chain, is of serious concern for its ecological relevance, also considering the widespread fishing and mussel farming activities in the area.     

Use of scenarios and strategic planning to explore an uncertain future in Greenland

Greenland is facing unpredictable changes due to ongoing exploration in the extractive sector. More exploration applications than ever are being submitted to the Greenlandic authorities and development trends are therefore hard to determine. Based on the challenge of securing strategic planning in the Greenlandic context, this article examines scenario building as a planning tool. An empirical study that uses local stakeholder input identifies nine primary driving forces to frame and setup four scenarios for potential Greenland futures. The study also demonstrates that there are significant barriers for strategic planning. These are related to creating an inclusive process, reaching agreement on values and content of the scenarios and securing coordination, ownership and commitment among the stakeholders.     

SoilTrEC: a global initiative on critical zone research and integration

Soil is a complex natural resource that is considered non-renewable in policy frameworks, and it plays a key role in maintaining a variety of ecosystem services (ES) and life-sustaining material cycles within the Earth's Critical Zone (CZ). However, currently, the ability of soil to deliver these services is being drastically reduced in many locations, and global loss of soil ecosystem services is estimated to increase each year as a result of many different threats, such as erosion and soil carbon loss. The European Union Thematic Strategy for Soil Protection alerts policy makers of the need to protect soil and proposes measures to mitigate soil degradation. In this context, the European Commission-funded research project on Soil Transformations in European Catchments (SoilTrEC) aims to quantify the processes that deliver soil ecosystem services in the Earth's Critical Zone and to quantify the impacts of environmental change on key soil functions. This is achieved by integrating the research results into decision-support tools and applying methods of economic valuation to soil ecosystem services. In this paper, we provide an overview of the SoilTrEC project, its organization, partnerships and implementation.     

Toxic effects of four sulphonylureas herbicides on soil microbial biomass

The effect of four triazinyl-sulfonylurea herbicides (cinosulfuron, prosulfuron, thifensulfuron methyl, triasulfuron) on soil microbial biomass, soil respiration, metabolic activity, metabolic quotient, and some enzymatic activities (acid and alkaline phosphatase, β-glucosidase, arylsulphatase, and fluorescein diacetate hydrolysis) were monitored under controlled conditions over 30 days. The herbicides were applied at the normal field dose (FD) and at ten-fold (10 FD) the field dose, in order to mimic a long term toxic effect. The measured soil microbial parameters showed that the FD had slight effects on soil microflora, while at 10 FD the tested herbicides exerted a stronger detrimental effect on soil microbial biomass and its biochemical activities.     

Modelling the biphasic sorption of simazine,imidacloprid, and boscalid in water/soil systems

The sorption kinetics of simazine (6-chloro-N,N′-diethyl-1,3,5-triazine-2,4-diamine), imidacloprid (1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine), and boscalid (2-chloro-N-(4′-chlorobiphenyl-2-yl)nicotinamide), three pesticides of wide use in agriculture, was determined in five different water/soil systems over a time interval from the initial few seconds to about 1 month. In all the experiments, sorption kinetics showed a biphasic pattern characterized by an initial, relatively short phase with a high sorption rate and a later phase with much a lower sorption rate. Initial sorption capacity increased with soil organic carbon content and with sorbate hydrophobicity. We postulate that the first phase of the process involves a fast second-order sorption reaction on superficial sites of soil particles, whereas the second phase depends on diffusion-controlled migration to internal binding sites. A kinetic equation based on this hybrid model accurately fitted all data sets. Less satisfactory results were obtained employing the pseudo-first order, pseudo-second order, Elovich, two site non-equilibrium, or Weber-Morris equation. The superior performance of the hybrid model for describing boscalid sorption probably reflects the high hydrophobic character and consequent low diffusion rates of this compound. The accuracy of modelling was in any case strongly dependent on the time interval considered.     

A Method for Determining Source Reduction Required to Meet Air Quality Standards

Governmental boundaries which divide our states frequently do not coincide with the natural geographic and atmospheric conditions affecting regional air pollution problems. Moreover, the control regulations of one state may vary from those of its neighbors. Such areal synthesis of air pollution control measures might only minimally curb the difficulties.

Continuity of control will require cooperation among contiguous states. In this study the attitudes of incumbent elected officials and air pollution experts (both from within the Philadelphia metropolitan area) toward governmental responsiveness have been investigated. It was hypothesized that politicians would want to demonstrate a status quo approach while experts would advocate the creation of an environmental agency for the Philadelphia region’s pollution problems. However, both sample groups responded to the questionnaire survey affirming that they want government to establish an environmental regional control agency, based upon an interstate compact, that has authority strong enough to be a strict enforcing agent. This regional agency should meet all federal conditions and thus receive maximum federal financial assistance. The policy level officials of this agency should be appointed experts—so as to avoid partisan politics, and to acquire the most qualified personnel.     

Response

While quality control has been defined and implemented for ambient criteria pollutant monitoring, such as for SO₂, O₃ and total suspended particulates, most of the noncriteria air pollutants currently being measured have not been subject to similar levels of data assurance.. The New Jersey Project on Airborne Toxic Elements and Organic Substances (ATEOS) included the measurement of nearly 50 gaseous and particulate phase noncriteria pollutants, within the structure of a rigorous quality assurance/quality control (QA/QC) program. The following report details the QA/QC results for the particulate and vapor phase pollutants measured during the ATEOS project. Consideration is given to a number of basic differences between measuring inorganic and organic pollutants including method detection limits, number of valid samples, and precision and accuracy of the overall methods. Particular emphasis is placed on how the QA/QC data place limits on statistical analyses of noncriteria air pollutant data sets.