Study of fluxing in Al refining process by rotary and crucible furnaces

The process used to obtain recycled Al alloys depends on the scrap quality. Rotary furnaces are normally used in Europe as they allow a great productivity and they can process low quality scrap using a salt flux to protect the molten metal from oxidation. In this article, the effect of the quantity of salt on the metal recovery has been experimentally investigated by melting several types of scrap under a mixture of NaCl–KCl–Na₃AlF₆ salts. The quantity of salt has been related to the salt factor (SF), which is the ratio between the non-metallic content in the scrap and the quantity of salt required. The same levels of salt factor have been tested by melting the scrap in rotary and crucible furnaces. The metal recovery increases with the salt content for both furnaces. The results obtained with the different melting processes are comparable because the yield difference is similar considering different salt factors. Crucible furnace gives greater metal recovery but it cannot replace rotary furnace in Al refining industry due to lower melting capacity. However, the results highlight that the optimisation of the Al refining process can be supported by preliminary tests through crucible furnaces reducing the time and material consumptions.     

Biological effects of ammonia released from a composting plant assessed with lichens

In this study, we investigated whether ammonia emissions from industrial composting of organic waste may influence the surrounding environment, using lichens as bioindicators. To this purpose, samples of N-tolerant and N-sensitive lichens, namely Xanthoria parietina and Evernia prunastri, were transplanted for 1–3 months along transects at increasing distance (0–400 m) from a composting facility in Tuscany, Italy. Atmospheric concentrations of ammonia were measured using passive samplers. The physiological response of lichen transplants was investigated by means of the photosynthetic efficiency (measured as chlorophyll a fluorescence emission), the integrity of cell membranes (measured as electrolyte leakage), and sample viability (measured as enzymatic activity of dehydrogenase). Epiphytic lichen communities were investigated using biodiversity indices. The results showed decreasing concentrations of ammonia, from 48.7 μg/m³ at the composting facility to 2.7 μg/m³ at 400 m. The N-tolerant X. parietina was not affected and some physiological parameters even showed a higher performance, while the N-sensitive E. prunastri showed a reduced performance with increasing atmospheric concentrations approaching the source. A shift from lichen communities composed by meso-acidophilous species (actual condition) to more nitrophilous communities in the near future, approaching the composting facility is suggested. It is concluded that lichens can provide useful data for decision-makers to establish correct science-based environmentally sustainable waste management policies.     

21,000 Years of Ethiopian African monsoon variability recorded in sediments of the western Nile deep-sea fan

The Nile delta sedimentation constitutes a continuous high-resolution record of Ethiopian African monsoon (EAM) regime intensity. Multi-proxy analyses performed on hemipelagic sediments deposited on the Nile deep-sea fan allow the quantification of the Saharan aeolian dust and the Blue/White Nile River suspended matter frequency fluctuations during the last 21,000 years. The radiogenic strontium and neodymium isotopes, clay mineralogy, elemental composition and preliminary palynological analyses reveal large changes in source components, oscillating between a dominant aeolian Saharan contribution during the Last Glacial Maximum (LGM) and the late Holocene (~4,000–2,000 years), a dominant Blue/Atbara Nile River contribution during the early Holocene (15,000–8,000 years) and a probable White Nile River contribution during the middle Holocene (8,000–4,000 years). The following main features are highlighted: (1) The rapid shift from the LGM arid conditions to the African Humid Period (AHP) started at about 15,000 years. The AHP extends until 8,000 years, and we suggest that the EAM maximum between 15,000 and 8,000 years is responsible for a larger Blue/Atbara Nile sediment load and freshwater input into the eastern Mediterranean Sea. (2) The transition between the AHP and the arid late Holocene is gradual and occurs in two main phases between 8,400–6,500 years and 6,500–3,200 years. We suggest that the main rain belt shifted southward from 8,000 to ~4,000 years and was responsible for progressively reduced sediment load and freshwater input into the eastern Mediterranean Sea. (3) The aridification along the Nile catchments occurred from ~4,000 to 2,000 years. This dry period, which culminates at 3,200 year, seems to coincide with a re-establishment of increased oceanic primary productivity in the western Mediterranean Sea. Such a pattern imposes a large and rapid northward shift of the rain belt over the Ethiopian highlands (5–15°N) since 15,000 years. Precipitation over Ethiopia increased from 15,000 to 8,000 years. It was followed by a gradual southward shift of the rain belt over the equator from 8,000 to 4,000 years and finally a large shift of the rain belt south the equator between 4,000 and 2,000 years inducing North African aridification. We postulate that the decrease in thermohaline water Mediterranean circulation could be part of a response to huge volumes of freshwater delivered principally by the Nile River from 15,000 to 8,000 years in the eastern Mediterranean.     

Challenges in assessing the environmental consequences of dietary changes

Tom et al. (Environ Syst Decis 1–12, 2015) compared the energy requirements, water footprint, and greenhouse gas emissions of diet regimens recently recommended by the US Department of Agriculture. This editorial comments on a number of challenges related to the use of the results of life-cycle assessment studies to quantify the environmental impacts of dietary shifts.     

Influence of angular exposure and proximity to vehicular traffic on the diversity of epiphytic lichens and the bioaccumulation of traffic-related elements

This study investigated the influence of angular exposure and distance from vehicular traffic on the diversity of epiphytic lichens and the bioaccumulation of traffic-related elements in a town of central Italy. An Index of Lichen Diversity (ILD) was calculated on the street-facing and the opposite side of road-lining trees and in a urban park 250 m away, and the content of selected trace elements (Al, Ba, Ce, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Sb, V, and Zn) was determined in samples of the lichen Punctelia borreri (Sm.) Krog growing on tree bark, both on the exposed and opposite sides. ILD increases with distance from traffic emissions. However, at the site with vehicle traffic, non-nitrophilous lichens decreased while nitrophilous ones increased. The concentration of the traffic-related elements Ba, Cr, Cu, Mn, Sb, and Zn accumulated in thalli of P. borreri was higher on roadside trees than in trees from the urban park. ILD was not affected by the angular exposure to the road and the bioaccumulation of traffic-related elements was similar in lichens from the side of the bole exposed to traffic emissions and particulate resuspension and from the opposite side. The angular exposure in respect to the traffic source does not influence trace element accumulation. These results are important when using lichens for biomonitoring purposes, both for planning future studies and for the reliability of the interpretation of past surveys that do not report information about the angular exposure of the collected lichen material.     

Choosing an Aerometric Data System

The air quality of an urban area depends to a great extent upon the quantity and type of fuel consumed. Thus, a marked change in energy demand from 1960 to 2000 A.D. will affect the air quality of all of our urban centers. Interwoven with this potential effect is the anticipated influence of the change in type and quality of fuels, e.g., nuclear fuels, high sulfur coals, and a major modification in energy derived motive power, i.e., fuel cells, and the subsequent depletion of natural gas as an energy raw material. The current trend is to greater urban population densities, and it is estimated that by the year 2000 A.D., 85 percent of America’s population will live on only 10 percent of the land mass. To assess the potential impact of the energy demands for the next half century on air quality, particularly of America’s urban centers, a review of current practices of combustion of coal, petroleum, and natural gas, and the potential effect on community air quality will be developed. To meet the impact of the interrelated changing patterns of population growth, urban developments, energy requirements and available sources, research needs on both a short and long term basis will be explored.     

Monitoring H2S air pollution caused by the industrial exploitation of geothermal energy: The pitfall of using lichens as bioindicators

This study showed that NH₃ emitted from geothermal power plants affects the surrounding epiphytic lichen vegetation and diversity, confounding the interpretation of lichen diversity counts in terms of air pollution by H₂S. The presence of nitrophytic lichen species around geothermal installations, determined by NH₃, caused relatively high diversity values that were not related with the levels of air pollution by H₂S. It is recommended that in the presence of NH₃ emission, nitrophytic species are excluded from the calculation of lichen diversity values.     

Valuing Improvements in The Water Rights System in South Africa: A Contingent Ranking Approach1

Speelman, Stijn, Stefano Farolfi, Aymen Frija, and Guido Van Huylenbroeck, 2010. Valuing Improvements in the Water Rights System in South Africa: A Contingent Ranking Approach. Journal of the American Water Resources Association (JAWRA) 46(6):1133–1144. DOI: 10.1111/j.1752-1688.2010.00480.x Abstract: In the context of increasing water scarcity, understanding is growing that irrigation water rights are important and that a lack of an effective water rights system constitutes a major reason for inefficient water management. This study carried out a contingent ranking experiment to study how smallholder irrigators in South Africa would value potential changes in water rights. Three specific dimensions of water rights, relevant for the South African case, are considered: duration, quality of title, and transferability. Results indicate that smallholder irrigators are prepared to pay considerably higher water prices if improvements are made in the water rights system. This implies that the proposed interventions in the water rights system would improve the efficiency and productivity of the small-scale irrigation sector. The increased willingness to pay could furthermore also assist the South African government to reach the objective of increased cost recovery.     

Lake Temperature and Ice Cover Regimes in the Alaskan Subarctic and Arctic: Integrated Monitoring,Remote Sensing,and Modeling1

Arp, C.D., B.M. Jones, M. Whitman, A. Larsen, and F.E. Urban, 2010. Lake Temperature and Ice Cover Regimes in the Alaskan Subarctic and Arctic: Integrated Monitoring, Remote Sensing, and Modeling. Journal of the American Water Resources Association (JAWRA) 46(4): 777-791. DOI: 10.1111/j.1752-1688.2010.00451.x Abstract: Lake surface regimes are fundamental attributes of lake ecosystems and their interaction with the land and atmosphere. High latitudes may be particularly sensitive to climate change, however, adequate baselines for these lakes are often lacking. In this study, we couple monitoring, remote sensing, and modeling techniques to generate baseline datasets of lake surface temperature and ice cover in the Alaskan Subarctic and Arctic. No detectable trends were observed during this study period, but a number of interesting patterns were noted among lakes and between regions. The largest Arctic lake was relatively unresponsive to air temperature, while the largest Subarctic lake was very responsive likely because it is fed by glacial runoff. Mean late summer water temperatures were higher than air temperatures with differences ranging from 1.7 to 5.4°C in Subarctic lakes and from 2.4 to 3.2°C in Arctic lakes. The warmest mean summer water temperature in both regions was in 2004, with the exception of Subarctic glacially fed lake that was highest in 2005. Ice-out timing had high coherence within regions and years, typically occurring in late May in Subarctic and in early-July in Arctic lakes. Ice-on timing was more dependent on lake size and depth, often varying among lakes within a region. Such analyses provide an important baseline of lake surface regimes at a time when there is increasing interest in high-latitude water ecosystems and resources during an uncertain climate future.     

Persistence and distribution of pesticide residues in fresh agricultural food consumed in the province of Bologna

The presence of pesticide residues in fresh vegetables and fruit have been qualitatively and quantitatively determined at the laboratories of the Regional Agency for Environmental Protection (ARPA), Division of the Province of Bologna. More than 1,700 samples have been tested by routine analyses. The possible risks for consumers have been evaluated by various parameters. The most important ones were: the amount of each residue; the respective ADI (Acceptable Daily Intake) limit; the contemporary presence of different residues; an estimation of the daily intake, based on the amount of fruit and vegetables consumed per person. It has been possible to evaluate that the daily intake of pesticide residues in the province of Bologna during the period 2003–06 resulted lower than the ADI limits concerning the vegetables. According to the information on fruit consumption the daily intake of omethoate (O,O-dimethyl S-methylcarbamoylmethyl phosphorothioate) resulted higher than its ADI limit, of dicofol (2,2,2-trichloro-1,1-bis(trichloromethyl)benzenemethanol) very close to the admitted limit, under the respective limits for all the other residues.