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951.
Stephen J. White Merched Azzi Dennys E. Angove Ian M. Jamie 《Atmospheric environment (Oxford, England : 1994)》2010,44(40):5375-5382
The photooxidation of fuel vapour was investigated in a smog chamber and simulated using three chemical mechanisms, the Master Chemical Mechanism (MCMv3.1), SAPRC-99 and the Carbon Bond chemical mechanism (CB05). Three varieties of fuel were used, unleaded petrol (ULP) and two ULP-ethanol blends which contained 5% and 10% ethanol (E5, E10). The fuel vapours were introduced into the chamber using two methods, by injecting the vapours from wholly evaporated fuel directly, and by injecting the headspace vapour from fuel equilibrated at 38 °C. The chamber experiments were simulated using the selected mechanisms and comparisons made with collected experimental data.The SAPRC-99 mechanism reproduced Δ(O3–NO) more accurately for almost all fuel types and injection modes, with negligible model error for both injection modes. The average model error for MCM simulations was ?16% and for CB05 the average model error was ?34%. The predictions for the CB05 mechanism varied depending on injection mode, the Δ(O3–NO) model error for wholly evaporated experiments was ?44%, compared to ?24% for headspace vapour experiments. The difference in aromatic content between experiments of different injection modes was likely to be the cause of the difference in model error for CB05. The model error for all headspace experiments was dependent upon the initial carbon monoxide concentrations.The results for Δ(O3–NO) were matched by the prediction of other key products, with formaldehyde predicted to within 20% by both SAPRC and the MCM. The addition of ethanol to the base SAPRC mechanism altered the predictions of Δ(O3–NO) by less than 2%. Changes observed in the concentrations of formaldehyde and acetaldehyde were consistent with the expected yields from ethanol oxidation. 相似文献
952.
A contingent valuation study was conducted with adult Kenyan citizens and foreign tourists to estimate the value of recreational
benefits arising from coral reefs at Mombasa Marine National Park and Reserve (MMNPR), and to assess the implications for
local reef management. Citizen and foreign visitors to MMNPR were willing to pay an extra $2.2 (median = $2.2 (median = 1.6) and $8 (median = $8 (median = 6.7)
per visit respectively, in addition to current park entrance fees, to support reef quality improvements. By aggregating visitors’
willingness to pay bids over the number of visitors to MMNPR in 2006–2007 the value of benefits was estimated at 346,733, which was more than twice the total annual operational expenditure of346,733,
which was more than twice the total annual operational expenditure of 152,383 for MMNPR. The findings indicate that annual
revenues from citizen and foreign visitors may be increased by 60% to 261,932 through the implementation of proposed higher park fees of261,932 through the implementation of proposed higher
park fees of 3.10 for citizens and $15 for foreign visitors. However, any fee increase would serve to intensify concerns
among citizens that only relatively affluent Kenyans can afford to visit MMNPR. Park managers need to demonstrate that the
extra revenue would be used to fund the proposed conservation activities. This valuation study demonstrates that visitors
are prepared to pay higher user fees for access to the marine protected area revealing considerable untapped resource to finance
reef quality improvements. 相似文献
953.
J. Denis Newbold Susan Herbert Bernard W. Sweeney Paul Kiry Stephen J. Alberts 《Journal of the American Water Resources Association》2010,46(2):299-310
Newbold, J. Denis, Susan Herbert, Bernard W. Sweeney, Paul Kiry, and Stephen J. Alberts, 2010. Water Quality Functions of a 15-Year-Old Riparian Forest Buffer System. Journal of the American Water Resources Association (JAWRA) 46(2):299-310. DOI: 10.1111/j.1752-1688.2010.00421.x Abstract: We monitored long-term water quality responses to the implementation of a three-zone Riparian Forest Buffer System (RFBS) in southeastern Pennsylvania. The RFBS, established in 1992 in a 15-ha agricultural (row crop) watershed, consists of: Zone 1, a streamside strip (∼10 m wide) of permanent woody vegetation for stream habitat protection; Zone 2, an 18- to 20-m-wide strip reforested in hardwoods upslope from Zone 2; and Zone 3, a 6- to 10-m-wide grass filter strip in which a level lip spreader was constructed. The monitoring design used paired watersheds supplemented by mass balance estimates of nutrient and sediment removal within the treated watershed. Tree growth was initially delayed by drought and deer damage, but increased after more aggressive deer protection (1.5 m polypropylene shelters or wire mesh protectors) was instituted. Basal tree area increased ∼20-fold between 1998 and 2006, and canopy cover reached 59% in 2006. For streamwater nitrate, the paired watershed comparison was complicated by variations in both the reference stream concentrations and in upslope groundwater nitrate concentrations, but did show that streamwater nitrate concentrations in the RFBS watershed declined relative to the reference stream from 2002 through the end of the study in early 2007. A subsurface nitrate budget yielded an average nitrate removal by the RFBS of 90 kg/ha/year, or 26% of upslope subsurface inputs, for the years 1997 through 2006. There was no evidence from the paired watershed comparison that the RFBS affected streamwater phosphorus concentration. However, groundwater phosphorus did decline within the buffer. Overland flow sampling of 23 storms between 1997 and 2006 showed that total suspended solids concentration in water exiting the RFBS to the stream was on average 43% lower than in water entering the RFBS from the tilled field. Particulate phosphorus concentration was lower by 22%, but this removal was balanced by a 26% increase in soluble reactive phosphorus so that there was no net effect on total phosphorus. 相似文献
954.
Daniel P. Connell Stephen E. Winter Vincent B. Conrad Myoungwoo Kim Kevin C. Crist 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1750-1766
Abstract The elemental compositions of the water-soluble and acid-digestible fractions of 24-hr integrated fine particulate matter (PM2.5) samples collected in Steubenville, OH, from 2000 to 2002 were determined using dynamic reaction cell inductively coupled plasma-mass spectrometry. The water-soluble elemental compositions of PM2.5 samples collected at four satellite monitoring sites in the surrounding region were also determined. Fe was the most abundant but least water soluble of the elements determined at the Steubenville site, having a mean ambient concentration of 272 µg/m3 and a median fractional solubility of 6%. Fe solubility and its correlations with SO4 2? and temperature varied significantly by season, consistent with the hypothesis that secondary sulfates may help to mobilize soluble Fe under suitable summertime photochemical conditions. Significantly higher ambient concentrations were observed at Steubenville than at each of the four satellite sites for 10 of the 18 elements (Al, As, Ca, Cd, Fe, Mg, Mn, Na, Pb, and Zn) determined in the water-soluble PM2.5 fraction. Concentrations of Fe, Mn, and Zn at Steubenville were substantially higher than concentrations reported recently for larger U.S. cities. Receptor modeling identified seven sources affecting the Steubenville site. An (NH4)2SO4-dominated source, likely representing secondary PM2.5 from coal-fired plants to the west and southwest of Steubenville, accounted for 42% of the PM2.5 mass, and two sources likely dominated by emissions from motor vehicles and from iron and steel facilities in the immediate Steubenville vicinity accounted for 20% and 10%, respectively. Other sources included an NH4NO3 source (15%), a crustal source (6%), a mixed nonferrous metals and industrial source (3%), and a primary coal combustion source (3%). Results suggest the importance of very different regional and local source mechanisms in contributing to PM2.5 mass at Steubenville and reinforce the need for further research to elucidate whether metals such as Fe, Mn, and Zn play a role in the PM2.5 health effects observed previously there. 相似文献
955.
956.
Research on the environmental fate and transport of PCBs in Lake Ontario basin depends, among other aspects, on the availability of representative data sets for upstream sources, but data are lacking for most US Lake Ontario tributaries. In this study, water samples were collected between September 2004 and October 2008 from five tributaries and were analyzed for 209 polychlorinated biphenyls (PCB) with high-resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) following EPA Method 1668A. Total PCB concentrations ranged between 0.31 and 42.75 ng L−1. Congeners between Di and Hexa PCBs accounted between 70 and 99% of the total PCB. The tributary with highest PCB concentrations presented similar pattern and percentage levels to Aroclor 1242. Total average loads for the sampling events ranged between 1.85 g d−1 and 59.08 g d−1. PCB concentrations were evaluated against other variables and other studies (including different matrices) to better understand their transport. The methodology used is reliable to assess PCB contamination in surface water. 相似文献
957.
Koracin D Vellore R Lowenthal DH Watson JG Koracin J McCord T DuBois DW Chen LW Kumar N Knipping EM Wheeler NJ Craig K Reid S 《Journal of the Air & Waste Management Association (1995)》2011,61(6):660-672
The main objective of this study was to investigate the capabilities of the receptor-oriented inverse mode Lagrangian Stochastic Particle Dispersion Model (LSPDM) with the 12-km resolution Mesoscale Model 5 (MM5) wind field input for the assessment of source identification from seven regions impacting two receptors located in the eastern United States. The LSPDM analysis was compared with a standard version of the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) single-particle backward-trajectory analysis using inputs from MM5 and the Eta Data Assimilation System (EDAS) with horizontal grid resolutions of 12 and 80 km, respectively. The analysis included four 7-day summertime events in 2002; residence times in the modeling domain were computed from the inverse LSPDM runs and HYPSLIT-simulated backward trajectories started from receptor-source heights of 100, 500, 1000, 1500, and 3000 m. Statistics were derived using normalized values of LSPDM- and HYSPLIT-predicted residence times versus Community Multiscale Air Quality model-predicted sulfate concentrations used as baseline information. From 40 cases considered, the LSPDM identified first- and second-ranked emission region influences in 37 cases, whereas HYSPLIT-MM5 (HYSPLIT-EDAS) identified the sources in 21 (16) cases. The LSPDM produced a higher overall correlation coefficient (0.89) compared with HYSPLIT (0.55-0.62). The improvement of using the LSPDM is also seen in the overall normalized root mean square error values of 0.17 for LSPDM compared with 0.30-0.32 for HYSPLIT. The HYSPLIT backward trajectories generally tend to underestimate near-receptor sources because of a lack of stochastic dispersion of the backward trajectories and to overestimate distant sources because of a lack of treatment of dispersion. Additionally, the HYSPLIT backward trajectories showed a lack of consistency in the results obtained from different single vertical levels for starting the backward trajectories. To alleviate problems due to selection of a backward-trajectory starting level within a large complex set of 3-dimensional winds, turbulence, and dispersion, results were averaged from all heights, which yielded uniform improvement against all individual cases. 相似文献
958.
A new method of determining the composition of sediment/soil gases and their volatile organic compound (VOC) content is described. VOCs were collected in situ from intertidal sediments in the Menai Strait and surrounding areas. The sampling was performed using a portable sampler comprising a funnel coupled to a SPME fibre. Gases were extracted from the sediments using a small vacuum pump pulling 100 mL min(-1) at atmospheric pressure. Sixty one different compounds were detected in the samples, and their fluxes and concentrations were determined. The compounds were classified into groups: halogenated, sulfur containing compounds, aldehydes, BTEXs (benzene, toluene, ethyl benzene and xylene) and aliphatic hydrocarbons. Results of principal component analysis (PCA) showed that the chemical composition of extracted gas was influenced primarily by sediment type. Muddy anoxic sediments were dominated by halogenated and sulfur containing compounds and sandy sediments had more aldehydes and BTEXs. 相似文献
959.
The relationship between residence time and oxygen saturation was investigated in a mesotidal lagoon in southern Portugal. The system receives no significant freshwater input during the summer months and has a high evaporation rate. These features enable an estimate of residence time from the salinity differences between ocean water entering the system and lagoon water. More than 10,000 GPS referenced measurements of oxygen saturation, temperature and salinity were made during large spring tides in September, 2006. The lowest oxygen saturation ( approximately 44%) was measured in the waters with the highest calculated residence times (7 days). There was a significant linear decrease in the oxygen saturation with increasing residence time of approximately 16% per day. This was similar to the rate measured on a neap tide in August, 2005. The high salinity, low oxygen saturated water was spatially confined to one inner channel, except at high water when this water was pushed into other channels. Although the tides investigated were the largest for several years, the oxygen saturation did not exceed 70% in this inner region. It is proposed that the direct discharge of oxygen consuming effluent, including domestic sewage, into this inner channel is responsible for this persistent oxygen deficit. 相似文献
960.
Hur J Schlautman MA Karanfil T Smink J Song H Klaine SJ Hayes JC 《Environmental monitoring and assessment》2007,132(1-3):171-187
The Reedy River in South Carolina is affected by the urban area of Greenville, the third most populous city in the state,
and by the effluents from two large-scale municipal wastewater treatment plants (WWTPs) located on the river. Riverine water
chemistry was characterized using grab samples collected annually under spring season baseflow conditions. During the 4-year
time period associated with this study, climatic variations included two severe drought spring seasons (2001 and 2002), one
above-normal precipitation spring season (2003), and one below-normal precipitation spring season (2004). The influence of
drought and human activities on the baseflow chemistry of the river was evaluated by comparing concentrations of dissolved
anions, total metals, and other important water chemistry parameters for these different years. Concentrations of copper and
zinc, common non-point source contaminants related to urban activities, were not substantially elevated in the river within
the urban area under baseflow conditions when compared with headwater and tributary samples. In contrast, nitrate concentrations
increased from 1.2–1.6 mg/l up to 2.6–2.9 mg/l through the urban stream reach. Concentrations of other major anions (e.g.,
sulfate, nitrate) also increased along the reach, suggesting that the river receives continuous inputs of these species from
within the urban area. The highest concentrations of major cations and anions typically were observed immediately downstream
from the two WWTP effluent discharge locations. Attenuation of nitrate downstream from the WWTPs did not always track chloride
changes, suggesting that nitrate concentrations were being controlled by biochemical processes in addition to physical processes.
The relative trends in decreasing nitrate concentrations with downstream distance appeared to depend on drought versus non-drought
conditions, with biological processes presumably serving as a more important control during non-drought spring seasons. 相似文献