Dissolution kinetics of sub-millimeter Composition B detonation residues: role of particle size and particle wetting

The dissolution of the 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) from microscale particles (<250 μm) of the explosive formulation Composition B was examined and compared to dissolution from macroscopic particles (>0.5 mm). The dissolution of explosives from detonation soot was also examined. The measured mass transfer coefficients for the microscale particles were one to two orders of magnitude greater than the macroscopic particles. When normalized to particle surface area, mass transfer coefficients of microscale and macroscale particles were similar, indicating that the bulk dissolution processes were similar throughout the examined size range. However, an inverse relationship was observed between the particle diameter and the RDX:TNT mass transfer rate coefficient ratio for dry-attritted particles, which suggests that RDX may be more readily dissolved (relative to TNT) in microscale particles compared to macroscale particles. Aqueous weathering of larger Composition B residues generated particles that possessed mass transfer coefficients that were on the order of 5- to 20-fold higher than dry-attritted particles of all sizes, even when normalized to particle surface area. These aqueous weathered particles also possessed a fourfold lower absolute zeta-potential than dry-attritted particles, which is indicative that they were less hydrophobic (and hence, more wettable) than dry-attritted particles. The increased wettability of these particles provides a plausible explanation for the observed enhanced dissolution. The wetting history and the processes by which particles are produced (e.g., dry physical attrition vs. aqueous weathering) of Composition B residues should be considered when calculating mass transfer rates for fate and transport modeling.     

The Effects of Population Density on Juvenile Growth Rate in White-Tailed Deer

Animal body size is driven by habitat quality, food availability, and nutrition. Adult size can relate to birth weight, to length of the ontogenetic growth period, and/or to the rate of growth. Data requirements are high for studying these growth mechanisms, but large datasets exist for some game species. In North America, large harvest datasets exist for white-tailed deer (Odocoileus virginianus), but such data are collected under a variety of conditions and are generally dismissed for ecological research beyond local population and habitat management. We contend that such data are useful for studying the ecology of white-tailed deer growth and body size when analyzed at ordinal scale. In this paper, we test the response of growth rate to food availability by fitting a logarithmic equation that estimates growth rate only to harvest data from Fort Hood, Texas, and track changes in growth rate over time. Results of this ordinal scale model are compared to previously published models that include additional parameters, such as birth weight and adult weight. It is shown that body size responds to food availability by variation in growth rate. Models that estimate multiple parameters may not work with harvest data because they are prone to error, which renders estimates from complex models too variable to detect interannual changes in growth rate that this ordinal scale model captures. This model can be applied to harvest data, from which inferences about factors that influence animal growth and body size (e.g., habitat quality and nutritional availability) can be drawn.     

A Framework to Integrate Habitat Monitoring and Restoration with Endangered Insect Recovery

Monitoring is essential to track the long-term recovery of endangered species. Greater emphasis on habitat monitoring is especially important for taxa whose populations may be difficult to quantify (e.g., insects) or when true recovery (delisting) requires continuous species-specific habitat management. In this paper, we outline and implement a standardized framework to facilitate the integration of habitat monitoring with species recovery efforts. The framework has five parts: (1) identify appropriate sample units, (2) select measurable indicators of habitat requirements, (3) determine rating categories for these indicators, (4) design and implement appropriate data collection protocols, and (5) synthesize the ratings into an overall measure of habitat potential. Following these steps, we developed a set of recovery criteria to estimate habitat potential and initially assess restoration activities in the context of recovering an endangered insect, the Karner blue butterfly (Lycaeides melissa samuelis). We recommend basing the habitat potential grading scheme on recovery plan criteria, the latest information on species biology, and working hypotheses as needed. The habitat-based assessment framework helps to identify which recovery areas and habitat patches are worth investing in and what type of site-specific restoration work is needed. We propose that the transparency and decision-making process in endangered insect recovery efforts could be improved through adaptive management that explicitly identifies and tracks progress toward habitat objectives and ultimate population recovery.     

Effects of attached data-logging devices on little penguins (Eudyptula minor)

Data-logging devices are commonly used to study the foraging behaviour of individual seabirds. Such studies need to examine the potential effects of using devices on instrumented individuals, not only for ethical reasons but also to ensure the validity of data gathered. We studied the effects of two types of device (time-depth recorder and global positioning system) on little penguins (Eudyptula minor) during the 2010 and 2011 breeding season at Oamaru, New Zealand. Mixed-effect models were used to test for effects of devices by comparing changes in body weight, chick growth and breeding performance between instrumented and control individuals. We found no detectable effects of the attached devices on body weight change, hatching success, fledging success, chick growth parameters or adult survival. We conclude that it is possible to attach data-logging devices to adult little penguins for extended periods during the breeding season with minimal impacts.     

The rise of risk and the decline of politics

This paper argues that the rise of risk and formal risk assessment has contributed to the demise of representative democratic politics by displacing public discourses about values with technical justifications for decision making. Furthermore, risk plays a central role in the displacement of governmental responsibility to private sector and NGO actors at the same time as facilitating government control over citizens—the Janus faces¹ of governance and governmentality. Arguing that the turn to public participation cannot be the panacea for the present situation, the paper concludes by calling for revitalisation of representative institutions, the development of real-time technology assessment and development of popular connoisseurship of science and technology.     

Book reviews

ENFORCEMENT AND STOP NOTICES

Felix Bourne

Sweet and Maxwell, London 1986

SMALL FACTORIES AND ECONOMIC DEVELOPMENT

By Martin Perry

(Aldershot; Gower, 1986, pp.xvi + 229) £22.50

WHATEVER HAPPENED TO PLANNING?

Peter Ambrose, 1986

Methuen, London and New York, 288pp, £8.95.     

Seeds and rights: new approaches to post-war agricultural rehabilitation in Sierra Leone

Based on preliminary findings of ongoing 'action research' in the war zone in central Sierra Leone, this paper shows how more equitable seed distribution could contribute to fostering a culture of human rights as well as to agricultural rehabilitation. Assessment of seeds-and-toosl programmes in 19 villages found that aid agency targeting and distribution modalities channelled inputs through village committees which denied assistance to intended beneficiary groups. Such distribution inequalities constitute violations of fundamental human rights, exacerbate grievance and division and maintain the threat of social disorder. The benefits and disadvantages of an alternative, more inclusive, rights-based approach to seed distribution are discussed, and preliminary results from the pilot phase of CARE's Rights-based Approach to Food Security Project are presented. Under this project, village-level peace and rights days are held to allow villagers to debate the vulnerabilities that facilitated the war and to elaborate on local notions of human rights. In symbolising new beginnings, seed can be seen as a useful medium through which to debate a more inclusive--and ultimately less vulnerable--society.     

Can public engagement democratize environmental policymaking in a resource-dependent state? Comparative case studies from Alberta,Canada

What factors shape the democratic potential of public consultation in environmental policymaking? Here, the motivations, purposes, designs, and outcomes of recent public engagement on land use planning, climate change policy, and water resource management in Alberta, Canada are reviewed in order to show how the power dynamics of the political and economic context shape the democratic potential of public and stakeholder consultations, especially where dominant resource interests are at stake. At the same time, political leadership, interactions between civil society actors and key design elements are shown to be important to democratization.