Distribution and transport of coal tar-derived PAHs in fine-grained residuum

We investigated the distribution and transport of coal tar-derived polycyclic aromatic hydrocarbons (PAHs) in fine-grained residuum and alluvial floodplain deposits that underlie a former manufactured gas plant. All 16 USEPA priority pollutant PAHs are present at this site and have penetrated the entire 4-5m thickness of clayey sediments, which unconformably overly limestone bedrock. Concentrations of less hydrophobic PAHs (e.g., naphthalene, 0.011-384mg kg(-1)) were about 10 times higher than those of highly hydrophobic PAHs (e.g., benzo[g,h,i]perylene -0.002 to 56.03mgkg(-1)). Microscopic examination of thin-sections of the clay-rich sediments showed that fractures and rootholes, which can act as pathways for flow, occur throughout the profiles. Tarry residue was found coating some fractures and rootholes, indicating that coal tar was, in some cases, able to penetrate as an immiscible phase. However, in the vast majority of samples in which PAHs were detected, there was no detectable tar residue, suggesting that much of the transport occurred in the dissolved phase. Examination of thin-sections with an epifluorescent microscope indicated that PAHs, which fluoresce brightly when exposed to UV light, are distributed throughout the soil matrix, rather than being confined to fractures and rootholes. The widespread distribution of PAHs is most likely due to diffusion-controlled exchange between the fast-flow pathways in the fractures and rootholes and the relatively immobile water in the fine-grained matrix. This implies that fractures and rootholes can play a major role in controlling transport of highly hydrophobic compounds in fine-grained sediments, which would otherwise act as barriers to contaminant migration.     

Landscape change: Perceptions and physical measures

This paper addresses questions of affective responses of residents of rural Arizona to changes in proximate community and riparian landscapes and the congruence of their perceptions of change with physical measures of change in those landscapes. Based on findings and concepts from previous studies, perceptions of change were assessed using a mail survey. Physical measures of land use and vegetation change were obtained from aerial photography for two points in time spanning approximately 13 years and were analyzed using a geographic information system. Significant differences were found in perceptions of change in the community and riparian landscapes. In contrast with previous findings, a majority of respondents found the changes as either improving or having no effect on landscape quality. Those who were more frequent users of the riparian landscape tended to be more aware of changes in it. The findings also suggest challenges for planners and resource managers working in rural areas adjacent to riparian landscapes.     

IRRIGATION DEVELOPMENT AND MANAGEMENT ALTERNATIVES OF A DOLOMITE AQUIFER IN NORTHEASTERN ILLINOIS1

ABSTRACT: Irrigation development of the dolomite aquifer in eastera Kankakee and northern Iroquois Counties, Illinois, is extensive and increasing. Interruptions of domestic supplies have been reported with increasing frequency during the 1980's. To address this issue, a regional assessment of the ground-water resources of the region was conducted in 1987 and 1988. Options for managing the dolomite aquifer were also investigated. Hydrogeology of the dolomite aquifer was determined using five aquifer tests. Tranamissivity values of the dolomite aquifer ranged from 14,000 to 50,000 gpd/ft (168 to 600 m³/m/day). Storage coefficients were between 0.0001 and 0.0002, within the range of a confined (artesian) aquifer. Based on flow-net analyses, recharge of the dolomite aquifer ranged from 85,000 to 285,000 gpd/mi² (124.4 to 417.0 m³/day/km²). Water levels of the dolomite aquifer were mapped during five periods in 1987 and 1988 by measuring up to 226 wells completed in the dolomite aquifer. Maximum regional water-level declines because of irrigation pumpage were 44 feet (13.4 m) in 1987 and 72 feet (21.9 m) during the drought of 1988. Based on ground-water use data, precipitation records, and hydrogeologic information, the magnitude of water-level declines can be attributed more to differing hydrogeologic conditions than to pumpage or climatic changes. Existing ground-water management methods for resolving conflicts over the ground-water resources of the study area are reviewed and alternative management options explored.     

GEOLOGIC INFERENCE FROM “FLOW NET” TRANSMISSIVITY DETERMINATION: THREE CASE STUDIES1

A graphical inverse method for determining the regional transmissivity distribution was applied to three field problems. The study areas were the Hanford Site, Washington; the Rocky Mountain Arsenal, Colorado; and the Nevada Test Site, Nevada. This method can aid in flow system conceptualization by revealing the location of bedrock controls for groundwater flow. It is a valuable tool for aiding the hydrogeologist in asking questions about the nature of trends in the pattern of transmissivity values. Quantitative estimates of regional transmissivities can be used as starting points for further parameter refinement. Sensitivity analysis using Monte Carlo simulation shows that quantitative estimates of transmissivity can be obtained when measurement error in the hydraulic head does not cause a large error in the hydraulic gradient.     

Woody plant roots fail to penetrate a clay-lined landfill: Managment implications

In many locations, regulatory agencies do not permit tree planting above landfills that are sealed with a capping clay, because roots might penetrate the clay barrier and expose landfill contents to leaching. We find, however, no empirical or theoretical basis for this restriction, and instead hypothesize that plant roots of any kind are incapable of penetrating the dense clays used to seal landfills. As a test, we excavated 30 trees and shrubs, of 12 species, growing over a clay-lined municipal sanitary landfill on Staten Island, New York. The landfill had been closed for seven years, and featured a very shallow (10 to 30-cm) soil layer over a 45-cm layer of compacted grey marl (Woodbury series) clay. The test plants had invaded naturally from nearby forests. All plants examined—including trees as tall as 6 m—had extremely shallow root plates, with deformed tap roots that grew entirely above and parallel to the clay layer. Only occasional stubby feeder roots were found in the top 1 cm of clay, and in clay cracks at depths to 6 cm, indicating that the primary impediment to root growth was physical, although both clay and the overlying soil were highly acidic. These results, if confirmed by experimental research should lead to increased options for the end use of many closed sanitary landfills.     

FREQUENCY-DURATION ANALYSIS OF DISSOLVED-OXYGEN CONCENTRATIONS IN TWO SOUTHWESTERN WISCONSIN STREAMS1

ABSTRACT: Historically, dissolved-oxygen (DO) data have been collected in the same manner as other water-quality constituents, typically at infrequent intervals as a grab sample or an instantaneous meter reading. Recent years have seen an increase in continuous water-quality monitoring with electronic dataloggers. This new technique requires new approaches in the statistical analysis of the continuous record. This paper presents an application of frequency-duration analysis to the continuous DO records of a cold and a warm water stream in rural southwestern Wisconsin. This method offers a quick, concise way to summarize large time-series data bases in an easily interpretable manner. Even though the two streams had similar mean DO concentrations, frequency-duration analyses showed distinct differences in their DO-concentration regime. This type of analysis also may be useful in relating DO concentrations to biological effects and in predicting low DO occurrences.     

Modeling channel management impacts on river migration: a case study of Woodson bridge state recreation area,Sacramento river,California, USA

Understanding how hydraulic factors control alluvial river meander migration can help resource managers evaluate the long-term effects of floodplain management and bank stabilization measures. Using a numerical model based on the mechanics of flow and sediment transport in curved river channels, we predict 50 years of channel migration and suggest the planning and ecological implications of that migration for a 6.4-km reach (river miles 218–222) of the Sacramento River near the Woodson Bridge State Recreation Area, California, USA. Using four different channel management scenarios, our channel migration simulations suggest that: (1) channel stabilization alters the future channel planform locally and downstream from the stabilization; (2) rock revetment currently on the bank upstream from the Woodson Bridge recreation area causes more erosion of the channel bank at the recreation area than if the revetment were not present; (3) relocating the channel to the west and allowing subsequent unconstrained river migration relieves the erosion pressure in the Woodson Bridge area; (4) the subsequent migration reworks (erodes along one river bank and replaces new floodplain along the other) 26.5 ha of land; and (5) the river will rework between 8.5 and 48.5 ha of land in the study reach (over the course of 50 years), depending on the bank stabilization plan used. The reworking of floodplain lands is an important riparian ecosystem function that maintains habitat heterogeneity, an essential factor for the long-term survival of several threatened and endangered animal species in the Sacramento River area.     

Sustainable urban planning and the brownfield development process in the United Kingdom: Lessons from the Thames Gateway

Over recent decades urban and regional development agendas in the United Kingdom have become dominated by the discourses of sustainable development, holistic regeneration and community capacity-building. It is in this context that brownfield development has emerged as a core feature in strategies to regenerate urban areas. Bringing brownfields back into use tends to be, a priori, presented as a 'good thing' that will have broader economic, environmental and social benefits. This paper assesses the role that brownfield development plays in urban and regional policy agendas in the UK. It begins by identifying the rationales for, and concerns associated with, the brownfield development process in the UK, before discussing the trajectories of policy under the New Labour government since 1997. It argues that at present too much is expected from brownfield-led regeneration programmes and that wider benefits will only accrue if these programmes are embedded within a wider and more comprehensive set of development projects and policy agendas.     

Risk communication as a key component of a successful remediation project

Decisions made during the course of investigating and remediating a contaminated site, as well as the technology used, are most often driven exclusively by physical, technical, and health-based concerns. Additionally, in both determining and managing the potential risks posed by a remediation project, the focus tends to be placed primarily on health risks. However, a contaminated site and its remediation are neither static over time nor do they exist in a vacuum. Other elements of risk associated with the site and remedial activities include continuing regulatory oversight and compliance, public and agency relations, remedial technology costs, current and future land-use issues, and future technological/regulatory risks. Agencies, consultants, contractors, and facility management must consider these other non-health-related elements of risk. Additionally, efforts made to communicate a project's decisions, technologies, and risks are often made in a defensive or reactive posture, resulting in ineffective communication and an alienated, angry, or distrustful public. Proactive risk communication, as well as public involvement in the remedial process, are critical to the success of any remedial activity.