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261.
A limited number of different foods were analysed for dioxin-like compounds by the CALUX bioassay which is an in vitro luciferase reporter gene assay measuring chemical activation of the aryl hydrocarbon receptor. Sixty-two milk samples were obtained from a surveillance campaign, 34 meat samples and 34 fishery products were purchased from the Belgian market. Bio-analytical and chemo-analytical dioxin toxicity equivalents (TEQ) values of the same milk samples were compared. Spearman's Rank correlation coefficients of 0.72, 0.67, 0.73 were obtained respectively between CALUX-TEQ and PCDD/F-TEQ, DL-PCB-TEQ and PCDD/F+DL-PCB-TEQ. The bioassay limit of detection was 0.1 pg TEQ from 1 g animal lipid, the limit of quantification was 0.4 pg TEQ. The repeatability of the CALUX bioassay (variability of butter fat samples analysed in the same run) showed a coefficient of variation (CV) of 10%, intra laboratory reproducibility based on independent runs of the same butter fat samples showed more variation (CV of 26% for samples above 2 pg TEQ/g lipid). All milk samples with a chemical TEQ value above the current limit value in Belgium showed an elevated CALUX-TEQ concentration, above 6 pg TEQ/g lipid. No false negative results were obtained. Based on the good correlation between CALUX-TEQ and chemically measured TEQ levels, the CALUX bioassay can be recommended as a screening tool for routine measurement of potentially toxic PHAHs in milk samples. Chemical analyses could then largely be restricted to positive samples, in order to identify the nature and to quantify the concentration of the chemicals that give the positive signal. Meat samples showed lower CALUX-TEQ values per gram lipid compared to fish samples. The fish samples showed a wider range of CALUX-TEQ values than the meat samples. 相似文献
262.
Diffusion coefficients (T=23±2 °C) and accessible porosities for HTO, 36Cl− and 125I− were measured on Opalinus Clay (OPA) samples from the Mont Terri Underground Rock Laboratory (URL) using the through-diffusion technique. The direction of transport (diffusion) was perpendicular to bedding. Special cells that allowed the application of confining pressure were designed and constructed. The pressures ranged from 1 to 5 MPa, the latter value simulating the overburden at the Mont Terri URL (about 200 m). The test solution used in the experiments was a synthetic version of the Opalinus Clay pore water, which has Na+ and Cl− as the main components (I=0.42 M).The measured values of the effective diffusion coefficients (De) and rock capacity factors (α) are: De=1.2–1.5×10−11 m2 s−1 and α=0.09–0.11 for HTO, De=4.0–5.5×10−12 m2 s−1 and α=0.05 for 36Cl− and De=3.2–4.6×10−12 m2 s−1 and α=0.07–0.10 for 125I−. For non-sorbing tracers (HTO, 36Cl) the rock capacity factor α is equal to the diffusion-accessible porosity . The experimental results showed that pressure only had a small effect on the value of the diffusion coefficients. Increasing the pressure from 1 to 5 MPa resulted in a decrease of the diffusion coefficient of 17% for HTO, 28% for 36Cl− and 30% for 125I−. Moreover, the diffusion coefficients for 36Cl− and 125I− are smaller than for HTO, which is consistent with an effect arising from anion exclusion.The diffusion coefficients of HTO and 125I− measured in this study are in good agreement with recent measurements at three other laboratories performed within the framework of a laboratory comparison exercise. The values of the diffusion-accessible porosities show a larger degree of scatter. 相似文献
263.
G.P.J. Draaijers E.P. Van Leeuwen P.G.H. De Jong J.W. Erisman 《Atmospheric environment (Oxford, England : 1994)》1997,31(24):4139-4157
Deposition of base cations (Na+, Mg2+, Ca2+, K+) in Europe was mapped for 1989 with a spatial resolution of 10 x 20 km using the so-called inferential modeling technique. Deposition fields resembled the geographic variability of sources, land-use and climate. Dry deposition constituted on average 45% of the total base cation deposition in Europe. Modeled deposition estimates compared reasonably well with deposition estimates derived from throughfall and bulk-precipitation measurements made at 174 sites scattered over Europe. Using error propagation, the random and systematic error in total deposition for an average grid cell of 10 x 20 km was estimated to equal 35–50% and 25–40%, respectively. Within individual grids a relatively large variability in deposition is expected. 相似文献
264.
Discrimination of factors influencing biota of a stream receiving multiple-source perturbations 总被引:1,自引:0,他引:1
Van Hassel JH Cherry DS Hendricks JC Specht WL 《Environmental pollution (Barking, Essex : 1987)》1988,55(4):271-287
Blaine Creek is a fifth-order stream located in eastern Kentucky that has been subject to contamination by oil brines, surface mining, and a coal fly ash settling pond discharge. Toxicity tests, effluent and receiving water chemical monitoring, and Blaine Creek benthic sampling were used to evaluate the effect of the ash pond effluent on the creek. Reproductive impairment of Ceriodaphnia was demonstrated at effluent concentrations ranging from 30 to 100%, but no instream impact on benthic invertebrates could be found at effluent flows that provided up to 65% of the creek's discharge. Correlation and regression analysis of physicochemical versus benthic monitoring data indicated that upstream oil brine contamination and scouring of the creek's predominately shifting sand substrate during rainfall events were the primary factors affecting the benthic fauna, and appeared to override potential effects from other sources. These results demonstrated the value of integrated field/laboratory investigations for effluent impact assessments. 相似文献
265.
Van Stempvoort DR Lesage S Novakowski KS Millar K Brown S Lawrence JR 《Journal of contaminant hydrology》2002,54(3-4):249-276
The enhanced solubility of petroleum-derived compounds in humic acid solutions is the basis for a new groundwater remediation technology. In this unique pilot-scale test, a stationary contaminant source consisting of diesel fuel was placed below the water table in a model sand aquifer (1.2 x 5.5 x 1.8-m deep) and flushed with water at a flow rate of 2 cm/h over 5 years. At 51 days, laboratory grade humic acid was added to the water and maintained at a level of approximately 0.8 g/l. The addition of humic acid had only a small impact on the aqueous transport of the BTEX components, which were rapidly dissolved from the diesel, but had a large effect on the flushing of PAHs, including methylated naphthalenes (MNs). Binding to aqueous humic acid enhanced the solubilization of MNs two- to tenfold. During aqueous transport, biodegradation of the BTEX and PAHs occurred, limiting the lateral and longitudinal extent of the diesel contaminant plume in the model aquifer. It appears that through enhanced solubilization, the overall biodegradation rate of the MNs was increased. As the various MNs were depleted from the diesel source, the MN plume shrank and then disappeared. 相似文献
266.
Environmental impact of two successive chemical treatments in a small shallow eutrophied lake: Part I. Case of aluminium sulphate 总被引:1,自引:0,他引:1
Van Hullebusch E Deluchat V Chazal PM Baudu M 《Environmental pollution (Barking, Essex : 1987)》2002,120(3):617-626
This paper deals with the efficiency and effects of addition of aluminium sulphate on soft water quality of a shallow eutrophic lake. Almost all the controlled variables improved with treatment, especially nutrient concentrations such as soluble reactive phosphorus (SRP) and transparency. However, aluminium sulphate was not added in sufficient quantity to reduce the total phosphorus content. SRP concentration was significantly reduced in the short term. Moreover, external loading of phosphorus was high and not taken into account by the in-lake treatments. Finally, resuspension of sediment (polymictic lake) removed the alum hydroxide layer on the sediment surface, which reduced treatment effectiveness. No significant pH decrease was noted following alum addition. According to bibliographical toxicological data, monomeric aluminium content does not show any toxic effect on aquatic fauna and flora. In spite of low SRP in the water column, the treatment did not prevent appearance of Microcystis sp. colony (> 10 colony per ml) approximately 30 days after alum application. 相似文献
267.
ABSTRACT The signing of Colombia’s peace agreement in 2016 signaled the end of a decades-long war between the government and the FARC (Las Fuerzas Armadas Revolucionarias de Colombia), but also an emerging assault against the country’s forests. This article aims to understand the interactions between forests and peace. In doing so, it traces landscape transformations of deforestation and possibilities for making landscapes livable in the midst of disturbance. Drawing on field research, including interviews and participant observation carried out in Colombia from 2016 to 2018, it reveals how deforestation is driven by ongoing colonization and land grabbing, mostly dedicated to extensive cattle ranching, coca cultivation, and campesinos’ transition to ‘licit’ agricultural alternatives. The article also shows how emerging coordination among farmers and forests following forest disturbance contributes to an interpretation of peace in which forests are integral. The article concludes with a call to incorporate forests in the construction of peace. 相似文献
268.
Although contemporary animal contest theory emphasises the importance of physical asymmetries in resolving disputes, such
asymmetries do not obviously settle fights in all groups. Territorial male butterflies, for example, compete via elaborate
non-contact aerial interactions in which success is determined by relative persistence. Prior research suggests that the resolution
of these contests is not clearly related to physical variables such as body size or energy reserves. However, given that the
contests involve elaborate aerial manoeuvres, one long-standing suggestion is that asymmetries in flight performance, and
thus flight morphology, may be important. We addressed this hypothesis via a manipulative investigation into the biophysical
correlates of contest success in the speckled wood butterfly, Pararge aegeria. This species possesses the ability for significant adaptive phenotypic plasticity in relevant flight morphological parameters.
We took advantage of this plasticity to rear 90 individuals of markedly varying flight morphologies, which we then pitted
against each other in a semi-controlled experimental fashion. Multiple logistic and lognormal analyses provided little evidence
for the relevance of morphological parameters, including relative flight musculature, wing loading and wing aspect ratio (wing
length relative to area), to the outcome and/or duration of experimental contests. Instead, we found a positive effect of
age upon contest success. Given that ability for high acceleration is strongly linked to variation in these morphological
parameters, our findings suggest that flight performance is not a strong determinant of resource-holding potential in this
notably territorial butterfly. 相似文献
269.
Pat M. Fidopiastis Daniel J. Bezdek Michael H. Horn Judith S. Kandel 《Marine Biology》2006,148(3):631-642
The zebraperch, Hermosilla azurea Jenkins and Evermann, a warm-temperate marine fish species with a strictly macroalgal diet, has a relatively long digestive
tract with an enlarged hindgut and an associated blind caecum (HC). In zebraperch sampled off Santa Catalina Island, California
(33°19′42′′N; 118°18′37′′W) in years 1995 through 2001, direct cell counts, gut epithelium assessment of bacterial attachment,
and short-chain fatty acid (SCFA) analyses verified that the zebraperch HC possesses a dense and morphologically diverse,
fermentative microbiota. Bacterial cell counts and morphological diversity were significantly higher in HC contents compared
to anterior gut regions, suggesting that microbial populations were growing along the digestive tract. Similarly, electron
micrographs of the HC epithelium revealed attached microbes, further supporting the possibility that these organisms constitute
resident microbiota. Five different SCFAs were detected in all three regions of the digestive tract, but levels were up to
three times greater in HC contents. Acetate was consistently the prevailing SCFA in all gut regions. Sequence analysis of
bacterial 16S rDNA was used to identify predominant bacterial groups in HC contents. Of the seven main bacterial types identified,
Enterovibrio spp. were the dominant bacteria in HC contents followed by species of Bacteroides,Faecalibacterium, and Desulfovibrio. Taken together, our findings show that the zebraperch HC harbors a consortium of microbes that appears to assist in the
breakdown of algal polysaccharides in the herbivorous diet of the fish. 相似文献
270.
The oxygen-binding properties of haemolymph from laboratory-reared Artemia franciscana were investigated in vitro. Adult female brine shrimp without eggs were acclimated to seven different combinations of salinity and oxygen. The oxygen affinity (P50) of unprocessed haemolymph rises with acclimation oxygen partial pressure (PO2) up to normoxic values, after which no influence of oxygen occurs. The increase in P50 with acclimation PO2 can be explained by the change in proportion of each of three different haemoglobins in the haemolymph. Salinity acclimation has no effect on haemolymph P50. The effects of the different major salts [NaNO3, NaCl, Ca(NO3)2, Mg(NO3)2], pH, and the metal-binding ligand EGTA on the oxygen-binding properties of buffered haemolymph (of shrimp acclimated to 10 salinity) were also studied. Little or no effect of these salts could be found. A small Bohr effect (pH 6.5 to 9.1, =-0.11) was noted. Addition of EGTA caused a significant decrease of the oxygen affinity at concentrations up to 50 mmoll-1. 相似文献