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101.
Tao Tang Kun QianTianyu Shi Fang WangPingliang Li Jianqiang LiYongsong Cao 《Chemosphere》2012,89(11):1419-1425
Quinestrol is synthetic estrogen used in contraceptive and hormone replacement therapy and occasionally for treating breast cancer and prostate cancer. It can make its way into the environment through sewage discharge and waste disposal produced by human excretions. In this study, the photodegradation kinetics of quinestrol in various conditions was investigated by UV and solar irradiation. The affecting factors were studied including concentration of hydrogen peroxide, different water types, and the initial concentrations of quinestrol. Concurrently, the transformation products and presumed pathways of quinestrol in distilled water by UV irradiation were identified and proposed. The results showed that the degradation of quinestrol in both irradiation conditions followed the pseudo-first-order kinetics. More rapid degradation was observed by UV irradiation (k = 0.018 min−1) than solar irradiation (k = 0.004 h−1), and the photodegradation rate of quinestrol depended on the concentration of hydrogen peroxide, the initial concentration of quinestrol and water types. The transformation products of quinestrol in distilled water were identified by gas chromatography/mass spectrometry. When exposed to UV irradiation, quinestrol in aqueous solution was rapidly degraded, giving at least ten photodegradation products. The chemical structures of ten degradation products were identified on the basis of mass spectrum interpretation and literature data. 相似文献
102.
维生素和酮苷生产废水中难降解污染物的溯源研究 总被引:2,自引:1,他引:1
研究了维生素和酮苷生产过程中各生产工段排水的生物降解特性,评价了各生产工段对生产废水中难降解有机物的贡献率,追溯了可能的难降解特征污染物。结果表明,维生素生产废水中的难降解物质主要来自W1-1、W1-3、W1-5和W1-6生产工段,甲醛、丁烯酮、醛酮聚合物和吡啶可能是导致生产废水难降解的重要原因;酮苷生产废水中的难降解物质主要来自W2-1、W2-3和W2-7生产工段,氯代有机溶剂和苯环类物质可能是导致生产废水难降解的重要原因。建议根据具体生产工段排水的水质特征,有针对性地进行物化处理,提高废水可生化性。 相似文献
103.
Renbin Zhu Yashu Liu Hua Xu Tao Huang Jianjun Sun Erdeng Ma Liguang Sun 《Atmospheric environment (Oxford, England : 1994)》2010,44(3):304-311
During the summertime of 2007/2008, carbon dioxide (CO2) and methane (CH4) fluxes across air–water interface were investigated in the littoral zones of Lake Mochou and Lake Tuanjie, east Antarctica, using a static chamber technique. The mean fluxes of CO2 and CH4 were ?70.8 mgCO2 m?2 h?1 and 144.6 μgCH4 m?2 h?1, respectively, in the littoral zone of Lake Mochou; The mean fluxes were ?36.9 mgCO2 m?2 h?1 and 109.8 μgCH4 m?2 h?1, respectively, in the littoral zone of Lake Tuanjie. Their fluxes showed large temporal and spatial dynamics. The CO2 fluxes showed a significantly negative correlation with daily total radiation (DTR) and a weakly negative correlation with air temperature and water temperature, indicating that sunlight intensity controlled the magnitude of CO2 fluxes from the open lakes. The CH4 fluxes significantly correlated with local air temperature, water table and total dissolved solids (TDS), indicating that they were the predominant factors influencing CH4 fluxes. Summertime CO2 budgets in the littoral zones of Lake Mochou and Lake Tuanjie were estimated to be ?152.9 gCO2 m?2 and ?79.7 gCO2 m?2, respectively, and net CH4 emissions were estimated to be 312.3 mgCH4 m?2 and 237.2 mgCH4 m?2, respectively. Our results show that shallow, open, alga-rich lakes might be strong summertime CO2 absorbers and small CH4 emitters during the open water in coastal Antarctica. 相似文献
104.
Guofeng Shen Wei Wang Yifeng Yang Chen Zhu Yujia Min Miao Xue Junnan Ding Wei Li Bin Wang Huizhong Shen Rong Wang Xilong Wang Shu Tao 《Atmospheric environment (Oxford, England : 1994)》2010,44(39):5237-5243
Coal consumption is one important contributor to energy production, and is regarded as one of the most important sources of air pollutants that have considerable impacts on human health and climate change. Emissions of polycyclic aromatic hydrocarbons (PAHs) from coal combustion were studied in a typical stove. Emission factors (EFs) of 16 EPA priority PAHs from tested coals ranged from 6.25 ± 1.16 mg kg?1 (anthracite) to 253 ± 170 mg kg?1 (bituminous), with NAP and PHE dominated in gaseous and particulate phases, respectively. Size distributions of particulate phase PAHs from tested coals showed that they were mostly associated with particulate matter (PM) with size either between 0.7 and 2.1 μm or less than 0.4 μm (PM0.4). In the latter category, not only were more PAHs present in PM0.4, but also contained higher fractions of high molecular weight PAHs. Generally, there were more than 89% of total particulate phase PAHs associated with PM2.5. Gas-particle partitioning of freshly emitted PAHs from residential coal combustions were thought to be mainly controlled by absorption rather than adsorption, which is similar to those from other sources. Besides, the influence of fuel properties and combustion conditions was further investigated by using stepwise regression analysis, which indicated that almost 57 ± 10% of total variations in PAH EFs can be accounted for by moisture and volatile matter content of coal in residential combustion. 相似文献
105.
非均相Fenton-流化床体系主要使用石英砂作为催化剂载体,该技术的实际应用由于催化剂活性寿命低、制备困难等原因而受到限制.提出了一种新型的Fenton-流化床催化剂——负载氧化铁陶粒.使用循环浸泡法制备的负载陶粒对苯甲酸模拟废水的处理效果良好.表征结果分析表明,载体表面铁含量大幅度上升,负载的氧化铁紧紧包裹在陶粒表面,且表面有大量缝隙,利于增加反应比表面积,而密度变化不大.该催化剂的催化活性重复性良好,重复使用4次后对苯甲酸模拟废水依然有较好的处理效果.使用该催化剂进行垃圾渗滤液的降解实验能在一定程度上减少亚铁的投加量,具有较好的实际应用前景. 相似文献
106.
107.
如何控制人力成本以使组织降本增效一直是国内学者研究的热点。本文主要对国内近5年人力成本管理的300多篇相关文献从研究领域、研究思路等进行综述和评论,并在此基础之上与国外人力成本管理的文献进行对比分析。研究表明:成本收益法是未来人力成本管理研究的发展趋势。 相似文献
108.
109.
纤铁矿是土壤中重要的活性矿物组分,常与硅、铝元素共存,对土壤污染物的迁移有重要的影响。采用氧化水解法制备了不掺杂和硅、铝掺杂的纤铁矿(分别记为Lep、Si-Lep、Al-Lep),通过X-射线衍射(XRD)、扫描电镜(SEM)、N2吸附/脱附、质子电位滴定等方法对样品进行表征和表面性质分析,并研究了3种样品对F~-的吸附性能。结果表明:与Lep相比,Si-Lep、Al-Lep的结晶度降低且铝掺杂显著抑制了纤铁矿向针铁矿转化。Lep、Si-Lep和Al-Lep的BET比表面积分别为25.37、28.18、32.51m2/g,孔体积、平均孔径和表面分形度均依次增大。Lep、Si-Lep和Al-Lep样品的电荷零点(pHPZC)依次为7.10、6.80、6.50;3种样品的表面羟基密度分别为0.33、0.32、0.36mmol/g。Lep、Si-Lep和Al-Lep对F~-的最大吸附量分别为6.58、7.32、9.88mg/g;与Lep相比,Si-Lep和Al-Lep对F~-的准二级动力学速率常数分别降低至0.013、0.014g/(mg·min);Si-Lep对F~-的吸附亲和力增大,而Al-Lep对F~-的吸附亲和力降低。 相似文献
110.
矿井井筒提升设备绕流的数值模拟 总被引:2,自引:0,他引:2
基于经典的流体力学理论,建立罐笼绕流的二维RNGκ-ε湍流模型,分析其初始边界条件,并结合工程实际应用FLUENT计算流体动力学软件模拟罐笼运行时井筒内流场及压力场,得出井筒内流场及压力场的变化规律。研究结果表明:在罐笼运行期间,由于空间受限而引发活塞效应,井筒内压力发生瞬态变化,造成通风系统的压力波动,导致气流运动的动态改变,对通风系统稳定性有一定的影响。 相似文献