Risk characterization, assessment, and management of organic pollutants in beneficially used residual products

A wide array of organic chemicals occur in biosolids and other residuals recycled to land. The extent of our knowledge about the chemicals and the impact on recycling programs varies from high to very low. Two significant challenges in regulating these materials are to accurately determine the concentrations of the organic compounds in residuals and to appropriately estimate the risk that the chemicals present from land application or public distribution. This paper examines both challenges and offers strategies for assessing the risks related to the occurrence of organic compounds in residuals used as soil amendments. Important attributes that must be understood to appropriately characterize and manage the potential risks for organic chemicals in biosolids include toxicity and dose response, transport potential, chemical structure and environmental stability, analytical capability in the matrix of interest, concentrations and persistence in waste streams, plant uptake, availability from surface application versus incorporation, solubility factors, and environmental fate. This information is complete for only a few chemicals. Questions persist about the far greater number of chemicals for which toxicity and environmental behavior are less well understood. This paper provides a synopsis of analytical issues, risk assessment methodologies, and risk management screening alternatives for organic constituents in biosolids. Examples from experience in Wisconsin are emphasized but can be extrapolated for broader application.     

How Science Contributes to Environmental Reporting in British Newspapers: A Case Study of the Reporting of Global Warming and Climate Change

This article examines the role of science in environmental reporting in a number of British newspapers. The findings indicated that in reporting about global warming and climate change, the views of scientists were used to give legitimacy to the content of articles. However, in both the tabloids and broadsheets, there was little evidence provided, in the form of data, to substantiate the claims being made. Furthermore, uncertainties about global warming were not explored effectively. Newspaper reports tended to focus on the potential consequences of global warming, but made little attempt to address the suspected causes that would inevitably involve criticism of highly consumptive lifestyles in the west.     

Maintenance of intact sediment box cores as laboratory mesocosms.

Mesocosms consisting of physically and biologically intact segments of natural communities are an ideal compromise between single species tests and ecosystem experiments in the assessment of sediment contamination. Therefore, large intact sediment cores, as mesocosms with naturally co-adapted communities, would allow sediment contamination to be assessed using the replicability and statistical power of laboratory techniques, while retaining much of the ecological realism of field studies. This study investigates the collection and maintenance of such cores, collected from an unimpacted site in Lake Erie. It demonstrates that box cores containing relatively undisturbed freshwater sediments can be brought back to the laboratory and maintained for up to 8 weeks with little change in the resident benthic fauna. Feeding the systems is not required, nor is it deleterious to the indigenous fauna.     

Inactivation of enzyme laccase and role of cosubstrate oxygen in enzymatic removal of phenol from water.

Research was conducted to evaluate the potential use of laccase and its susceptibility to inactivation in an alternative enzyme-based treatment technology to remove parent phenol from buffered distilled water. Enzymatic oxidative polymerization of phenol with laccase was carried out in continuously stirred batch reactors. The reaction products were insoluble polymers, which precipitated out of the solution once their solubility limits were exceeded. The findings demonstrated that the polymeric products had significant effects on enzyme activity consumption and subsequent phenol removal. Enzyme species present in the reaction vessel were classified into enzyme remaining in the solution (type 1) and enzyme adhering to the precipitate polymers (type 2). Type 1 enzyme was more efficient in removal of phenol from solution compared with type 2. Subsequent filtration enhanced the phenol removal by removing type 2 enzyme adhering to the polymer particles and decelerating enzyme inactivation. The study also investigated the effects of available dissolved oxygen, provided through aeration and hydrogen peroxide addition, on phenol removal. Aeration and hydrogen peroxide addition increased the dissolved oxygen concentration, but had no effect on the progress curve for phenol removal.     

Adjusting to new work teams: Testing work experience as a multidimensional resource for newcomers

The successful performance adjustment of team newcomers is an increasingly important consideration given the prevalence of job‐changing and the uncertainty associated with starting work in a new team setting. Consequently, using sensemaking and uncertainty reduction theories as a conceptual basis, the present study tested work experience as a potential resource for newcomer performance adjustment in teams. Specifically, we tested work experience as a multidimensional predictor of both initial newcomer performance and the rate of performance change after team entry. We tested hypotheses using longitudinal newcomer performance data in the context of professional basketball teams. Although the traditional quantitative indicators of the length and amount of work experience were not meaningfully associated with newcomer performance adjustment, their interaction was. In addition, the qualitative indicator of newcomers' past transition experience revealed a significant, positive association with the rate of newcomer performance improvement following team entry. These results suggest that work experience is a meaningful facilitator of newcomer adjustment in teams and emphasize the dual consideration of both quantitative and qualitative work experiences. The theoretical and practical implications of these findings are discussed. Copyright © 2013 John Wiley & Sons, Ltd.     

The deployment of an advanced gasification technology in the treatment of household and other waste streams

The Gasplasma^® process developed by APP is an advanced thermal conversion (ATC) technology which has been developed for the treatment of household and trade wastes and has also been successfully applied to the handling of wastes derived from landfill and would be capable of achieving effective energy conversion when utilised as an integrated part of the Enhanced Landfill Mining (ELFM) concept.The core Gasplasma^® technology comprises a two-stage thermal treatment system—firstly, a fluidizing bed gasifier which converts the wastes to a crude syngas using oxy-steam and, secondly, a plasma converter that efficiently cracks problematic tars in the raw syngas to produce a reformed and clean syngas suitable for generating electrical power in gas engines and also recovering an environmentally stable vitrified product for use as a secondary aggregate material. The utilization of oxy-steam as a gasifying agent greatly reduces the syngas volume compared to other ATC processes and incineration and hence reduces the cost of the gas cleaning system while improving the efficiency of the process. By adopting this two-stage approach, high energy conversion (74–90%) and carbon conversion (95 ± 1.6%) efficiencies were achieved with the Gasplasma^® plant that compare favourably with published efficiencies data. The calculated net exportable power generation efficiency for a commercial scale plant is significantly in excess of 25%. This compares well with the published figures of 17.7–23% for fluidized bed technologies processing MSW.     

Community social capital and individual functioning in the post‐disaster context

Disasters can have severe and long‐lasting consequences for individuals and communities. While scholarly evidence indicates that access to social support can ameliorate their negative impacts, less understood is whether or not neighbourhood social capital can facilitate recovery. This study uses two waves of survey data—collected before and after a significant flood in Brisbane, Australia, in 2011—to examine the relationship between the severity of the event at the individual and neighbourhood level, access to neighbourhood social capital and individual‐level social support, and functioning in the post‐disaster environment. In line with previous research, the results indicate that the severity of the flood is the most salient predictor of post‐disaster functioning. No evidence was unearthed to show that neighbourhood social capital amassed before the flood leads to better functioning subsequently, but the findings do suggest that individual‐level social support can moderate the effect of flood severity on functioning.