Role of complex organic arsenicals in food in aggregate exposure to arsenic

For much of the world''s population, food is the major source of exposure to arsenic. Exposure to this non-essential metalloid at relatively low levels may be linked to a wide range of adverse health effects. Thus, evaluating foods as sources of exposure to arsenic is important in assessing risk and developing strategies that protect public health. Although most emphasis has been placed on inorganic arsenic as human carcinogen and toxicant, an array of arsenic-containing species are found in plants and animals used as foods. Here, we 2evaluate the contribution of complex organic arsenicals (arsenosugars, arsenolipids, and trimethylarsonium compounds) that are found in foods and consider their origins, metabolism, and potential toxicity. Commonalities in the metabolism of arsenosugars and arsenolipids lead to the production of di-methylated arsenicals which are known to exert many toxic effects. Evaluating foods as sources of exposure to these complex organic arsenicals and understanding the formation of reactive metabolites may be critical in assessing their contribution to aggregate exposure to arsenic.     

Greenhouse gas scenarios for Austria: a comparison of different approaches to emission trends

In the present paper, national and externally organized projections of greenhouse gas emissions for Austria were compared to gain insight on the underlying scenario data assumptions. National greenhouse gas emission trends extend until 2030, an assessment of European Union (EU) countries to 2050. In addition, data for 2000–2100 was extracted from the global emission database described by the Representative Concentration Pathways (RCP). By identifying trends in these projections, it was possible to produce (a) a long-term assessment of national scenarios until 2100, (b) an assessment of the ambition level toward national climate strategies, and (c) a standardized method to compare trends across countries. By extracting RCP data, Austrian’s methane, nitrous oxide, and carbon dioxide emissions up to 2100 could be projected for all sources as well as specific sectors. With respect to the RCP scenario emission data, national projections did not seem to employ the mitigation potentials available for the most stringent RCP scenario, RCP2.6. Comparing projections that supported the EU Climate Strategy 2030 with national projections revealed similar trends. Because RCP2.6 is the only scenario consistent with a 2 °C global warming target, and it is much more ambitious than any of the national or European projections, further measures will be required if Austria is to adequately contribute to this widely accepted policy goal.     

Climate change impact and potential adaptation strategies under alternate climate scenarios for yam production in the sub-humid savannah zone of West Africa

Globally, yam (Dioscorea spp.) is the fifth most important root crop after sweet potatoes (Ipomoea batatas L.) and the second most important crop in Africa in terms of production after cassava (Manihot esculenta L.) and has long been vital to food security in sub-Saharan Africa (SSA). Climate change is expected to have its most severe impact on crops in food insecure regions, yet very little is known about impact of climate change on yam productivity. Therefore, we try estimating the effect of climate change on the yam (variety: Florido) yield and evaluating different adaptation strategies to mitigate its effect. Three regional climate models REgional MOdel (REMO), Swedish Meteorological and Hydrological Institute Regional Climate Model (SMHIRCA), and Hadley Regional Model (HADRM3P) were coupled to a crop growth simulation model namely Environmental Policy Integrated Climate (EPIC) version 3060 to simulate current and future yam yields in the Upper Ouémé basin (Benin Republic). For the future, substantial yield decreases were estimated varying according to the climate scenario. We explored the advantages of specific adaptation strategies suggesting that changing sowing date may be ineffective in counteracting adverse climatic effects. Late maturing cultivars could be effective in offsetting the adverse impacts. Whereas, by coupling irrigation and fertilizer application with late maturing cultivars, highest increase in the yam productivity could be realized which accounted up to 49 % depending upon the projection of the scenarios analyzed.     

Got milk? Workplace factors related to breastfeeding among working mothers

The American Academy of Pediatrics recommends that women breastfeed because of improved health outcomes for mothers and children. Because maternal employment during the first year of the child's life has been identified as a reason for breastfeeding cessation, we develop and test a role‐theory‐based framework to explain women's continuation of breastfeeding after return to work (Study 1) and report results of an exploratory study linking breastfeeding at work with job attitudes and well‐being (Study 2). Applying survival analysis to a longitudinal dataset gathered by the Centers for Disease Control (Study 1), we identify pregnant women's perceived employer support for breastfeeding as a predictor of women's breastfeeding goal intentions. Supervisors' negative workplace remarks about breastfeeding related to an eightfold increase of women's likelihood to discontinue exclusive breastfeeding and perceived support for breastfeeding after return to work predicted exclusive breastfeeding continuation. Results of Study 2 suggest that women who return to work and continue breastfeeding experience more family‐to‐work conflict and overload than women who do not reconcile work and breastfeeding. Further, results of Study 2 provide preliminary evidence suggesting that perceptions of supervisor and coworker support for breastfeeding relate positively to general perceptions of organizational support and negatively to depressive symptoms. Copyright © 2015 John Wiley & Sons, Ltd.     

Laboratory validation study of new vapor‐phase‐based approach for groundwater monitoring

Recent improvements in field‐portable analytical equipment allow accurate on‐site measurement of VOCs present in air at concentrations of less than 0.1 parts per million volume (ppmv). The objective of this project is to determine if the use of these instruments for vapor‐phase measurements of headspace in a monitoring well can serve as a reliable and accurate method for monitoring volatile organic compound (VOC) concentrations in groundwater under equilibrium conditions. As part of a comprehensive research project investigating the utility of this proposed monitoring method, the authors have completed a laboratory validation study to identify instruments and sample‐collection methods that will provide accurate measurement of VOC concentrations in groundwater. This laboratory validation study identified two field‐portable instruments (a gas chromatograph and a photoionization detector) with sufficient sensitivity to measure VOCs in groundwater at concentrations below typical monitoring standards (i.e., 1 to 5 μg/L). The accuracy and precision of these field instruments was sufficient to satisfy typical data‐quality objectives for laboratory‐based analysis. In addition, two sample‐collection methods were identified that yield vapor‐phase samples in equilibrium with water: direct headspace sampling and passive diffusion samplers. These sample‐collection methods allow the field instruments (which measure VOC concentrations in vapor‐phase samples) to be used to measure VOC concentrations in water. After further validation of these sample‐collection methods in the field, this monitoring method will provide a simple way to obtain accurate real‐time measurements of VOC concentrations in groundwater using inexpensive field‐portable analytical instruments. © 2009 Wiley Periodicals, Inc.     

Impacts of residential development on vegetation cover for a remote coastal barrier in the Outer Banks of North Carolina, USA

Coastal barrier environments are heavily influenced by human activities yet there are few examples of landscape ecological work investigating human dimensions of settlement disturbance patterns and processes. We investigated the impacts of residential development on vegetation cover for a remote roadless coastal barrier in Carova, North Carolina that is subject to policies from the federal to local levels and addressed three research questions: How has the region’s the policy history influenced patterns of residential parcel development? What are the spatial and temporal patterns of parcel development? How has development impacted patterns of barrier vegetation cover? We traced the influences of the federal 1982 Coastal Barrier Resources Act (CBRA) designed to discourage development in risky coastal areas as well as state/local coastal policies and employed remote sensing change detection, NDVI analysis and spatial analysis and regression techniques. Results showed an acceleration of new housing structures since 1990, contrary to the intended effects of CBRA. An estimated vegetation cover loss of 437 m² was associated with each newly developed parcel. NDVI varied along spatial and temporal gradients with more recent development having lower NDVI than older development. Recently developed parcels were larger in area, closer to the beach, and contained houses with larger footprints compared to older developed parcels. Our approach represents a place-based analytical framework for coastal barrier landscapes. Beyond the Carova case study, adopting such an approach coupling natural and human systems for the entire eastern US barrier system requires defining a comprehensive set of coastal barrier spatial units to enable typological classification and subsequent systematic investigation to inform debates regarding coastal ecosystem services and sustainability.     

Effects of zooplankton diel vertical migration on a phytoplankton community: A scenario analysis of the underlying mechanisms

A mechanistic model was applied to study the influence of diurnal vertical migration (DVM) of planktonic crustaceans on the succession and composition of the phytoplankton community. While zooplankton was restricted to only one functional group, the phytoplankton community was divided into two functional groups which are distinguished by their maximum growth rates and vulnerability to zooplankton grazing. DVM causes a pulsed grazing regime and may also entail a corresponding reduction of the cumulative daily rates of ingestion and losses of zooplankton. To study the relative importance of these two mechanisms of DVM to phytoplankton we performed a scenario analysis consisting of 5 different scenarios. The results show that DVM has a strong influence on the phytoplankton community. Well edible algae benefit during the first 3–4 weeks of summer stratification by reduced daily grazing. The typical shift from small, well edible algae to larger, poorly or non-edible phytoplankton is distinctly delayed. Under the assumption of unchanged daily grazing, however, a pulsed grazing regime has nearly no influence on the resulting phytoplankton composition. As similar effects are also found for completely non-edible phytoplankton, indirect effects via phosphorus availability must be assumed. Thus, the scenario analysis reveals that the observed effects of DVM on phytoplankton can be explained by a combination of two mechanisms: (1) reduction of the daily zooplankton grazing, and (2) changed assimilation and remineralisation of phosphorus. Surprisingly and in contradiction to earlier reports there is almost no DVM effect on phytoplankton due to the sole action of a pulsed grazing regime.     

Global effects of extreme temperatures on wild bumblebees

Climate plays a key role in shaping population trends and determining the geographic distribution of species because of limits in species’ thermal tolerance. An evaluation of species tolerance to temperature change can therefore help predict their potential spatial shifts and population trends triggered by ongoing global warming. We assessed inter- and intraspecific variations in heat resistance in relation to body mass, local mean temperatures, and evolutionary relationships in 39 bumblebee species, a major group of pollinators in temperate and cold ecosystems, across 3 continents, 6 biomes, and 20 regions (2386 male specimens). Based on experimental bioassays, we measured the time before heat stupor of bumblebee males at a heatwave temperature of 40 °C. Interspecific variability was significant, in contrast to interpopulational variability, which was consistent with heat resistance being a species-specific trait. Moreover, cold-adapted species are much more sensitive to heat stress than temperate and Mediterranean species. Relative to their sensitivity to extreme temperatures, our results help explain recent population declines and range shifts in bumblebees following climate change.     

Ecological and economic impacts of green roofs and permeable pavements at the city level: the case of Corvallis,Oregon

A city's spatial footprint is covered by extensive impervious building roofs and paved surfaces, which contribute to greater storm-water runoff, more surface pollutants, and less carbon sequestration, hence, worse ecosystem services. This research conducts an empirical study on the ecological and economic impacts of a citywide adoption of green roofs and permeable pavements in Corvallis, OR. The effects on ecosystem services of using green roofs and pervious pavements for a low impact development are modelled using Integrated Value of Ecosystem Services Trade-offs and compared to those from the City's current conventional development without green roofs and pervious pavements. The differences are analysed for ecological impact by storm-water yield, storm-water purification, and carbon sequestration and economic impact by a cost-benefit comparison. The results indicate that low impact development, especially intensive green roofs on commercial/industrial buildings and permeable pavements for parking lots, plays a significant role, even with a higher initial implementation cost, for long-term urban sustainability.