C60 fullerene: a powerful antioxidant or a damaging agent? The importance of an in-depth material characterization prior to toxicity assays

Since the discovery of fullerenes in 1985, these carbon nanospheres have attracted attention regarding their physico/chemical properties. Despite little knowledge about their impact on the environment and human health, the production of fullerenes has already reached an industrial scale. However, the toxicity of C₆₀ is still controversially discussed.The aim of this study was to clarify the biological effects of tetrahydrofuran (THF) suspended C₆₀ fullerene in comparison to water stirred C₆₀ fullerene suspensions. Beyond that, we analyzed the effects on the Crustacea Daphnia magna an indicator for ecotoxicological effects and the human lung epithelial cell line A549 as a simplified model for the respiratory tract.We could demonstrate that water-soluble side products which were formed in THF nC₆₀ suspension were responsible for the observed acute toxic effects, whereas fullerenes themselves had no negative effect regardless of the preparative route on either A549 cell in vitro or D. magna in vivo.     

A Multilevel Model of the Impact of Farm‐Level Best Management Practices on Phosphorus Runoff1

Abstract: Multilevel or hierarchical models have been applied for a number of years in the social sciences but only relatively recently in the environmental sciences. These models can be developed in either a frequentist or Bayesian context and have similarities to other methods such as empirical Bayes analysis and random coefficients regression. In essence, multilevel models take advantage of the hierarchical structure that exists in many multivariate datasets; for example, water quality measurements may be taken from individual lakes, lakes are located in various climatic zones, lakes may be natural or man‐made, and so on. The groups, or levels, may effectively yield different responses or behaviors (e.g., nutrient load response in lakes) that often make retaining group membership more effective when developing a predictive model than when working with either all of the data together or working separately with the individuals. Here, we develop a multilevel model of the impact of farm level best management practices (BMPs) on phosphorus runoff. The result of this research is a model with parameters which vary with key practice categories and thus may be used to evaluate the effectiveness of these practices on phosphorus runoff. For example, it was found that the effect of fertilizer application rate on farm‐scale phosphorus loss is a function of the application method, the hydrologic soil group, and the land use (crop type). Further, results indicate that the most effective method for controlling fertilizer loss is through soil injection. In summary, the resultant multilevel model can be used to estimate phosphorus loss from farms and hence serve as a useful tool for BMP selection.     

MODIS Biophysical States and NEXRAD Precipitation in a Statistical Evaluation of Antecedent Moisture Condition and Streamflow1

Abstract: The potential of remotely sensed time series of biophysical states of landscape to characterize soil moisture condition antecedent to radar estimates of precipitation is assessed in a statistical prediction model of streamflow in a 1,420 km² watershed in south‐central Texas, Moderate Resolution Imaging Spectroradiometer (MODIS) time series biophysical products offer significant opportunities to characterize and quantify hydrologic state variables such as land surface temperature (LST) and vegetation state and status. Together with Next Generation Weather Radar (NEXRAD) precipitation estimates for the period 2002 through 2005, 16 raw and deseasoned time series of LST (day and night), vegetation indices, infrared reflectances, and water stress indices were linearly regressed against observed watershed streamflow on an eight‐day aggregated time period. Time offsets of 0 (synchronous with streamflow event), 8, and 16 days (leading streamflow event) were assessed for each of the 16 parameters to evaluate antecedent effects. The model results indicated a reasonable correlation (r² = 0.67) when precipitation, daytime LST advanced 16 days, and a deseasoned moisture stress index were regressed against log‐transformed streamflow. The estimation model was applied to a validation period from January 2006 through March 2007, a period of 12 months of regional drought and base‐flow conditions followed by three months of above normal rainfall and a flood event. The model resulted in a Nash‐Sutcliffe estimation efficiency (E) of 0.45 for flow series (in log‐space) for the full 15‐month period, ?0.03 for the 2006 drought condition period, and 0.87 for the 2007 wet condition period. The overall model had a relative volume error of ?32%. The contribution of parameter uncertainties to model discrepancy was evaluated.     

Investigations on CO2 storage capacity in saline aquifers—Part 2: Estimation of storage capacity coefficients

Many studies on geological carbon dioxide (CO₂) storage capacity neglect the influence of complex coupled processes which occur during and after the injection of CO₂. Storage capacity is often overestimated since parts of the reservoirs cannot be reached by the CO₂ plume due to gravity segregation and are thus not accessible for storage. This work investigates the effect of reservoir parameters like depth, temperature, absolute and relative permeability, and capillary pressure on the processes during CO₂ injection and thus on estimates of effective storage capacity. The applied statistical characteristics of parameters are based on a large reservoir parameter database. Different measured relative permeability relations are considered. The methodology of estimating storage capacity is discussed. Using numerical 1D and 3D experiments, detailed time-dependent storage capacity estimates are derived. With respect to the concept developed in this work, it is possible to estimate effective CO₂ storage capacity in saline aquifers. It is shown that effective CO₂ mass stored in the reservoir varies by a factor of 20 for the reservoir setups considered. A high influence of the relative permeability relation on storage capacity is shown.     

Model-based prediction of long-term leaching of contaminants from secondary materials in road constructions and noise protection dams

In this study, contaminant leaching from three different secondary materials (demolition waste, municipal solid waste incineration ash, and blast furnace slag) to groundwater is assessed by numerical modeling. Reactive transport simulations for a noise protection dam and a road dam (a typical German autobahn), in which secondary materials are reused as base layers, were performed to predict the breakthrough of a conservative tracer (i.e., a salt) and sorbing contaminants (e.g., PAHs like naphthalene and phenanthrene or heavy metals) at the groundwater table. The dam constructions have a composite architecture with soil covers in inclined layers and distinct contrasts in the unsaturated hydraulic properties of the used materials. Capillary barrier effects result in strong spatial variabilities of flow and transport velocities. Contaminant breakthrough curves at the groundwater table show significant tailing due to slow sorption kinetics and a wide distribution of travel times. While conservative tracer breakthrough depends primarily on subsoil hydraulic properties, equilibrium distribution coefficients and sorption kinetics represent additional controlling factors for contaminant spreading. Hence, the three secondary materials show pronounced differences in the temporal development of leached contaminant concentrations with consequences for breakthrough times and peak concentrations at the groundwater table. Significant concentration reductions due to dispersion occur only if the source concentrations decrease significantly prior to the arrival of the contaminant at the groundwater table. Biodegradation causes significant reduction of breakthrough concentrations only if flow velocities are low.     

Feasibility of incorporating waste grass clippings (Lolium perenne L.) in particleboard composites

This study investigated some of the important physical (thickness swelling) and mechanical (modulus of rupture, modulus of elasticity and internal bond) properties of single-layer particleboard panels made from eucalyptus (Eucalyptus camaldulensis Dehn.), waste of grass clippings (Lolium perenne L.) and combinations of the two. The chemical properties (pH, holocelluse and alpha cellulose contents, and water, alcohol-benzene and 1% sodium hydroxide solubilities) of the raw materials were also determined. Panels with a 6:94 ratio of grass-to-eucalyptus particles had the required mechanical properties for interior fitments including furniture and general uses. Boards manufactured with 100% grass clippings exhibited the lowest quality. The overall panel properties improved with a lower percentage of grass clippings added. Based on initial results, it also appears that grass should compose no more than 13% to achieve acceptable panel properties for interior fitments and general uses.     

Bench-scale composting of source-separated human faeces for sanitation

In urine-diverting toilets, urine and faeces are collected separately so that nutrient content can be recycled unmixed. Faeces should be sanitized before use in agriculture fields due to the presence of possible enteric pathogens. Composting of human faeces with food waste was evaluated as a possible method for this treatment. Temperatures were monitored in three 78-L wooden compost reactors fed with faeces-to-food waste substrates (F:FW) in wet weight ratios of 1:0, 3:1 and 1:1, which were observed for approximately 20 days. To achieve temperatures higher than 15 degrees C above ambient, insulation was required for the reactors. Use of 25-mm thick styrofoam insulation around the entire exterior of the compost reactors and turning of the compost twice a week resulted in sanitizing temperatures (>or=50 degrees C) to be maintained for 8 days in the F:FW=1:1 compost and for 4 days in the F:FW=3:1 compost. In these composts, a reduction of >3 log(10) for E. coli and >4 log(10) for Enterococcus spp. was achieved. The F:FW=1:0 compost, which did not maintain >or=50 degrees C for a sufficiently long period, was not sanitized, as the counts of E. coli and Enterococcus spp. increased between days 11 and 15. This research provides useful information on the design and operation of family-size compost units for the treatment of source-separated faeces and starchy food residues, most likely available amongst the less affluent rural/urban society in Uganda.     

The effects of aeration rate on generated compost quality, using aerated static pile method

To determine the most appropriate composting process in an active municipal solid waste system, an experiment was carried out using a nested design method with three aeration rates. During each aeration rate, parameters such as temperature, pH, EC, carbon-to-nitrogen ratio, NO(3)-N, nitrogen, potassium and phosphorous were measured and the efficiency of different composting processes was evaluated. The result of this study showed that the lower and medium aeration rates had a significant impact on nitrogen, carbon-to-nitrogen ratio and temperature profile, while higher aeration rates led to higher EC values. Furthermore, the thermophilic phase lasted 13, 9 and 4 weeks for the aeration rates of 0.4, 0.6 and 0.9 L min(-1)kg(-1), respectively. Accordingly, it was concluded that starting at a rate of 0.6 L min(-1)kg(-1) during first 2 months (about 9 weeks) of the process and continuing at a rate of 0.4 L min(-1)kg(-1)until the end of composting process would result in lower energy consumption.     

Aging and compressibility of municipal solid wastes

The expansion of a municipal solid waste (MSW) landfill requires the ability to predict settlement behavior of the existing landfill. The practice of using a single compressibility value when performing a settlement analysis may lead to inaccurate predictions. This paper gives consideration to changes in the mechanical compressibility of MSW as a function of the fill age of MSW as well as the embedding depth of MSW. Borehole samples representative of various fill ages were obtained from five boreholes drilled to the bottom of the Qizhishan landfill in Suzhou, China. Thirty-one borehole samples were used to perform confined compression tests. Waste composition and volume-mass properties (i.e., unit weight, void ratio, and water content) were measured on all the samples. The test results showed that the compressible components of the MSW (i.e., organics, plastics, paper, wood and textiles) decreased with an increase in the fill age. The in situ void ratio of the MSW was shown to decrease with depth into the landfill. The compression index, Cc, was observed to decrease from 1.0 to 0.3 with depth into the landfill. Settlement analyses were performed on the existing landfill, demonstrating that the variation of MSW compressibility with fill age or depth should be taken into account in the settlement prediction.