全文获取类型
收费全文 | 3019篇 |
免费 | 42篇 |
国内免费 | 25篇 |
专业分类
安全科学 | 163篇 |
废物处理 | 154篇 |
环保管理 | 612篇 |
综合类 | 334篇 |
基础理论 | 729篇 |
环境理论 | 5篇 |
污染及防治 | 752篇 |
评价与监测 | 212篇 |
社会与环境 | 107篇 |
灾害及防治 | 18篇 |
出版年
2023年 | 21篇 |
2022年 | 37篇 |
2021年 | 26篇 |
2020年 | 21篇 |
2019年 | 31篇 |
2018年 | 66篇 |
2017年 | 67篇 |
2016年 | 89篇 |
2015年 | 58篇 |
2014年 | 84篇 |
2013年 | 280篇 |
2012年 | 143篇 |
2011年 | 177篇 |
2010年 | 120篇 |
2009年 | 122篇 |
2008年 | 154篇 |
2007年 | 187篇 |
2006年 | 152篇 |
2005年 | 105篇 |
2004年 | 105篇 |
2003年 | 116篇 |
2002年 | 89篇 |
2001年 | 67篇 |
2000年 | 47篇 |
1999年 | 52篇 |
1998年 | 38篇 |
1997年 | 43篇 |
1996年 | 43篇 |
1995年 | 40篇 |
1994年 | 41篇 |
1993年 | 34篇 |
1992年 | 37篇 |
1991年 | 26篇 |
1990年 | 29篇 |
1989年 | 19篇 |
1988年 | 13篇 |
1987年 | 20篇 |
1986年 | 25篇 |
1985年 | 17篇 |
1984年 | 18篇 |
1983年 | 30篇 |
1982年 | 28篇 |
1981年 | 25篇 |
1980年 | 19篇 |
1979年 | 16篇 |
1977年 | 11篇 |
1976年 | 9篇 |
1975年 | 9篇 |
1974年 | 10篇 |
1971年 | 11篇 |
排序方式: 共有3086条查询结果,搜索用时 328 毫秒
911.
Schultz MK Biegalski SR Inn KG Yu L Burnett WC Thomas JL Smith GE 《Journal of environmental monitoring : JEM》1999,1(2):183-190
We have developed a coulometric technique to optimize the removal of the carbonate and organic fractions for sequential chemical extractions of soils and sediments. The coulometric system facilitates optimizing these two fractions by direct real-time measurement of carbon dioxide (CO2) evolved during the removal of these two fractions. Further analyses by ICP-MS and alpha-spectrometry aided in interpreting the results of coulometry experiments. The effects of time, temperature, ionic strength and pH were investigated. The sensitivity of the coulometric reaction vessel/detection system was sufficient even at very low total carbon content (< 0.1 mol kg-1). The efficiency of the system is estimated to be 96% with a standard deviation of 8%. Experiments were carried out using NIST Standard Reference Materials 4357 Ocean Sediment (OS), 2704 Buffalo River Sediment (BRS), and pure calcium carbonate. Carbonate minerals were dissolved selectively using an ammonium acetate-acetic acid buffer. Organic matter was then oxidized to CO2 using hydrogen peroxide (H2O2) in nitric acid. The carbonate fraction was completely dissolved within 120 min under all conditions examined (literature suggests up to 8 h). For the OS standard, the oxidation of organic matter self-perpetuates between 45 and 50 degrees C, a factor of two less than commonly suggested, while organic carbon in the BRS standard required 80 degrees C for the reaction to proceed to completion. For complete oxidation of organic matter, we find that at least three additions of H2O2 are required (popular methods suggest one or two). 相似文献
912.
In this paper, we use a two-region version of the CETA model to analyze international CO2 emission control policies. The policies we consider are all substantially equivalent to a policy recently proposed by the Alliance of Small Island States (AOSIS). The AOSIS proposal requires the OECD alone to reduce emissions, while the alternatives we consider achieve equivalent reductions via emission rights traded (1) between regions, (2) between time periods, or (3) both. We find that tradeable rights systems provide significant overall cost savings relative to the AOSIS proposal. Cost reductions may be roughly 60% for rights tradeable between regions, 50% for rights tradeable between time periods, and 95% for rights tradeable between regions and time periods. The benefits of these cost reductions accrue to both the OECD and the Rest of the World. Our results underscore the importance of using an efficient policy to achieve any given atmospheric concentration objective. 相似文献
913.
Summary The distributions of mountain hare (Lepus timidus) and European hare (L. europaeus) overlap in central Sweden, but they occupy separate food niches in winter. In Scandinavia, the European hare is mainly a grazer while mountain hare is a predominant browser. Browse contain high amounts of secondary metabolites, such as phenols, compared to grass. This raises the question if the two hare species differ in their metabolic tolerance of plant phenols and that these differences influence their food choice.Phenolic excretion in urine increased significantly with phenolic intake in both species. Excretion of glucuronic acid conjugates, one of the major pathways of elimination of phenols in both hare species, is positively correlated to phenolic intake and excretion. However, the extent of excretion of phenolics by this route was different in the two species of hare. European hares excreted substantially more glucuronic acid per amount of phenolics than mountain hare. The phenols were metabolized to a larger extent in the mountain hare, indicating a higher detoxification capacity. From these results it is likely that European hare have a higher cost for the detoxification of plant phenols compared to mountain hare. This cost and negative effect on sodium balance when feeding on browse may prevent exploitation of forest habitats by European hares, whereas mountain hare are better able to do so. 相似文献
914.
Summary Associations among female sperm whales, Physeter macrocephalus, and their dependent offspring, off the Galapagos Islands were studied between 1985 and 1989. The whales were found in groups containing about 23 individuals, with each individual having approximately 12 constant (over years) companions. These permanent units associated with one another for periods of 6.5 days, although the rate and duration of these associations seemed to vary between years, perhaps because of differences in the food supply. The principal function of the closed units may be care of the offspring, and units in the same general area may derive benefit from feeding in a coordinated manner.Offprint requests to: H. Whitehead 相似文献
915.
Assessing Ecological Integrity of Ozark Rivers to Determine Suitability for Protective Status 总被引:3,自引:0,他引:3
Preservation of extraordinary natural resources, protection of water quality, and restoration of impaired waters require a strategy to identify and protect least-disturbed streams and rivers. We applied two objective, quantitative methods to determine stream ecological integrity of headwater reaches of 10 Ozark rivers, 5 with Wild and Scenic River federal protective status. Thirty-four variables representing macroinvertebrate and fish assemblage characteristics, in-stream habitat, riparian vegetation, water quality, and watershed attributes were quantified for each river and analyzed using two multivariate approaches. The first approach, cluster and discriminant analyses, identified two groups of river with only one variable (% forested watershed) reliably distinguishing groups. Our second approach employed ordinal scaling to compare variables for each river to conceptually ideal conditions that were developed as a composite of optimal attributes among the 10 rivers. The composite distance of each river from ideal was then calculated using a unidimensional ranking technique. Two rivers without Wild and Scenic River designation ranked highest relative to ideal (highest ecological integrity), and two others, also without designation, ranked most distant from ideal (lowest ecological integrity). Fish density, number of intolerant fish species, and invertebrate density were influential biotic variables for scaling. Contributing physical variables included riparian forest cover, water nitrate concentration, water turbidity, percentage of forested watershed, percentage of private land ownership, and road density. These methods provide a framework for refinement and application in other regions to facilitate the process of establishing least-disturbed reference conditions and identifying rivers for protection and restoration. 相似文献
916.
An assessment of household willingness to pay for curbside recycling: a comparison of payment card and referendum approaches 总被引:8,自引:0,他引:8
Curbside recycling is a tool that communities use to reduce the need for landfill space. This study provides contingent valuation estimates of household willingness to pay (WTP) to continue a curbside recycling program in the face of budget cuts. Comparisons of two forms of the contingent valuation method (CVM) are provided: a single bounded referendum and a payment card. Neither approach emerges as unambiguously superior. Response rates were virtually identical. Both approaches show that support for curbside recycling is highly sensitive to price. Regression results from the payment card provided a more thorough identification of socio-demographic variables associated with WTP than the referendum, but the explanatory power of the two regressions did not differ significantly. The referendum estimates of mean WTP exceed those from the payment card, although the disparities are less than those typically reported in the CVM literature. Local policy makers cited the CVM results as influencing their decisions regarding funding options for the future of the program, and seemed to appreciate the fact that the two approaches provided a fairly narrow range of estimates of WTP. In an era when more of the burden of financing of environmental programs is being shifted to the local level, use of CVM to estimate the WTP of consumers for highly disaggregated goods and services designed to achieve environmental improvement will likely become more relevant to local decision makers who are interested in understanding their constituents' views. 相似文献
917.
Lying in negotiations can cause negative emotions, so participants may use neutralization strategies to reduce these feelings. We conducted a 2 (ethical versus non‐ethical climate) × 2 (low versus high negative consequences) experiment to examine how individual and situational factors affect the use of three such strategies: minimizing the lie, denigration of the target, and denial. Lying, psychological distress, and self‐perceived moral attributes were measured as non‐manipulated independent variables. One hundred and ninety‐two MBA students participated in a business negotiation in which they were provided with incentives to lie. As predicted, higher distress was associated with greater denial of lies. In addition, climate and consequences interacted to affect minimization and liars engaged in less minimization than did participants who merely concealed information. Climate and moral attributes interacted to affect denigration. We believe these findings support further study of neutralization strategies in the workplace. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
918.
Modified Fenton's processes for effective in‐situ chemical oxidation—Laboratory and field evaluation
Prasad K. Kakarla Thomas Andrews Richard S. Greenberg David S. Zervas 《补救:环境净化治理成本、技术与工艺杂志》2002,12(4):23-36
Fenton's reagent in its conventional form, although effective for contaminant treatment, is impractical from an in‐situ field application perspective due to low pH requirements (i.e., pH 3‐4), and limited reagent mobility when introduced into the subsurface. Modified Fenton's processes that use chelated‐iron catalysts and stabilized hydrogen peroxide have been developed with the goal of promoting effective in‐situ field application under native pH conditions (i.e., pH 5‐7), while extending the longevity of hydrogen peroxide. Laboratory experiments conducted in soil columns packed with organic soil to compare modified Fenton's catalysts with conventional catalysts (acidified iron [II]) indicated superior mobility and sorption characteristics for modified Fenton's catalysts. Furthermore, the acidic pH of a conventional catalyst was buffered to the native soil range, leading to increased iron precipitation/adsorption following permeation through the soil column. The chelates present within the modified Fenton's catalyst showed greater affinity toward iron compared with the native soil and, hence, minimized iron loss through adsorption during the permeation process even at pH 5‐7. Field effectiveness of the modified Fenton's process was demonstrated at a former dry‐cleaning facility located in northeast Florida. Preliminary laboratory‐scale experiments were conducted on soil‐slurry and groundwater samples to test the process efficacy for remediation of chlorinated solvents. Based on successful experimental results that indicated a 94 percent (soil slurry) to 99 percent (groundwater) reduction of cis‐1,2‐DCE, PCE, and TCE, a field‐scale treatment program was initiated utilizing a plurality of dual‐zone direct push injection points installed in a grid fashion throughout the site. Results of treatment indicated a 72 percent reduction in total chlorinated contamination detected in the site groundwater following the first injection event; the reduction increased to 90 percent following the second injection event. © 2002 Wiley Periodicals Inc. 相似文献
919.
Biodegradability of Urea-Aldehyde Condensation Products 总被引:1,自引:0,他引:1
Thomas Jahns Heiko Ewen Heinrich Kaltwasser 《Journal of Polymers and the Environment》2003,11(4):155-159
Condensation products of urea and different aldehydes (formaldehyde, isobutyraldehyde, crotonaldehyde) are used in large amounts (more than 300,000 tons per year) as resins, binders, and insulating materials for industrial applications, as well as in controlled-release nitrogen fertilizer for greens, lawns, or bioremediation processes. The biodegradability of these condensates and the enzymic mechanism of their degradation was studied in mircoorganisms isolated from soil, which were able to use these compounds as the sole source of nitrogen for growth. Different pure cultures of both gram-positive and gram-negative bacteria completely degraded methylenediurea, dimethylenetriurea, isobutylidenediurea, and crotonylidenediurea to urea, ammonia, and the corresponding aldehydes and carbon dioxide. Enzymes initiating this degradation were purified and characterized and turned out to be different with regard to their regulation of expression, their physicobiochemical properties, and their reaction mechanism. 相似文献
920.
This study investigated value congruence effects on organizational commitment and job satisfaction. We used the competing values framework to measure values, and response‐surface methodology employing polynomial regression equations to investigate congruence effects. Our sample, 1,358 hospital employees, made judgments about their personal preferences for the four competing value sets—internal process, open systems, rational goal, and human relations. They also rated how much the same values were operating in the organization. We predicted that organizational commitment and job satisfaction would be maximized when a ‘match’ or ‘congruence’ occurred between the two component value measures. We evaluated congruence effects using the following criteria: (1) the proportion of variance explained by the overall equation was significant; (2) the quadratic and interaction terms were significant individually and as a set, and their signs were in the right direction; (3) the implied constraints were valid; and (4) no higher‐order terms beyond those indicated by the model were significant. The results indicated that although quadratic and interaction components were present in all eight models, they were weak in their support for congruence. The study's findings suggested that congruence effects were relatively unimportant compared to main effects in explaining variance in organizational commitment and job satisfaction, at least in the large organization we investigated in this study. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献